Re: Stop Bath

2002-03-16 Thread Shel Belinkoff

I processed my first roll of film in 1967, and since then have processed
countless rolls, many emulsions, and used numerous developers, and have
always used a stop bat.  I've used many dilutions of stop bath 'cause
I'm always in a hurry (I Hate Developing Film) and often don't measure
precisely.  Never had a pin hole.  Is this just a theoretical problem,
or does it really happen to some people?

Paul Stenquist wrote:
 
 Isn't venegar pretty much the same thing as stop bath (ascetic acid), athough
 in diution? I use about one teaspoon of stop bath per quart. Smells exactly
 like vinegar. However, when developing film, I do a quick water rinse before
 pouring in the stop bath. I think that reduces the possibility of pinholing.
 Paul

-- 
Shel Belinkoff
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Re: Stop Bath

2002-03-16 Thread William Robb

- Original Message -
From: Shel Belinkoff
Subject: Re: Stop Bath


 I processed my first roll of film in 1967, and since then have
processed
 countless rolls, many emulsions, and used numerous developers,
and have
 always used a stop bat.  I've used many dilutions of stop bath
'cause
 I'm always in a hurry (I Hate Developing Film) and often don't
measure
 precisely.  Never had a pin hole.  Is this just a theoretical
problem,
 or does it really happen to some people?

It is a very real problem with Kodalith, and can also be a
problem with a very high PH developer if the stopbath is too
strong. I have only seen pinholes with Kodalith, however.
William Robb
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Re: Stop Bath

2002-03-16 Thread Bob Rapp

I had the pinhole problem when developing the old Panatomic-X. As a
result, I have only used a water rinse, I fill, invert twice and dump.

Bob Rapp
- Original Message -
From: Shel Belinkoff [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, March 17, 2002 1:39 AM
Subject: Re: Stop Bath


 I processed my first roll of film in 1967, and since then have processed
 countless rolls, many emulsions, and used numerous developers, and have
 always used a stop bat.  I've used many dilutions of stop bath 'cause
 I'm always in a hurry (I Hate Developing Film) and often don't measure
 precisely.  Never had a pin hole.  Is this just a theoretical problem,
 or does it really happen to some people?

 Paul Stenquist wrote:
 
  Isn't venegar pretty much the same thing as stop bath (ascetic acid),
athough
  in diution? I use about one teaspoon of stop bath per quart. Smells
exactly
  like vinegar. However, when developing film, I do a quick water rinse
before
  pouring in the stop bath. I think that reduces the possibility of
pinholing.
  Paul

 --
 Shel Belinkoff
 mailto:[EMAIL PROTECTED]
 http://home.earthlink.net/~belinkoff/
 http://home.earthlink.net/~belinkoff/darkroom-rentals/index.html
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Re: Stop Bath

2002-03-16 Thread Christian Skofteland

Thanks everyone for replying to my original message.

I'll continue to use tap water since I don't re-use fixer and I like the
results I'm getting.

Christian Skofteland
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Re: Stop Bath

2002-03-16 Thread Bob Poe

One more shot at this topic, if I may,
Someone may have already mentioed this but I've found
that right after my fix starts to go bad, I use it for
my stop bath.  It still keeps disolving unexposed
silver, albeit at a less effective level, but it
allows my final fix to last about 3-4 times longer
than it otherwise would.
my 2 farthings worth...Bob
--- Christian Skofteland [EMAIL PROTECTED]
wrote:
 Thanks everyone for replying to my original message.
 
 I'll continue to use tap water since I don't re-use
 fixer and I like the
 results I'm getting.
 
 Christian Skofteland
 [EMAIL PROTECTED]
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Re: Stop Bath

2002-03-16 Thread Paul Stenquist

I've had it happen, but not in the last twenty-five years. I think I probably was
mixing the stop bath a bit on the acidic side back in the seventies. It probably
had something to do with the stuff I was ingesting. But I just got in the habit of
the quick water rinse. I think it also adds about 5 or 10 seconds to my
development time, so it has become part of the process. You know how that is Shel,
one of those things you leave in place if everything else is working okay. Can't
say for sure that there are any real benefits. (Aside from the fact that it keeps
the stop bath fresh and allows me to reuse it in the print tray.)
Paul

Shel Belinkoff wrote:

 I processed my first roll of film in 1967, and since then have processed
 countless rolls, many emulsions, and used numerous developers, and have
 always used a stop bat.  I've used many dilutions of stop bath 'cause
 I'm always in a hurry (I Hate Developing Film) and often don't measure
 precisely.  Never had a pin hole.  Is this just a theoretical problem,
 or does it really happen to some people?

 Paul Stenquist wrote:
 
  Isn't venegar pretty much the same thing as stop bath (ascetic acid), athough
  in diution? I use about one teaspoon of stop bath per quart. Smells exactly
  like vinegar. However, when developing film, I do a quick water rinse before
  pouring in the stop bath. I think that reduces the possibility of pinholing.
  Paul

 --
 Shel Belinkoff
 mailto:[EMAIL PROTECTED]
 http://home.earthlink.net/~belinkoff/
 http://home.earthlink.net/~belinkoff/darkroom-rentals/index.html
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Re: Stop Bath

2002-03-15 Thread moesg

For negs I just use tap water for one minute, and then two more tanks of 
water to rinse, this works for me since I dump my fix.  I have heard that 
water allows some developer to stay on the negatives and bring out the 
highlightsas the less exposed areas don't use the deveolper as quick. I 
don't know if it is true but it always sounded good to me.

Geoff
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Re: Stop Bath

2002-03-15 Thread Bob Rapp

The primary reason for using water over an acid stop bath is that, on some
emulsions, there is a danger of developing pin holes due to the liberation
on gas as a result on neutralising the alkaline developer.

Bob
- Original Message -
From: Bill D. Casselberry [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, March 16, 2002 2:51 AM
Subject: Re: Stop Bath


 Christian wrote:

  Just a novice question about BW film development:
  What are your choices for stop baths?  I learned from
  my dad who just uses tap water for 1 minute.

 Preferences vary - water bath stop works by massively
 diluting any residual developer and real stop bath works
 by being acidic and stopping the reaction in its tracks
 chemically. Stop bath is cheap  easy  effective, so IMHO
 it makes little sense not to use it.

 I'll leave the rest to others w/ greater experience.

 Bill

 -
 Bill D. Casselberry ; Photography on the Oregon Coast

 http://www.orednet.org/~bcasselb
 [EMAIL PROTECTED]
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Re: Stop Bath

2002-03-15 Thread Collin Brendemuehl

Perhaps we should all stop
and bathe on occasion.
(Sorry.  It's just Friday.)

Collin


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Dr. Laura

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Re: Stop Bath

2002-03-15 Thread Ann Sanfedele

I'm a white vinegar girl, myself. It works and it doesn't bite.  stop
bath
is a nasty chemical. The developers and fix are bad enough.  just a
couple of tablespoons to a quart of water seems adequate to me. Better
for you, better
for the environement.

annsan

Christian Skofteland wrote:
 
 Just a novice question about BW film development:
 
 What are your choices for stop baths?  I learned from my dad who just uses
 tap water for 1 minute.
 
 How does this choice effect the final processed negative?
 
 Thanks
 
 Christian
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Re: Stop Bath

2002-03-15 Thread tom

On 15 Mar 2002 at 22:02, Ann Sanfedele wrote:

 I'm a white vinegar girl, myself. It works and it doesn't bite.  stop
 bath
 is a nasty chemical. 

Huh? It's the same stuff, unless you're talking glacial acetic acid, which is the same 
stuff, just *very* concentrated.

 The developers and fix are bad enough.  just a
 couple of tablespoons to a quart of water seems adequate to me. Better
 for you, better
 for the environement.

Again, white vinegar = dilute acetic acid, though probably not as pure as you would 
get from Kodak or Ilford.

Also, a couple of tablespoons probably isn't enough. In that scenario, you're 
basically using a water stop. 

OTOH, that might not be a bad thing.

tv
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Re: Stop bath and vinegar

2001-01-23 Thread Mike Johnston



 I don't even use selenium toner on
 a regular basis, since that's a
 pollutant unless you live near the ocean.
 
 Care to expand upon that Mike?  What's one's proximity to the
 ocean got to do with selenium toner being a pollutant?


Shel,
Because selenium is a pollutant in fresh water but not in seawater. If you
live in an area where your "gray water" (municipal term for used household
water that doesn't need to go to the septic tank or sewer) sheds to the
ocean, you can put selenium toner down the drain without a care--selenium
occurs naturally in seawater anyway and a miniscule bit more won't hurt
anything. However, if you live in an arid region where gray water is
processed and recovered or goes into the soil and thence to the water table,
it's not really a nice thing to do to add selenium to it.

Most selenium poisoning of water, however, is not the result of the
inconsequential amounts used by art photographers--it's the result of
irrigation in dry areas. By pumping water up from wells, watering crops with
it and then letting it settle down into the water table again, selenium is
"leached" out of the soil and into the water, and the concentrations of
selenium can get unacceptable. This is just a byproduct of filtering the
water through the soil again and again, not the result of Mad Scientist
Zoner photographers maniacally tossing spent toner down their household
drains. Still, it's not something I want to do, just for form's sake. There
are a number of papers that look just fine without toning and aren't much
improved with toning--my standard paper, Agfa MCC, being one of them--so I
just use those.

--Mike

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Re: Stop bath and vinegar

2001-01-22 Thread Mike Johnston



 Well, I guess for 20 odd years then the prints have just been developing a bit
 more in the fix.   I use rapid fix, tho, and that's pretty strong so I think
 it
 stops
 quickly enough.  Never refresh chemicals, always start new.
 


Annsan,
You've been stopping your prints with water. No harm in that. Lots of
photographers I know do that as part of their usual method. I think you can
dispense with the tablespoon of vinegar, though, as it's not having any
effect.

As to whether you should replace the tray during your printing session, try
this: after you finish a session, place the tray of water aside somewhere
and let it evaporate over the next few weeks. When it's finished
evaporating, you'll be able to see fairly easily how much developer solution
has carried over into the water tray that you're using as stop.

So as not to create any gratuitous suspense, I'll just say that I think what
you find will shock you--there will prove to be lots of developer in the
stop-water which will reveal itself as a brown, oxidized layer of crud on
the bottom of the evaporated stop-bath tray.

 
 Please note - BE CAREFUL GLACIAL CAN BURN YOU.For a very short time in
 my life I worked in a chemistry lab at the U of Maine in Orono - that was
 horror

Glacial is pure acetic acid. Stop bath mostly comes as a 28% solution, which
is sufficiently diluted that it can't do any harm. "Indicator" stop bath has
a testing chemical called Bromocresol Purple added to it. Most photographers
start with 28%, which is the standard stop bath formula that is sold in
stores. Then you dilute it further to get to acidic solution you want--Ansel
Adams recommended 6% solution (slightly stronger than vinegar), many books
recommend 3% (slightly weaker than vinegar)--it doesn't really matter. I
only use glacial because it is cheaper and it's not polluted with that
yellow "indicator" which is useless anyway (because, by the time the
bromocresol purple changes from yellow to purple, it's been ineffective for
some time already). Many people who use glacial as a starting point first
dilute it to a 28% solution, store it that way, then dilute it further for
use. If you buy 28% solution or mix stock 28% solution, acetic acid isn't
potentially harmful to you.

What you want to end up with is a weakly acidic solution that stops the
action of the developer, mainly to protect the acidity of the fixer. To test
this, here's a simple trial. Put your fingers in the developer. It's
alkaline, like soap, so it should have a soapy, slimy feel when you rub your
fingers together. Then put your fingers into the stop bath and rub them
together again. With a fresh stop bath of sufficient acidity, the slimy feel
will go away instantly and you'll get the same "clean" feel that you do when
you wash soap off your hands. With water, it just takes a little longer for
the alkaline developer to wash off your fingers.

The "slimy feel" indicator is more accurate than bromocresol purple.

I choose my chemicals to make a safe and environmentally benign darkroom. I
don't even use selenium toner on a regular basis, since that's a pollutant
unless you live near the ocean.

--Mike



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