That error message generally means that no server is listening on the 
host/port name you entered.  Have you tried actively testing mail calls 
to all environments via telnet?

telnet mail.yourdomain.com 25

=> should receive a 220 response

greet your postman

HELO test.yourdomain.com

=> should get a 250 mail response from the postman telling you who it 
is.

MAIL FROM:<[email protected]>

=> 250 2.1.0 Ok

DATA

=> 354 End data with <CR><LF>.<CR><LF>

Subject: test message
Press enter/return and then you can type the body of the message.

=> 250 2.0.0 Ok: queued as blahblahblah

=============

You should run a full test message through telnet not just a connect. 
Since you are using multiple mail domains you need to test each and 
every one listed in devel, test, production...

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