[biofuel] Fox/Ginosar

2002-01-26 Thread David E. Cruse

Hi Keith and Everyone,

#6Detailed Description of the Preferred Embodiments

As the reaction proceeds, glycerol and the alkyl esters of the glyceride 
are produced. Glycerol has low solubility in critical fluids such as CO2 and 
propane which will cause the glycerol product to drop
out of the critical fluid medium. This removal of the glycerol from the 
reaction phase of the critical 
fluid medium will enhance the reaction equilibrium and drive the reaction 
further to completion with
limited excess alcohol. One skilled in the art will then recognize that the 
quantity of excess alcohol
required to drive reaction to completion will depend not only on such factors 
as the desired reaction
rate, but also the glycerol solubility in the chosen critical fluid.
The ability of the critical fluid medium to solvate the reactants 
eliminates the immiscible phases
found in conventional processes. The single phase reaction eliminates 
inter-phase mass transfer of
the individual reactants and catalyst, thereby greatly increasing the 
reaction's rate.
After completion of  the reaction, the reaction vessel may be the 
separation vessel, a final product
stream  110  exits the reactor  10  and enters a first product separator. In 
the first product separator
12  the product stream's temperature and/or pressure are modified to allow the 
least soluble product
in the critical fluid to quantitatively drop out, the glycerol in this 
embodiment . Once the glycerol has
dropped out of the critical fluid medium, a physical separation of the two 
phases can be readily
accomplished. A glycerol product stream  112  and a glycerol depleted product 
stream  114  exits the
first separator  12. The glycerol depleted product stream  112  consists of the 
critical fluid, excess
alcohol, alcohol ester of the glycerides, and any remaining catalyst, if a 
liquid catalyst is used, and
then enters a second product separator  14.  Again the temperature and pressure 
of the critical fluid
are lowered to allow the desired product, the alkyl ester of the glyceride of 
this embodiment, to drop
out of the critical fliud while retaining the excess alcohol in the critical 
fluid. The physical separation
of the two phases then creates a second product stream of the alcohol ester  
116  and the critical
fluid recycle  104  which will be reintroduced back into the front of the 
process after having its pressure
and temperature restored to the original input reaction requirements.
While this embodiment describes a process with two product streams, the 
glycerol and alkyl ester,
it should also be apparent to one skilled in the art that a reaction producing 
more than two products
can produce multiple product streams by simply increasing the number of product 
separators.
Although the present invention has been described with reference to 
preferred embodiments, those
skilled in the art will recognize that changes may be made in form and detail 
without departing from
the spirit and scope of the invention.


Well that's it folks, all that's left are the claims which are required in 
any Patent,
so this goes out to those skilled in the art, hope someone out there can use 
this,
David Cruse


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[biofuel] Fox/Ginosar

2002-01-20 Thread David E. Cruse

Hi Keith and Everyone,
   Don't know if anyone is still interested in this stuff, as 
someone posted a message that the patent could be viewed on a website that they 
gave the address to, so if anyone wants me to continue after this post please 
let me know.

#5  Detailed Description of the Preferred Embodiments continued

 Figure 1 provides a basic flow diagram for the glyceride reaction process 
employing a continuous
reactor. Throughout the description of the process diagram, the various process 
vessels will be 
numbered between 1 and 99, with the various process streams being numbered 
beginning with 100.
While the following discussion will describe a continuous reactor process for a 
transesterification
reaction of glycerides with an alcohol  ROH, one skilled in the art will 
recognize the process principles
apply equally well in other process settings such as ones using batch reactors 
and separation processes as well as reactions producing alternate products to 
the alcohol esters as well as processes
beginning with fatty acid feeds.
A glyceride containing feed  100  is mixed with an input alcohol stream  
102. The choice of alcohol will be a function of the desired reaction product, 
and typically such alcohols as methanol, ethanol, propanol, and butanol are 
chosen for practical reasons, however, one skilled in the art will readily 
recognize the flexibility of choices and non-limiting aspect of the above list. 
This input alcohol stream  102  contains approximately a stoichiometric 
quantity of alcohol necessary to quantitatively react the
glyceride feed  100. While the reaction will require some excess alcohol, that 
needed excess is
contained in a critical fluid recycle  104  which provides a transport medium 
that solvates the reactants
to create the required process conditions. The exact critical fluid employed 
for a given reaction will 
depend on specifically chosen process parameters such as temperature, pressure, 
desired reaction
products, solubility of the reaction products, quantity of excess alcohol 
needed to drive the reaction
to completion, post reaction separation processes and chosen catalyst. Examples 
of possible critical
fluid solvents are carbon dioxide, sulfur dioxide, methane, ethane, propane, or 
mixtures thereof, with
or without critical fluid co-solvents such as methanol, ethanol, butanol, or 
water. Naturally, to the
extent quantities of the critical fluid are lost during the process they can be 
replenished with a critical
fluid makeup stream  106.
   The mixing of the input feed  100 (substance containing free fatty acids 
and/or glycerides), the input
alcohol  102, the critical fluid recycle  104  and critical fluid makeup  106  
streams, creates a reactant
input stream  108  which is fed into a continuous reactor 10. The temperature 
and pressure of the reactant input stream will depend on its components and the 
desired  process parameters. The important criteria for the critical fluid is 
its ability to dissolve the reactants. Reaction temperatures 
should be within 20% of the critical temperature of the fluid as measured in 
Kelvin, and pressures 
within 0.5-15 times critical pressure as modified by any co-solvent. Reaction 
temperatures are typically
in the range from about 20 to 200 degrees C with reaction pressures in the 
range from about 150 psig
to 4,000 psig.
The transesterification reaction generally proceeds in the presence of a 
catalyst either acidic or
basic. Liquid acids and bases, such as the common inorganic acids HCL, H2SO4, 
and HNO3, and
inorganic bases NaOH and KOH typically provide the needed catalytic activity. 
Additionally, the use
of a critical fluid medium allows for use of a solid phase catalyst with either 
acidic or basic surfaces
such as microporous crystalline solids such as zeolites, and non-crystalline 
inorganic oxides such as
alumina, silica, silica-alumina, boria, oxides of phosphorus, titanium dioxide, 
zirconium dioxide, chromia, zinc oxide, magnesia, calcium oxide, iron oxides, 
unmodified, or modified with chlorine,
florine, sulfur or an acid or base, as well as mixtures of the above group or 
an exchange resin with acidic or basic properties. Where solid catalysts are 
used in the reactor, they may create a catalytic
packed bed or float free inside the reactor.

To be continued,
David Cruse


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[biofuel] Fox/Ginosar

2002-01-16 Thread David E. Cruse

Hi Keith and Everyone,

#4 Detailed Description of the Preferred Embodiments Continued

 In the case of mono,di, and triglycerides, fats and oils, R1 is the aliphatic 
hydrocarbon (C4 to C24)
 chain, R2 is glycerol and R3 is a hydrocarbon group, and preferably a short- 
chain alkyl group, more
 preferably methyl, ethyl, propyl or butyl group attached to the alcohol. In 
the case of free fatty acids,
 R1 is the aliphatic hydrocarbon chain wherein the terminal carboxylic acid 
group could be 
 R1COO  or  R1COOM+  where  M+  is a metal (thus, the salt of a free fatty 
acid); and, R3 is the
 short-chain hydrocarbon attached to the alcohol. In the case of a wax, R  is 
an aliphatic hydrocarbon
 chain linked to  R2  via the carboxylic ester linkage, and  R3  is the 
short-chain hydrocarbon attached
 to the alcohol.
 

To be continued,
David Cruse


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[biofuel] Fox/Ginosar

2002-01-15 Thread David E. Cruse

Hi Keith,Dana,And Everyone,

#3  Detailed Description of the Preferred Embodiments

   The present invention describes a process for reacting organic compounds 
having the generic
formula  R1COOR2  with short-chain (C1 to C4) alcohols in a single critical 
fluid phase over an 
acidic or basic catalyst to produce alkyl esters suitable as a biodiesel fuel. 
One skilled in the art
will recognize that organic compounds from the family of compounds known as 
acylglycerols, fats,
oils, waxes, or free fatty acids have the general formula  R1COOR2 .  One 
skilled in the art will also 
recognize that acylglycerols can be mono,di,or tri substituted in any manner. 
The invention includes
the transesterification and esterification of  R1COOR2  molecules with short 
-chain alcohols such as
methanol, ethanol, propanol, or butanol to produce alcohol esters. The 
invention also encompasses
the acid and base catalyzed hydrolysis of  R1COOR2  compounds in a single 
critical fluid medium
where  R1  is a chain of aliphatic hydrocarbons (C4 to C36), and where R2 can 
either be glycerol or
can be another aliphatic hydrocarbon chain (C4 to C36) linked to R1 via the 
carboxylic ester (BCOO-)
linkage. The reaction is generally described as follows:

 R1COOR2 + R3OH -- R1COOR3 + R2OH
   
   catalyst

To be continued,
David


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[biofuel] Fox/Ginosar

2002-01-13 Thread David E. Cruse

Hi Keith and Everyone,   #2

   It is the object of the present invention to provide a process for 
reacting triglyceride-
and free fatty acid-containing substances capable of completing the reaction in 
significantly
less time than present conventional processes.
   It is another object of the present invention to provide a process 
for reacting triglyceride-
and free fatty acid-containing substances capable of using reusable catalyst 
thereby avoiding 
the need for process neutralization.
   It is yet another object of the present invention to provide a 
process for reacting triglyceride-
and free fatty acid-containing substances capable of using a solid phase 
catalyst.
   It is yet another object of the present invention to provide a 
process for reacting triglyceride-
and free fatty acid-containing substances with higher yields of desired product 
over conventional 
processes.
   It is yet another object of the present invention to provide a 
process for reacting triglyceride-
and free fatty acid-containing substances capable of operating in a single 
phase, thereby eliminating
immiscible liquid phases and reducing mass transfer reaction limitations.
   It is yet another object of the present invention to provide a 
process for reacting triglyceride-
and free fatty acid-containing substances with improved separation capabilities 
for for separating purified reaction products without the need for washing 
steps.
   It is yet another object of the present invention to provide a 
process for reacting triglycerides and free fatty acids which can 
quantitatively react the triglycerides or free fatty acids with significantly
less excess alcohol than present processes.

  At this point, if everyone interested would go to 
http://pctgazette.wipo.int/  and click 
search IPDL, then enter IN/GINOSAR, then select WO 00/05327 and find the flow 
diagram
and print it out, you will have an illustration of the embodiment of the 
invention employing a
continuous reactor.

To be continued,
David Cruse


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[biofuel] Fox/Ginosar

2002-01-11 Thread David E. Cruse

Hi Keith,Dana,and Everyone,
  I'm going to send one page per 
e-mail, and I'm not going to send 
Claims, Prior Art,or the Abstract, as I see no real reason to waste effort on 
these things, so lets
begin !
#1Summary and Objects of the Invention
This invention provides a single-phase process for 
producing alkyl esters as biofuels
 and lubricants by the reactions of triglyceride esters and free fatty 
acids. This invention teaches
 a process where the reactants enter a reactor, whether batch or 
continuous, dissolved in a critical
 fluid. The critical fluid provides a single-phase medium in which 
diffusion of the reactants into
 different liquid phases is eliminated, and mass transfer limitations are 
essentially eliminated
 thereby increasing the overall reaction rate. A critical fluid is a fluid 
whose temperature is within
 20% of the critical temperature of the fluid as measured in Kelvin and 
pressure within 0.5-15
 times the critical pressure as modified by any co-solvent.
 Additionally, the solubility of the reaction products such 
as alkyl esters in the critical
 fluid can be controlled by controlling the reactor's temperature and 
pressure. Where a reaction 
 product's solubility is low or nonexistent such as glycerol, it drops out 
of the fluid as it is created,
 thereby driving the reaction equilibrium toward product production which 
significantly reduces
 the quantity of excess reactants such as alcohol needed to drive the 
reaction to completion.
 The use of a critical fluid also allows for a wide range 
of catalysts, both liquid phase
 and reusable solid phase acid or base catalysts. Solid phase catalysts 
have significant additional
 advantages by limiting unwanted side reactions and producing higher 
conversion rates of the
 desired products.
  With the reaction completed, the critical fluid medium 
also facilitates clean separations.
 The reaction products typically can be sequentially and selectively 
removed from the critical fluid
 medium by adjusting the temperature and pressure of the critical fluid 
medium. In a 
 transesterification reaction of the triglycerides, the glycerol is removed 
first leaving the alcohol
 esters in the critical fluid. With the glycerol removed, the temperature 
and pressure is again 
 changed to drop out the alkyl esters. Once the products are removed the 
critical fluid and any 
 excess reactants are returned to the beginning of the process.


 To be continued,
 David Cruse


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[biofuel] solid catalyst

2002-01-10 Thread David E. Cruse

Hi Keith and Everyone,

I would be glad to post a small part of the process
using a solid catalyst from the Fox/Ginosaur et al
Patent. Hopefully this will give everyone an idea as to
how difficult the process really is and may shed some 
light on the ongoing mystery about this fabled process.
It will take a little time for me to get this posted (this
weekend), so let me know if you would like for me to 
do this.

David Cruse


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Re: [biofuel] Solid Catalyst

2002-01-10 Thread David E. Cruse

Hi Arne,
 This is not the Patent on the biodiesel process !
David Cruse
- Original Message -
From: Arne P. Ryason [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, January 10, 2002 11:10 AM
Subject: Re: [biofuel] Solid Catalyst


 I just did a search of the US patent office website  entered Fox AND
 Ginosar in the inventor terms search and got patent # 6,103,948:
 Solid catalyzed isoparafin alkylation at supercritical fluid and
 near-supercritical fluid conditions

 Abstract:

 This invention relates to an improved method for the alkylation reaction
 of isoparaffins with olefins over solid catalysts including contacting a
 mixture of an isoparaffin, an olefin and a phase-modifying material with
 a solid acid catalyst member under alkylation conversion conditions at
 either supercritical fluid, or near-supercritical fluid conditions, at a
 temperature and a pressure relative to the critical temperature(T.sub.c)
 and the critical pressure(P.sub.c) of the reaction mixture. The
 phase-modifying phase-modifying material is employed to promote the
 reaction's achievement of either a supercritical fluid state or a
 near-supercritical state while simultaneously allowing for decreased
 reaction temperature and longer catalyst life.

 (I'm not a chemist )

 The assignee is Bechtel BWXT Idaho LLC of Idaho Falls, the biggest town
 near the INEEL. Although INEEL is a government lab it is populated
 with private corporate interests.

 Arne.




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Re: [biofuel] Re: solid catalyst

2002-01-10 Thread David E. Cruse

Hi Keith,
  Ok I'll post enough info so that everyone can
at least understand the basics.
David Cruse
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, January 10, 2002 11:43 AM
Subject: [biofuel] Re: solid catalyst


 Hi David, John

 David, I think a lot of people would be grateful if you'd post what
 you can of the patent. Thankyou. The Files section is not open for
 uploads by members, I have to do it. I don't mind doing it, if that
 seems a good idea. What format is it in now? Whatever, please post it
 as an email, the archives is much more often consulted than the Files
 section. If you head it something like INEEL Fox/Ginosar solid
 catalyst patent it shouldn't be hard to find! The archives search
 function works well, I find.

 Best

 Keith Addison
 Journey to Forever
 Handmade Projects
 Tokyo
 http://journeytoforever.org/



 Hi David
 I would like to see the patent. If you could upload it into the files
 section instead of an email it may stay easier to find
 Regards
 JohnH
 
 --- In [EMAIL PROTECTED], David E. Cruse [EMAIL PROTECTED] wrote:
   Hi Keith and Everyone,
  
   I would be glad to post a small part of the process
   using a solid catalyst from the Fox/Ginosaur et al
   Patent. Hopefully this will give everyone an idea as to
   how difficult the process really is and may shed some
   light on the ongoing mystery about this fabled process.
   It will take a little time for me to get this posted (this
   weekend), so let me know if you would like for me to
   do this.
  
   David Cruse
 


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Re: [biofuel] Solid catalyst,

2002-01-08 Thread David E. Cruse

Hi Christian and Everyone,
 I'm not sure if you folks were in
this group last year or not, but
if you are interested in using solid catalyst or other methods to make
biodiesel, might I
suggest that you look in the US Patent office website www.uspto.gov . Just
enter biodiesel
in the search query box and you should get a wealth of information on the
subject, or enter
any other keyword that is associated with the subject and you will find many
patents with
lots of info that will help you with your questions. I mentioned last year
and possibly the
year before because there was a lot of discussion back then about all of
these things. Search
a little farther back in the archives of this group and you should find some
of these subjects, a
lot of research has already been done by members of this group, and it's
just sitting there waiting to be accessed. The famed Fox/Ginosaur process
using a solid catalyst, (which to this date)
hasn't been used commercially, is on Delphion.com. I was lucky enough to
download a copy of
the Fox/Ginosaur patent from the Delphion website before they started
charging a fee to access
the International Patents. It is at best vague and very careful to be as
vague as possible with all
the info in the Patent. The Lockheed Martin Idaho Technologies Company is
the company
that actually owns the Patent and they don't seem to be rushing into
production of biodiesel
with the process so that should tell you that the process probably isn't all
that good ! The
USPTO website has a lot of other more practical info on how to make
biodiesel with an
alternate method, so give it a look and you may find something that will fit
!! US Patent
number 4,695,411 is a process to make biodiesel using hydrated ethanol,
that is to say
using ethanol with water in it. One problem that is always associated with
using ethanol is,
how obtain ethanol with no water content ! This Patent may not be practical,
I don't know,
but it may be of some help. You can search for millions of things that will
be of help in
all areas of any endeavor.

Good Hunting,
David Cruse

- Original Message -
From: Christian [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, January 08, 2002 7:00 PM
Subject: Re: [biofuel] Solid catalyst,


 In my humble opinion, the process described seems the counterpart to the
 alchemists recipe for turning lead into gold. A process as described
would,
 as Dana said, revolutionize production.

 Count me into the subject, though I don«t know what you«re implying with
 this. Sure, when I find some time, I«ll try to look it up. Any hints
 regarding a little more detail on the process, or where it came from?...
 just so as to get started.

 I was currently trying to do some testing with hydrochloric and ethanol..
 but my whole first attempt processor project (traditional NaOH  Meth
 recipe) is currently quite delayed due to the fact that all imported goods
 have gone up by 40% in the past week (due to the currency problems here in
 Argentina).

 Hope to hear more on the subject

 Regards,

 Christian


 - Original Message -
 From: Dana Linscott [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Monday, January 07, 2002 11:30 PM
 Subject: Re: [biofuel] Solid catalyst,


  Arne,
 
  I have not heard any further info on the process you
  describe. Of course this type of continuous process
  biodiesel/glycerin production would REVOLUTIONIZE home
  production of BD if made available. It would also work
  well in conjunction with the inexpensive WVO/SVO
  processing modules I am attempting to design and
  integrate.
 
  As I stated before even a very expensive catalyst
  module would pay for itself if shared by a group of
  users to maximize its use either by forming a
  cooperative around a shared WVO/SVO/biodiesel
  processor or by shipping the expensive catalyst module
  from one (otherwise inexpensive) home processor to
  another.
 
  I believe that this deserves more thorough
  investigation. Unfortunately, as you can see from my
  recent posts I already have a rather full plate. If
  there are three or four others that are willing to
  join forces to dig deeper I am more than willing to
  contribute to the effort as best I can.  alarge oart
  of my living hinges on gathering intelligence but I
  can't do it on my own right now.
 
  Anyone else interested? Ed?,Keith? Others???
 
  Dana
 
 
  --- Arne P. Ryason [EMAIL PROTECTED] wrote:
   Is there any known progress on the INEEL process
   which uses a solid
   catalyst to produce biodiesel and food grade
   glycerin? Two scientists
   have developed a continuous process that eliminates
   the alcohol, base,
   acid,  water wash steps of making biodiesel. Also,
   it is a continuous
   process, versus the batch process that is used now.
   The glycerin
   byproduct is food grade. Selling it would offset the
   refining process,
   making biodiesel competative with petrodiesel.
  
   Anyone with 

Re: [biofuel] The Flood

2001-09-24 Thread david e cruse

Hi Greg,

I checked out this website, found no wormgard. When you click on
the address you have listed it goes to a site called analogx !

Regards,
David Cruse
- Original Message -
From: greg [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, September 23, 2001 6:45 PM
Subject: Re: [biofuel] The Flood


 go to www.wormguard.com i have used it for about 2 months. they also have
a
 trogan program.greg m
 - Original Message -
 From: Keith Addison [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Sunday, September 23, 2001 5:06 PM
 Subject: Re: [biofuel] The Flood


  i think it was a worm or a trojan. from what it looks like on this end.
  greg m
 
  Dunno. No idea at all. Very puzzled.
 
  Keith Addison
  Journey to Forever
  Handmade Projects
  Tokyo
  http://journeytoforever.org/
 
  List owner
 
 
  - Original Message -
  From: kirk [EMAIL PROTECTED]
  To: biofuel@yahoogroups.com
  Sent: Sunday, September 23, 2001 10:38 AM
  Subject: RE: [biofuel] The Flood
  
  
A virus sent them?
Viruses are getting to be a real nuisance.
Kirk
   
-Original Message-
From: Keith Addison [mailto:[EMAIL PROTECTED]
Sent: Sunday, September 23, 2001 3:28 AM
To: biofuel@yahoogroups.com
Subject: [biofuel] The Flood
   
   
Sorry folks, I don't know what's going on here with this flood of
mostly empty messages, but I've put a stop to it until I find out.
   
Keith Addison
Journey to Forever
Handmade Projects
Tokyo
http://journeytoforever.org/
   
List owner
 
 
 
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Re: [biofuel] Re: Energy Department Lab Develops Cleaner Fuel

2001-08-29 Thread david e cruse

Hi Andrew,

The Fox / Ginosaur biodiesel Patent is  assigned to Lockheed-
Martin Idaho Technologies Company . It is at www.delphion.com ,
under a World Intellectual Property Organization International
Patent ! Unfortunately delphion.com is now charging $75.00US
a month to access their database of  international patents !

Regards,
David Cruse
- Original Message -
From: [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, August 29, 2001 8:50 PM
Subject: [biofuel] Re: Energy Department Lab Develops Cleaner Fuel


 The article mentions at the end that the two researchers have
 obtained a provisional patent. Working at a national lab myself, I'm
 wondering how the details of their work can be kept out of the public
 view. Perhpas it's just a matter of time for them to share, but the
 patent is surely owed by INEEL not by them personally.
 -andrew


 --- In [EMAIL PROTECTED], Edward Beggs [EMAIL PROTECTED] wrote:
  Probably sold it to an energy company, in the national interest.
 
 
  - Original Message -
  From: Keith Addison [EMAIL PROTECTED]
  To: [EMAIL PROTECTED]
  Sent: Wednesday, August 29, 2001 11:03 AM
  Subject: [biofuel] Energy Department Lab Develops Cleaner Fuel
 
 
   Wonder what happened to Ginosar's famous better biodiesel method?
 See:
  
   http://ens.lycos.com/ens/mar99/1999L-03-11-02.html




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[biofuel] ethanol and ethyl esters apology

2001-08-16 Thread david e cruse

BlankHi Everyone,

Sorry for the goof on the uspto website address. The right
address is as Hanns said,  www.uspto.gov . I guess I was a
little tired at the time, I had read so many things last night.
So please excuse the goof ! 

If anyone out there has any  new  info on using soapstock
as a feedstock to make biodiesel I have been looking for a
while now, and would appreciate anything anyone could pass
on. 

Best Regards,
David Cruse




[Non-text portions of this message have been removed]


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[biofuel] ethanol and ethyl esters

2001-08-15 Thread david e cruse

BlankHi Everyone,

Here is something of interest for all you folks interested
in making and using ethanol in the biodiesel process.
At www.uspto.com under patent number 4,695,411 there
are 12 Examples of different ways to manufacture ethyl
esters from different feedstocks. One Example uses 
cottonoil, another uses raw palm oil, several others use
palm oil in different ways. One note of interest is the use
of hydrated ethanol, that is to say ethanol with a water content
of 1% to 60% !!!  They use a first step acid transesterification
and also use a regular base ( naoh or koh ) esterification
with methanol or other alcohol as a second step. As always
Patents are tough reading but the information in this Patent
could yield some very helpful tips for those of you who want
to use ethanol in your process. The Description section also
says that the processes described can use vegetable or
animal oil or greases. Another note of interest is the fact that
the Patent was granted in September 1987 !!

Best Regards,
David Cruse




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Re: [biofuel] Support Grows for Corn-Based Fuel Despite Critics

2001-07-27 Thread david e cruse

Hi Keith and Everyone,

I personally think that they will win by force of money
and political influence. The financial might these corporations
wield is enough to win in most any arena they enter.

David Cruse
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, July 26, 2001 1:33 PM
Subject: Re: [biofuel] Support Grows for Corn-Based Fuel Despite Critics


 I have a niggling feeling that 10 years from now, the environmentalists
will
 be fighting the ethanol industry tooth and nail. anything can be done
badly,
 and I expect the ADM's of the world will be successful in turning a clean
 renewable resource into a dirty unsustainable one..
 
 
 Steve Spence

 Definitely a major worry. ADM, Cargill et al are already winning that
 future war, seems to me, with the likes of Club Sierra apparently
 preferring MTBE to ethanol, mainly through opposition to the ADMs,
 from what I can make out, and a misplaced concern about nitrate
 run-off from industrialised maize production, along with which party
 the corn-state senators belong to. They've completely confused
 ethanol and agribusiness. How can you win if you've got it all wrong
 in the first place?

 Keith Addison
 Journey to Forever
 Handmade Projects
 Tokyo
 http://journeytoforever.org/



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 - Original Message -
 From: Keith Addison [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Thursday, July 26, 2001 2:16 AM
 Subject: [biofuel] Support Grows for Corn-Based Fuel Despite Critics
 
 
   http://www.nytimes.com/2001/07/23/business/23ETHA.html
  
   July 23, 2001
  
   Support Grows for Corn-Based Fuel Despite Critics
  
   By LIZETTE ALVAREZ with DAVID BARBOZA
   WASHINGTON, July 22 - Supporters of ethanol, a fuel made from corn,
   are gaining in their push to make it a major part of the nation's
   energy policy, despite persistent doubts about its economic and
   environmental benefits.



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Re: [biofuel] Model American.........

2001-07-21 Thread david e cruse

Hi Christopher,

Well said !! I notice that number 1. on your list is
be self reliant ! In my time here on Earth I have also
noticed that the folks who subscribe to this self evident
truth that we all need to be self reliant in every way
possible are always the people that care the most about
each other and everything else that matters in our world.
My hat is off to you Sir.

Best Regards,
David Cruse
- Original Message -
From: Christopher S. Weller [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, July 19, 2001 10:05 AM
Subject: Re: [biofuel] Model American.


 Personally I think the Model American is the keep up with the Jones got
to make more money so I
 can buy more stuff on credit as long as I have my Cable TV and a Full
Belly every thing is Fine why
 mess with the system because they're not messing with me type of person.
 These are the same type of people who don't vote because it doesn't matter
any way then complain
 about how the gov runs things Instead of trying to change things.

 I personally am a member of several different groups(numerous) receive
about 600 emails a day that I read
 (not counting the junk and Spam) try to learn as much as I can so that I
can
 1. be Self Reliant
 2. Spread the Word to like minded people
 3. ask the right questions to Public Officials (to include my
representatives in gov.) and get the ball rolling
 4. help teach and guide the young people in my neighborhood
 5. keep the bad elements out of are family orientated neighborhood (i.e.
no hookers,drug dealers,etc.)
 6. Vote knowledgeable







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Re: [biofuels-biz] Re: Biz Plan (was)Quiet...

2001-07-17 Thread david e cruse

Hi Cordain,

Have you looked for a bakery or a plant that turns out fried
snacks like potato chips etc in your area, a donut company
is also a good bet, for your oil needs ? You may have to go
just a little farther than you anticipated for your oil supply.
Restaurants are not always a good bet ! I would be interested
in the generic business plan if you could post it.

Regards,
David Cruse
- Original Message -
From: doctor who [EMAIL PROTECTED]
To: biofuels-biz@yahoogroups.com
Sent: Tuesday, July 17, 2001 7:53 AM
Subject: [biofuels-biz] Re: Biz Plan (was)Quiet...


 hello all,
 Well good news. I've made good progress on my business plan. The actual
 company outline/structure is really easy to write. However the marketing,
 research and competition portions have required tremendous amounts of
 localized research. This is a yet not realized market in my area so I'm
 having to write out several scenarios and then go through them with a fine
 tooth comb to find the most feasible, least costly but long term effective
 solutions. I'm also trying to minimize the costly trial and error process.
 To err is human, to err without forethought is silly.

 I forgot how tedious writing one of these things gets. But I'm painting a
 portrait not a house. So little strokes.

 My biggest challenge thus far has not even been the figuring out my budget
 or financial concerns as it has been finding an adequate WVO oil supply to
 keep up with my propossed plant size (1000 US Gallons input per 24 hours
 period). Of the 50 or so restaurants I've queried in my immediate area
none
 of them [net totals] cycle out oil fast enough to meet my needs. (Which is
 quickly narrowing down the restaurants that I patronize.)

 Vegetable oil gets to the viscosity of used motor oil quickly with heavy
 usage. I dont understand trying to stretch the oil (topping off old oil),
it
 makes the food taste like soap after a while. I've written in an incentive
 program into the model that compensates restaurants for their WVO, but I'm
 trying to avoid that for the moment. However I may wind up resorting to
it,
 if WVO quality is too poor.

 I'm continuing my survey of surrounding zones (about 15 miles radious from
 propossed plant sites) for the the highest oil consumption. This will
 ultimatly decide where I put the plant. Recovery and distribution figures
 are the most easily controlled cost in my current model.

 I may wind up moving the project closer to Washington DC as it has a much
 higher ratio of restaurants per square mile.

 In any case I need to get back to researching and writing my back-up plans
 for the model.

 If anyone is interested I can post a generic WVO business plan (outline).
 It's more or less a fill in the blanks deal. No single business plan is
 going to work for every business and it's definetly a living document.
It's
 not a cut and dry plan, but it will get you going in the correct
direction.

 cheers,
 cordain
 dulles, va



 From: Pat McCotter [EMAIL PROTECTED]
 Reply-To: biofuels-biz@yahoogroups.com
 To: biofuels-biz@yahoogroups.com
 Subject: Re: [biofuels-biz] Quiet...
 Date: Fri, 13 Jul 2001 06:16:26 -0400
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 Mailing-List: list biofuels-biz@yahoogroups.com; contact
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 Delivered-To: mailing list biofuels-biz@yahoogroups.com
 Precedence: bulk
 List-Unsubscribe: mailto:[EMAIL PROTECTED]

 Thank you for the kick. I just joined a couple days ago. I am walking,
nay,
 running, to the archives right now to see if my questions can be answered
 concerning government regs in setting up a mini-refinery, taxation (I'm in
 Connecticut, US, and I see that UK does tax biodiesel) on sale of product,
 etc. I have talked to in power Democratic folks about it - Biodiesel?
 What's that?

 So, again, thanks for the kick.

 Pat





 _
 Get your FREE 

[biofuel] Was : Social effects Re:Rebel

2001-07-15 Thread david e cruse

Hi Kirk and Everyone,

That`s what is so great about being from the South (Georgia) !
Everyone from the South is labeled from birth as a Rebel and
as such we get to be as crazy and 'non-model American' as we
like ! This is very convenient when someone expects you to go along
with the rest of the crowd, because all you have to say is
'hell no I`m a Rebel' and I don`t like that bull you`re trying to
run on me so 'take a hike'  :-) !

David Cruse
- Original Message -
From: kirk [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, July 14, 2001 3:07 PM
Subject: RE: [biofuel] Social effects of motorized transport


 Model Americans need remodeling.
 :)
 Kirk

 -Original Message-
 From: Pat McCotter [mailto:[EMAIL PROTECTED]
 Sent: Saturday, July 14, 2001 10:54 AM
 To: biofuel@yahoogroups.com
 Subject: RE: [biofuel] Social effects of motorized transport


 The model American is the phrase used, Kirk. I don't buy vehicles just
to
 buy vehicles either. I keep the one I have in good running condition until
I
 no longer can, then I get another. I am not a model American.

 Auto manufacturers build for model Americans.
 City planning is for model Americans.
 Highway planning is for model Americans.
 Energy policy is for model Americans.

 From: kirk [EMAIL PROTECTED]
 Reply-To: biofuel@yahoogroups.com
 To: biofuel@yahoogroups.com
 Subject: RE: [biofuel] Social effects of motorized transport
 Date: Sat, 14 Jul 2001 10:50:54 -0600
 
 I drive 100 miles(roundtrip) once or twice a month to go grocery
shopping.
 My auto is 25 years old.
 People that trade them in every 3 years are on the hamster wheel. I'm
not.
 
 Kirk
 

 _
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Re: [biofuel] Mixing times for complete reactions

2001-06-09 Thread david e cruse

Hi Todd,
   Great post !!
David Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, June 08, 2001 1:24 PM
Subject: [biofuel] Mixing times for complete reactions


 I know that there are differing beliefs on this list as to required mixing
times for reaction completion.

 We never had any need to vary mixing time beyond 2 hours until we got up
to the 300 gallon level. What we found was that our mixing times changed
relative to the motor we were limited to and the number of gallons being
batched out. The limiting factors on the motor were amperage draw, available
electric supply, etc, coupled with the propeller configuration to get
vigorous mixing (too large a prop over amped the motor, too small resulted
in slow attainment of homogeneity).

 Another variable was the tank geometry. Whereas most tanks are cylindrical
and vertical, our prototype was a used 400 gallon stainless steel dairy
cooling tank. (It was free, so we aren't complaining.) In such a tank, the
far left and right regions of the tank don't receive as much agitation as
the center area, which means a requisite longer reaction time than something
akin to a 55 gallon drum - again, cylindrical and vertical.

 100 gallon batches took ~8 hours, 300 gallons took ~24 to insure that the
reaction was complete.

 Using nothing but shadetree ingenuity, completion here is being determined
by subjecting a liter of supposedly finished product to the entire process a
second time to determine if any more glycerin will drop out. (An antique gas
chromatograph is on its way.)

 So, while 2 hours may be sufficient for a 55 gallon drum reactor, unless
the agitator is increased in mechanical capacity to proportionally match the
increase in fluid volume being processed, we strongly suggest increased
reaction times when upscaling, until such a time as the exact completion
point can be determined by the operator.

 It's a whole heck of a lot easier to increase reaction time until the
appropriate time window can be determined than ending up with a passel of
mega-emulsifying mono- and di-glycerides from an incomplete reaction - read
mayonnaise - and suffering deflating bouts of biodiesel despair. (Been
that. Done there.)

 Todd
 Appal Energy
 [EMAIL PROTECTED]



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Re: [biofuel] a question.....

2001-06-05 Thread david e cruse

Hi  Gerry,
That sounds like you are paying too much
for the methanol. I don`t know where you are located,
but if you`re near a large city, try the yellow pages under
Chemicals. You should be able to find a supplier that
will give you a decent price. Here in Atlanta,Ga. I can
buy a 55gal. drum for $2.75 a gallon and that includes
delivery, or you can pickup smaller amounts for the
same price.  Congrats on getting started.

David Cruse
- Original Message -
From: [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, June 04, 2001 8:13 PM
Subject: Re: [biofuel] a question.



 Got all the chemicals and a bucket of pure McDonald's waste veg oil. Will
 be going thru the learning curve soon.
 The methanol was real expensive, US$35 per 5gal drum.
 Anyone got the price for methanol in bulk and the recovery rate of the
home
 made distiller.
 Figured that the bulk price and methanol recovery would made me decide
 whether it can be commercialised.
 Gerry


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[biofuels-biz] cost

2001-05-31 Thread david e cruse



Hi Keith  Steve,
 
I would like to know an easy way, if
there is one, to figure what my cost will be, in a 
gallon
of biodiesel, in any given batch that I process. 
How do 
you figure in your start up costs i.e. equipment, 
chemicals,
etc. ?
Thanks,
David Cruse P.S. Congrats on the 
new site.






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Re: [biofuels-biz] cost

2001-05-31 Thread david e cruse



Hi Pedro,
 
No specific amount, just bottom line cost
on any amount produced.

David Cruse

  - Original Message - 
  From: 
  Pedro M. 
  To: biofuels-biz@yahoogroups.com 
  
  Sent: Wednesday, May 30, 2001 4:50 
  PM
  Subject: Re: [biofuels-biz] cost
  
  To produce how many liters ??? ( i.e. 3.000 
  l)???
  
  Elabore caseramente biodiesel para su actual motor de gasoil 
  petrol’feroLa soluci—n a sus problemas energŽticos.
  
  http://sitio.de/energiahttp://journeytoforever.org/energiaweb/
  
- Original Message - 
From: 
david e cruse 
To: biofuels-biz@yahoogroups.com 

Sent: Wednesday, May 30, 2001 10:05 
PM
Subject: [biofuels-biz] cost

Hi Keith  Steve,
 
I would like to know an easy way, if
there is one, to figure what my cost will be, 
in a gallon
of biodiesel, in any given batch that I 
process. How do 
you figure in your start up costs i.e. 
equipment, chemicals,
etc. ?
Thanks,
David Cruse P.S. Congrats on 
the new site.Biofuels at Journey to Foreverhttp://journeytoforever.org/biofuel.htmlBiofuel 
at WebConXhttp://www.webconx.com/2000/biofuel/biofuel.htmTo 
unsubscribe from this group, send an email 
to:[EMAIL PROTECTED]Your 
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Re: [biofuels-biz] Greetings

2001-05-31 Thread david e cruse

Hi Cordain,
  Can`t be of much help on your questions
about these things, but just wanted to say thanks for
your answers to my question about costs.
David Cruse
Atlanta,Ga.
- Original Message -
From: doctor who [EMAIL PROTECTED]
To: biofuels-biz@yahoogroups.com
Sent: Wednesday, May 30, 2001 2:31 AM
Subject: [biofuels-biz] Greetings


 Greetings my name is Cordain Lucas I am also on Biofuels and BFIC. I
joined
 this list because I am looking for more information on getting funding,
 licensing, trading requirements, safety requirements, insurance,
 distribution and marketing, and so on  and on, nor about the special
 requirements of biofuels operations in these areas. As Keith Addison put
 it.

 I am in the long process of getting a 1k gpd RVO bio-diesel plant up and
 operational. Insert Theme to 'Impossible Dream' But as such am buried
 behind a stack of papers that has taken over my home and all my free time.
 BTW I still work a full time job until I start generating capitol or find
 some wealthy investors. Does anyone have Woody Allen's phone number?

 I have alot of questions about licensing, special permits (federal I'll be
 doing the VA state stuff soon). As I am writing my business plan right now
 my main questions right now have to deal with collection and distribution.
 What are folks using to collect mass quantities of used vegetable oil?
Also
 what kind of contract is necessary for waste oil collection? (I know what
a
 contract is, and I could have my lawyer draft one easily, but I'm more
 concerned about specifics that I may not think to have him include or
 possible oversights) .

 I have hundreds more questions but I need to keep myself organized and I'm
 sure as this list picks up alot of them will be answered. I look forward
to
 chatting with you folks.

 Also since I'm at it if your looking for free/confidential counseling to
 starting your business check out www.score.org and www.sba.gov. These are
 both government programs or agencies so I didnt get payed to say that.

 cheers,
 Cordain Lucas
 Dulles, VA




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Re: [biofuel] CMS Paragon mini turbine

2001-05-29 Thread david e cruse

Hi David R.,
   Thanks for the info. Off the topic of
miniturbines---What is the best way to figure the
cost per gallon of the biodiesel you make, is there a
general formula or do you have to figure down to
the smallest expense you incur , and tally everything up,
and then do an average on the whole thing ?
Just wondering !

David C.
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, May 28, 2001 7:06 PM
Subject: [biofuel] CMS Paragon mini turbine


 Hi David C and others who are interested,
 Just received
the following reply re Paragon mini turbine.
 B.r.,  David


 Mr Reid:

 As EPI is currently testing our first unit at a land fill site in New
 Jersey, firm technical data and costs will not be available until such
time
 as testing is complete and we are moving toward full production. We can
only
 predict that this will occur sometime this year. It is our intent to test
 our (CMS) field unit in Canada on a flare gas application.

 Thank you for your interest.

 Kyle King
 Canadian Microturbine Systems




 David  Reid wrote:
 Jim,
   Would like some more info on your Paragon series Micro Turbine at
   some point (no hurry) including indicative prices. Thanks.
 Best regards, David Reid
 [EMAIL PROTECTED]
 78 Wade River Rd, Whangaparaoa, Auckland 1463, New Zealand
 --
   Jim Fiddler -- [EMAIL PROTECTED]




 [Non-text portions of this message have been removed]


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Re: [biofuel] French Fry Fuel - Associated Press/ABC Article

2001-05-24 Thread david e cruse

Hi Jerry,
   The price of diesel here in Georgia  USA
is  $1.30 9/10  to  $1.39 9/10  right now. I travel
the Interstate hwy every day so I see a lot of truckstops,
I`ll be glad to keep the prices posted if it will help.
 David Cruse
- Original Message -
From: jerry dycus [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 24, 2001 6:38 AM
Subject: Re: [biofuel] French Fry Fuel - Associated Press/ABC Article


   Hi Ed and All,
 100% biodiesel costs between $.30 and $1.40 a
 gal to make depending on your source of feedstock.
 Heating oil, slightly better grade of diesel
 sells in the $.75 / $.80 a gal on the spot market now.
   As many biodiesel makers get their feedstock for
 almost free biodiesel would cost about the same as
 diesel if there was enough supply.
Adding 10/20% biodiesel to diesel shouldn't
 raise the price much if at all.
 Taxes not included, YMMV.
jerry dycus
 --- NBT -  E. Beggs [EMAIL PROTECTED]
 wrote:
  Three Times the Price
 
  Because biodiesel costs three times as much as
  regular diesel, adding
  biodiesel even in small amounts raises the cost of
  the fuel by several cents
  per gallon. It was selling in Sparks for $1.62 per
  gallon. 
 
  What's the average price of diesel in Nevada at this
  time...anyone know? 54
  cents a gallon?
 
  Ed B.


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Re: [biofuel] The MN Way

2001-05-18 Thread david e cruse

Hi  Dana   Ed,

Here are some of the current microturbine websites:
www.microturbine.com  this is the Capstone Corp. site
www.honeywell.com  this is the Honeywell/Allied Signal
site, they sell the Parallon 75 microturbine.
www.ingersoll-rand.com  they have a good lineup and
are adding more in the near future.
www.iesl.com  these folks are distributors for Elliot
microturbines, Elliot has a 45kw unit at present and are
adding an 80kw and 200kw unit soon, before the year
is out.
www.bowmanpower.co.uk  these folks will have a unit out
soon also.
www.cmspower.com  these folks are in Canada and have
by far what will be one of the best if not the very BEST
unit to hit the market before years end.  Their opening
shot will be a 500kw microturbine featuring a disk turbine,
it will have a 20 year life span and can be rebuilt with
less than 20 off the shelf components, first maintenance
will be at 5 years and that will consist of changing fluids
and that`s it. It will have an unheard of for a microturbine
top rpm of 3600 rpm. With more units with higher
kw ratings to follow soon, all in all I would say they look
pretty impressive !!
- Original Message -
From: NBT - E. Beggs [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 17, 2001 11:29 AM
Subject: Re: [biofuel] The MN Way


 Who had the info on building experimental from automotive turbochargers?
 Steve? Saw it somewhere, used for R/C model helos, I think.

 Anyway, Capstone is building and shipping. Don't know cost. Anyone have
the
 link for them?

 Ed B.




 - Original Message -
 From: Keith Addison [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Thursday, May 17, 2001 7:12 AM
 Subject: Re: [biofuel] The MN Way


  Keith,
  
  Mn has no energy resources save for wind, sun,and bio.
  We also have very long cold winters that give each MN
  citizen an annual and unavoidable high energy bill.
  
  However, in honor of Pres. Bush Jr. visit we also had
  a rolling blackout 3 days ago that shut down some
  schools and businesses in the southern part of the
  state.
  
  Can you give me a little more information on
  microturbines?
  
  Thanks,
  Dana
 
  Hi Dana
 
  Not my strong point, got some (necessary) learning to do there. Maybe
  Steve Spence can help you though.
 
  Sorry!
 
  Keith Addison
  Journey to Forever
  Handmade Projects
  Tokyo
  http://journeytoforever.org/
 
 
 
 
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Re: [biofuel] Misinformation and Scare Tactics

2001-05-18 Thread david e cruse

OK folks,

Jimmy only had one term in office, but by
golly he gave it his best shot. Ronald the raygun
tried to wipe out everything Jimmy started and
darn near suceeded. For a peanut farmer Jimmy
did pretty good and is still a good man .

Another Georgia boy,
David Cruse
- Original Message -
From: doctor who [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 17, 2001 8:46 PM
Subject: [biofuel] Misinformation and Scare Tactics



 Please feel free to distribute this, but please keep the link and author
 attached. This article copyright THE  washingtonpost.com and the normal
 jibberish here.

 reagards,
 cordain
 --

 http://washingtonpost.com/wp-dyn/articles/A37159-2001May16.html

 Misinformation and Scare Tactics

 By Jimmy Carter
 Thursday, May 17, 2001; Page A23
 It has been more than 20 years since our country developed a comprehensive
 energy policy. It is important for President Bush and Congress to take
 another look at this important issue, but not based on misleading
statements
 made lately by high administration officials. These comments have
distorted
 history and future needs.

 I was governor of Georgia during the administration of Richard Nixon, when
a
 combination of oil shortages and an OPEC boycott produced a real energy
 crisis in the United States. Five years later, the Iran-Iraq war shut off
4
 million barrels of the world's daily oil supplies almost overnight, and
the
 price of energy more than doubled in just 12 months. This caused a wave of
 inflation in all industrialized countries and created energy shortages. As
 before, there were long lines of vehicles at service stations, with
drivers
 eager to pay even astronomical prices for available fuel.

 No energy crisis exists now that equates in any way with those we faced in
 1973 and 1979. World supplies are adequate and reasonably stable, price
 fluctuations are cyclical, reserves are plentiful, and automobiles aren't
 waiting in line at service stations. Exaggerated claims seem designed to
 promote some long-frustrated ambitions of the oil industry at the expense
of
 environmental quality.

 Also contrary to recent statements by top officials, a bipartisan Congress
 worked closely with me for four years to create a well-balanced approach
to
 the problem. No influential person ever spoke exclusively of
conservation,
 and my administration never believed that we could simply conserve or
 ration our way out of any energy crisis. On the contrary, we emphasized
 both energy conservation and the increased production of oil, gas, coal
and
 solar energy. Permanent laws were laboriously hammered out that brought an
 unprecedented commitment to efficient use of energy supplies. We mandated
 improved home insulation, energy savings in the design of industrial
 equipment and home appliances and a step-by-step increase in gas mileage
of
 all automobiles manufactured in our country.

 When I was inaugurated, American vehicles were averaging only 12 miles per
 gallon. Today, new cars reach more than twice this gas mileage, which
would
 be much higher except for the failure to maintain the efficiency
standards,
 beginning in the Reagan years. (Gas mileage has actually gone down during
 the past five years.)

 Official statistics published by the departments of energy and labor
reveal
 the facts: Since I signed the final energy bills in 1980, America's gross
 national product has increased by 90 percent, while total energy
consumption
 went up only 26 percent. Our emphasis on coal and other sources of energy
 and improved efficiency has limited petroleum consumption to an increase
of
 only 12 percent. During this time, non-energy prices have risen 2 1/2
times
 as much as energy prices, and gasoline prices have actually declined by 41
 percent, in real terms and even including the temporary surge in the past
 two years.


 Although these energy conservation decisions have been criticized as a
sign
 of [my] personal virtue, it is clear that the benefits have resulted from
a
 commitment to improved technology, with extremely beneficial results for
 American consumers, business and commerce. Top executives in the oil
 industry should acknowledge their tremendous freedom to explore, extract
and
 market oil and gas products that resulted from the decisions made by
 Congress during my term in Washington.

 In fact, our most difficult legislative battle was over the deregulation
of
 oil and gas prices, designed so that competitive prices would both
 discourage the waste of energy and promote exploration for new sources of
 petroleum products. At the end of 1980, every available drilling rig in
the
 United States was being utilized at full capacity, and dependence on
foreign
 imports was falling rapidly.

 Despite these facts, some officials are using misinformation and scare
 tactics to justify such environmental atrocities as drilling in the Arctic
 National Wildlife Refuge. The Alaska National 

Re: [biofuel] Re: Misinformation and Scare Tactics

2001-05-18 Thread david e cruse

Hi Andrew,

Thanks for the compliment on Jimmy.
Yeah he was definitely a whiz kid !

David Cruse
- Original Message -
From: [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 17, 2001 5:50 PM
Subject: [biofuel] Re: Misinformation and Scare Tactics





 --- In [EMAIL PROTECTED], david  e  cruse [EMAIL PROTECTED] wrote:
 snip
  For a peanut farmer Jimmy
  did pretty good and is still a good man .
 

 Jimmy is a great man, but you know the whole peanut farmer thing,
 although true, has always been a PR thing to make him appeal to the
 common man. The man has a PhD in AstroPhysics.

 -andrew


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Re: [biofuel] The MN Way

2001-05-18 Thread david e cruse

Hi David R.,
Just kidding about the honey :-). I have heard a
lot about manuka honey, but not the others you mention.
The mites are a problem everywhere I hear. I know you are probably right
about the price on the CMS unit, but let me
know when you get any info.
Thanks,
David Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 17, 2001 10:23 PM
Subject: Re: [biofuel] The MN Way


 Hi David,
Thanks. Have sent them an e-mail saying I wouldnt  mind
some
 information and an indicative price in due course but no hurry. Dont think
 it will be too cheap somehow.
 O.T.We certainly had some of the best honey in the world here and there
was
 a multimillion dollar business exporting queen bees all over the world
 particularly to the northern hemisphere because we had none of the
diseases
 that most northern hemisphere countries have until last year until the
 varroa bee mite was introduced either accidentally or deliberately. The
 feeling is that it may have been deliberate but without any smoking gun
who
 is to say. I have just opened the local paper which has just been
delivered
 asI came in and there on the front page is an article titled Feeling sting
 of varroa bee mite.
 Some of our native flora honeys are delicious with ones like manuka having
 very strong proven anti-viral and other health benefits. As a result the
 price for this type of honey has hit the roof in comparison to what it
used
 to be with most going to health food pharmacy shops overseas.  If you get
a
 chance try it and I am sure you will really enjoy it.(a liquid honey so
very
 different to a lot of white clover honey which tastes as if it has wax in
it
 by comparison. Red clover is a lot better. Others that are really nice are
 Pohutakawa (our native Xmas tree which grows round the coast with dark
green
 leaves and which flowers with a bright red flower right on Xmas. Very
 beautiful) and Rata (another native that starts out as a vine in the bush
 proper being a saphrophyte and which turns into a massive tree, again with
a
 flower very similar to Pohutakawa Travelling around NZ in the bush areas
 around Xmas time again, although this one flowers for a much longer time,
 one is impressed by the sheer beauty of these. There is quite a number of
 honey gift packs made up of various honeys available and they are sent all
 over the world.

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Friday, May 18, 2001 10:22 AM
 Subject: Re: [biofuel] The MN Way


  Hi David R.,
 
  Nothing yet on the price David. I think their plans
  are for the fourth quarter, if they don`t make that date
  it will be spring 2002. It would be an extremely good
  unit to go with biodiesel as the fuel. What`s amazing
  about the whole thing is that the entire unit is being
  built with widely and readily available on the shelf
  components ! Got to hand it to those UK chaps
  from Canada, a real sharp bunch ! Must be those
  Northern Lights . I have to say also that they have
  the best honey in the world so far ! I haven`t had any honey from New
  Zealand yet and I hear the bees there make
  a great honey.
 
  David C.
 


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Re: [biofuel] Revised reactor schematic ver1bMa

2001-05-17 Thread david e cruse

Hi  Ian,

Excellent work ! Your efforts are greatly appreciated !

David Cruse
- Original Message -
From: ian [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 16, 2001 5:15 PM
Subject: Re: [biofuel] Revised reactor schematic ver1bMa


 sorry, heres the link
 http://www.hammaskeep.demon.co.uk/reac1bMa.gif
 - Original Message -
 From: ian [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Wednesday, May 16, 2001 9:57 PM
 Subject: [biofuel] Revised reactor schematic ver1bMa


  This is a new revised layout with some changes ive made to my own
system.
  Ive also included the methoxide mixing tank.
  Again this is still beta format.
  Anyone using this schematic as a guide to helping build a system, I give
 no
  gaurantees as to its effectiveness.
  So, if you get squirted with something nasty, its not my fault ;)
  Ive saved it as a gif this time, remeber (sorry got a cold) if you want
to
  print it use landscape and fit to printer, in printer options.
  Ian
 
 
 
  [Non-text portions of this message have been removed]
 
 
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Re: [biofuel] step by step schematic of 2 stage biod process

2001-05-12 Thread david e cruse

HI  Ian,

Well you`ve really done it this time ! It is absolutely
fantastic ! A Gold Star effort without a doubt.

David Cruse
- Original Message -
From: ian [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, May 11, 2001 5:57 PM
Subject: [biofuel] step by step schematic of 2 stage biod process


 Here is a step by step sequence of my tank in action using the Alecs Kac 2
 stage process.
 http://www.hammaskeep.demon.co.uk/2stage.jpg
 It can be used in other ways.
 You'll notice on schematic
 react1a.jpg -http://www.hammaskeep.demon.co.uk/react1a.jpg  I have
installed
 a drying holding tank, this frees up the system to keep on producing. The
 process is the same.
 Ian
 NB its a 400k download


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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  Keith  and  Terry  at  Biofuels  and  Aleks  if  you`re
out  there,

Forget  the  lipase  thing  I  brought  up  and  take
a  look  at  this  at  www.delphion.com ,
WO 00/05327.  This  is  the  process  I  was  looking
for  to  begin  with.  There  are  references  to  it
all  over  the  web.  It  says  that  a  wide  range  of  both
liquid  and  solid  catalyst  can  be  used  and  it  tells
what  can  be  used  as  a  solid  catalyst  and  how
to  use  it!  This  may  be  one  of  those  that  is  too
difficult  to  do  things .  Maybe  Aleks  could  make
it  a  practical  process  to  do.  They  mention  a
device  called  a  product  separator  and  using
temperature  and  pressure  in  the  process  so
anyway  please  give  it  a  look  you  guys.  After  all
is  said  and  done  it  sounds  like  a  way  all  of
us  could  make  use  of ,  if  it  could  be  worked  out.
I  can`t  think  of  who  suggested  delphion  at  the
moment,  I  think  it  was  Ed  I`m  not sure,  but
anyway  thank  you  whoever  it  was.

David  Cruse
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, May 05, 2001 3:21 PM
Subject: [biofuel] Re: Enzymes


 Biofuels [EMAIL PROTECTED] wrote:

 Nice link to patent.
 Appears, at first reading, to confirm my suspicions -
 1.  Enzymes are too specific to be of any use if transesterifying used
 oils/fats
 2.  Process is very labour intensive
 3.  Process is not cost-effective
 
 Anyone think different?

 Hi Terry

 That's my impression too, but I'm rather waiting for some results
 from Aleks. He's been quiet though, maybe he's on holiday. I reckon
 if there's an effective way of doing it, Aleks'll find it. He was
 certainly determined, got the bit between his teeth.

 David Cruse, you're doing right well, please keep it up. I suggest
 you do a search for lipase in the list message archives, you'll
 find quite a lot:
 http://groups.yahoo.com/group/biofuel/messages

 This, for instance:

 A small quantity of porcine lipase can be purchased from Worthington
 http://www.worthington-biochem/com/priceList/L/Lipase.html for US$21.
 There is also some good info at
 http://www.worthington-biochem/manual/L/PL.html

 Best

 Keith Addison
 Journey to Forever
 Handmade Projects
 Tokyo
 http://journeytoforever.org/




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Re: [biofuel] using glycerol as BD extender!

2001-05-07 Thread david e cruse

Hi  Michael,

Didn`t  see  your  post  before  I  made  my
reply  to  Keith  and  Terry.  If  you  have  time
and  it  sounds  like  you  have  some  nice
equipment;  take  a  look  at  www.delphion.com
under  biodiesel  at  WO 00/05327  and  see
what  you  think.

David  Cruse
- Original Message -
From: Michael Aereboe [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 5:55 AM
Subject: [biofuel] using glycerol as BD extender!


 well these patent searches are really interesting.

 heres an example where glycerol is derivatised further under acidic
conditions to form glycerol ethers and adds favourable properties to BD as
well as using the glycerol as fuel!  uNFORTUNATELY THE ETHERIFICATION OF
GLYCEROL IS DONE AT 80c/320 PSI.

 I HAVE A 10 MM stainless steel pressure vessel (100 l) with heating mantel
and pressure dome so at some point i may get around to looking into this.


 TX  MIKE.

 EXAMPLE

 As a practical example of the described process, it is to be understood
that approximately 137.5 lbs/hr of soy oil, 40 lbs/hr methanol and 0.1775
lbs/hr of sodium hydroxide can be entered to continuously stirred tank
Reaction unit (1) which is operated at 20 psig and approximately 80 degrees
centigrade. Said conditions providing essentially 100% conversion of entered
triglycerides to fatty acids and methyl esters. Phase separation in
Separator unit (2) provides methyl esters in an upper location, and a
mixture of glycerol and approximately 10-15 wt % residual methyl esters,
methanol and base at a lower location. Approximately 14 lbs/hr of glycerol
phase is then neutralized, present methanol flashed off, and the results
sent to a continuously stirred Reaction unit (5) which is operated at 80
degrees centigrade and 320 psig. Said Reaction unit (5) also has present
therein approximately 4 wt % Amberlyst-15 catalyst with a residence time of
2 hrs. Approximately 17.5 lbs/hr isobutylene is also fed to Reaction unit
(5). Said conditions provide for the following approximate flow stream (K)
composition, in (wt %):


 __
 TRI-   MONO-   ISO-METHYL-
   ETHER DIETHER ETHER GLYCEROL BUTYLENE ESTERS
 __
 9%47%  21% 5%  14% 4%
 __


 The flow stream (K) is then caused to pass through Flash unit (6) and
Extraction unit (7) such that diethers, triethers, methyl esters and trace
monoethers are formed into flow stream (O) and added back to the bulk
methyl esters present in flow stream (F) to provide the present invention
Biodiesel fuel. The final product Biodiesel fuel is produced at
approximately 145 lbs/hr and consists of approximately, (in wt %):


 __
 ETHERS   METHYL ESTERS
 __
 12%  88%
 __


 Said produced Biodeisel has a kinematic viscosity of 5.94 cst at 70
degrees Fahrenheit and a Cloud-point of 23 degrees Fahrenheit, which is a
greater than 0.5 cSt reduction in viscosity and 9 degree Cloud-point
depression compared to Biodiesel without glycerol ethers present.

 Briefly, the present invention process then comprises providing
Triglycerides which are reacted in a liquid phase reaction with methanol and
a homogeneous basic catalyst, said reaction yielding a spatially separated
two phase result with an upper located non-polar phase consisting
principally of non-polar methyl esters and a lower located phase consisting
principally of glycerol and residual methyl esters. At least the glycerol
phase, is passed through a strong cationic ion exchanger to remove anions,
resulting in a neutral product which is flashed to remove methanol and which
is reacted with isobutylene in the presence of a strong acid catalyst to
produce glycerol ethers. The glycerol ethers are then added back to the
upper located methyl ethyl ester phase to provide an improved present
invention biodiesel fuel.

 Turning now to FIGS. 2a-2c there is shown details of a specific Heat
Exchange/Reactor unit. As mentioned infra herein, the Transesterification
unit (1) can consist of one or more, (up to hundreds or even thousands),
heated tube(s), each optionally containing a static mixer (SM) configured as
shown in FIGS. 2a-2c. FIG. 2a shows a side cross-sectional view indicating
the presence of Feed Tubes (FT), and Feed-In means for entering Triglyceride
(A), Base (NaOH, KOH etc.) (B) and Methanol (C) streams thereto. Also
indicated are Steam/Heating-Fluid entering means, and Steam/Heating
Fluid-Out and Product-Out means. FIG. 2b shows an elevational end-on view,
and FIG. 2c shows a detail of a single Feed Tube (FT) within which is
present a Static Mixer (SM). In use triglycerides are caused feed-In Feed
Tubes (FT) at said Feed-In means, and steam or heating fluid is caused to
flow over the Feed-Tubes, to the end that the 

Re: [biofuel] ENERGIES... week of 4/29/01

2001-05-07 Thread david e cruse

Hi  B.  Mulliken,

All  fuel  cells  that  I  have  seen  on  the  market
so  far  are  reformers  and  what  they  reform
is  a  fossil  fuel  such  as  natural  gas,  methanol,
( methanol  from  synthesis  of  fossil  fuel  such as
natural  gas), and  other  unpleasant  fossil  derived
things!  Plug  Power  is  a  major  player  here  in
Georgia,US .  They  cut  a  deal  with  Flint  Energies
to  be  their  exclusive  provider  of  fuel  cells in
100  of  159  counties  in  Georgia.  And  wouldn`t
you  just  know  it,  you  have  to have a  natural  gas
line  to  your  house  to  get  one  of  the  things !!
How  convenient  for  Flint  Energies ! Lets  all
give  a  big  round  of  applause  for  Flint  Energies,
they  are  so  thoughtful  and  green  ha  in  a pigs
eye !
As  I  said  so  far  all  I`ve  seen  are  fuel  cells
that  reform  some  sort  of  fossil  derived
electrolyte.  Gasoline and  diesel  using  fuel  cells
are  being  worked  on  also, and  they  can  use
propane  also. They  say  that  a  fuel  cell  using
just  plain  water  as  the  electrolyte  is  to  hard
to  mass  produce ( they  have  them  in  the  space  shuttle ),  so  your
choices  are  being  defined
by  the  big  petroleum  boys  once  again !!

David  Cruse
- Original Message -
From: [EMAIL PROTECTED] (by way of Keith Addison)
[EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 2:29 PM
Subject: [biofuel] ENERGIES... week of 4/29/01


 ENERGIES... week of April 29 2001,

  HUNDREDS OR MILLIONS? In the U.S., Vice President Dick Cheney stated
 that the nation needs to build 1300 -1900 large-scale power plants
 during the next 20 years.  Clean coal and nuclear has been suggested.
 An additional option, aside from building more large-scale renewable
 generation facilities, would be a national effort to bring small-scale
 power generation into homes and businesses.
  Distributed and home power systems - fuel cell, solar, wind, or
 clean combustion - could be environmentally clean, provide reliable
 power and create new business opportunities for equipment manufacturers,
 installers and, depending on the technology, fuel suppliers. Individual
 home and business power plants would lessen the demand on the grid, so
 fewer large power plants would need to be built. Instead of building
 hundreds large-scale facilities maybe we need millions at a much smaller
 scale.
  Companies are rapidly developing power plants for home use.
 IdaTech, a division of IDACORP has delivered a 3 kilowatt fuel cell
 power plant to the Research and Development Division of Electricite de
 France (EDF). The small cogenerator was developed to supply all the
 electricity - plus heat - for the average single-family home.
  The fuel for this particular unit is methanol, but future models are
 being designed to run on natural gas, propane, diesel and other
 conventional fuels.  Methane, the common waste gas from all homes, is
 also possible, though not mentioned by IdaTech.
  Commercialization of IdaTech's home fuel cell is aimed for 2003.
 EDF would possibly become a distributor at that time. Visit IdaTech at
 http://www.idatech.com/ .

  HYDROGEN EVERYWHERE. Not surprisingly most major oil companies have
 shown an interest in hydrogen fuel cells for vehicles. They control the
 fuel and fueling infrastructure for cars and trucks and, naturally,
 would like to continue in that position by selling hydrogen extracted
 from fossil fuels. Yet hydrogen is everywhere on the planet, though in
 nature the single proton is almost always bonded to other atoms.
  Millennium Cell has announced that initial testing with
 DaimlerChrysler of its Hydrogen on Demand (tm) system for automotive
 applications has been completed successfully. Hydrogen on Demand
 eliminates the need for hydrogen storage since it is produced as needed
 by the fuel cell. The Millennium Cell process is to collect hydrogen
 released from the reaction of water and sodium borohydride. When the two
 are combined in the presence of catalyst, hydrogen or electricity is
 produced. Electricity can be used directly. Hydrogen would fuel a fuel
 cell or be fed into a combustion engine.
  Sodium borohydride is a derivative of borax. Fossil fuels are not
 needed with this technology, which if proven viable would not be met
 warmly by the old-guard oil industry. Visit Millennium Cell at
 http://www.millenniumcell.com/ .

  WIND WATCH. After one Danish energy expert predicted this week that
 wind energy would supply 10 percent of the world's energy demands in 20
 years,  shares for Vestas Wind Systems and NEG Micon shot skyward. The
 expert claimed that the wind energy industry in Denmark could be akin to
 the busy automobile industry in Germany and France.
  Vestas announced it will be selling 123 V-47 660 kilowatt turbines
 to the Sadid Industrial Group in Iran along with the know-how for the
 local construction of towers and turbine blades. 

Re: Ginosar Model was Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  Todd,

You`re  right .  But  they  do  give  a  list  of
the  solid  inorganic  oxides  which  are  among
those  used  in  the  process  described  in
claim  8 .  Maybe  someone  among  us  can
help  with  this  stuff.  I`m  going  to  talk  to  two
of  my  friends  here  who  have  some  knowledge
of  this  sort  of  chemistry.  If  that  don`t  work
I`ll  think  of  some  other way.  It  can  be  unraveled.
The  benefits  are  just  too  good  not  to  try .

David  Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 4:41 PM
Subject: Ginosar Model was Re: [biofuel] Re: Enzymes


  This is the famous Fox/Ginosar process - but they won't tell anybody
what
  the permanent catalyst is!
 ..

 Could be a Lewis acid or base or similar such - solids which act as acids
at
 high temps. They are descriptive of higher heat and pressures.

 Todd
 Appal Energy
 [EMAIL PROTECTED]




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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  David  R..

I  guess  one  of  those  will  cost  about  a
few  thousand  or  so,  but  I  do  like  this
one  over  the  lipase  deal.  Anyway  I`m
hoping  that  it  could  work  for  us  all  and
open  up  a  better  way. I`ll  try  to  find  out
if  the  equipment  can  be  put  together  for
a  reasonable  amount. I  have  a  catalogue
from  a  chem/ equip  house, and  there  is
a  lot  on  the  web.


- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 4:33 PM
Subject: Re: [biofuel] Re: Enzymes


 David C,
   Have just looked at the abstract at this point but suspect
 they may mean a centrifugal separator such as an Alfa Laval or Sharples at
 this point.
 B.r., David

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Monday, May 07, 2001 3:22 AM
 Subject: Re: [biofuel] Re: Enzymes
 They  mention  a
  device  called  a  product  separator  and  using
  temperature  and  pressure  in  the  process  so
  anyway  please  give  it  a  look  you  guys.


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Re: [biofuel] ENERGIES... week of 4/29/01

2001-05-07 Thread david e cruse

Hi  Keith,

That`s  a  trade  secret!!  You  know  I
was  thinking  the  same  thing  about  the  fuel  cells.
Of  course  they  will  never  think  of  it,  they  have
been  breathing  petrol  fumes  to  long  and  are
hopelessly  addicted.

David  Cruse
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 4:24 PM
Subject: Re: [biofuel] ENERGIES... week of 4/29/01


 Hi David

 Hi  B.  Mulliken,

 He ain't there - I get this newsletter and usually forward it to the list.

 All  fuel  cells  that  I  have  seen  on  the  market
 so  far  are  reformers  and  what  they  reform
 is  a  fossil  fuel  such  as  natural  gas,  methanol,
 ( methanol  from  synthesis  of  fossil  fuel  such as
 natural  gas), and  other  unpleasant  fossil  derived
 things!

 Yep.

 Plug  Power  is  a  major  player  here  in
 Georgia,US .  They  cut  a  deal  with  Flint  Energies
 to  be  their  exclusive  provider  of  fuel  cells in
 100  of  159  counties  in  Georgia.  And  wouldn`t
 you  just  know  it,  you  have  to have a  natural  gas
 line  to  your  house  to  get  one  of  the  things !!
 How  convenient  for  Flint  Energies ! Lets  all
 give  a  big  round  of  applause  for  Flint  Energies,
 they  are  so  thoughtful  and  green  ha  in  a pigs
 eye !
 As  I  said  so  far  all  I`ve  seen  are  fuel  cells
 that  reform  some  sort  of  fossil  derived
 electrolyte.  Gasoline and  diesel  using  fuel  cells
 are  being  worked  on  also, and  they  can  use
 propane  also. They  say  that  a  fuel  cell  using
 just  plain  water  as  the  electrolyte  is  to  hard
 to  mass  produce ( they  have  them  in  the  space  shuttle ),  so
your
 choices  are  being  defined
 by  the  big  petroleum  boys  once  again !!

 Absolutely right. Nonetheless, the gasoline/diesel bit is interesting
 - if they can use diesel, can they use biodiesel? If they can use
 gasoline, can they use bioethanol?

 By the way, David, you've got me really puzzled - how DO you get two
 spaces in between each word??

 Best wishes

 Keith Addison
 Journey to Forever
 Handmade Projects
 Tokyo
 http://journeytoforever.org/



 David  Cruse
 - Original Message -
 From: [EMAIL PROTECTED] (by way of Keith Addison)
 [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Sunday, May 06, 2001 2:29 PM
 Subject: [biofuel] ENERGIES... week of 4/29/01
 
 
   ENERGIES... week of April 29 2001,
  
HUNDREDS OR MILLIONS? In the U.S., Vice President Dick Cheney
stated
   that the nation needs to build 1300 -1900 large-scale power plants
   during the next 20 years.  Clean coal and nuclear has been suggested.
   An additional option, aside from building more large-scale renewable
   generation facilities, would be a national effort to bring small-scale
   power generation into homes and businesses.

 snip

  
 Visit Green Energy News on the Web at http://www.nrglink.com/ . For
   free ENERGIES subscription contact [EMAIL PROTECTED] Copyright
   Green Energy News Inc. 5/5/01 vol.6 no.5


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Re: [biofuel] ENERGIES... week of 4/29/01

2001-05-07 Thread david e cruse

Hi  Terry,

Don`t  know  that  one.  But  heard  many  times
that  their  fuell  cells  use  plain  water.
They  have  probably  developed  more  technology
with  the  solar  panels.  I  don`t  go  to  the  NASA
site  too  often,  and  there  are  other  space  tech
sites  I  don`t  check  in  too  often.  You`re
probably  right.

David  Cruse
- Original Message -
From: Biofuels [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 3:58 PM
Subject: Re: [biofuel] ENERGIES... week of 4/29/01


 Doesn't the fuel cell in the shuttle use energy from the solar panels to
 produce the electricity to produce the hydrogen to produce the
electricity?
 We could do that down here.
 If we had enough room.


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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  David  R.

Distillation does seem to be the way, the
Gen. Mgr. at OAE says that`s the way they use,
and they have a million gals. a yr. !

David Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 5:41 PM
Subject: Re: [biofuel] Re: Enzymes


 Points to start and research:
 (From the Woollatt book but remember published 1985).

 Bleaching and the treatment of Distillates with ion-exchange resins to
 upgrade quality :
 initial bleaching with 0.2-2.0% activated carbon
 ion-exchange resins from Rohm and Haas instead of or after a.c.
 [Macrorecticular resins (which have large discrete pores capable of
removing
 relatively large molecular mass compounds from the liquid) are normally
best
 for this duty which demands the removal of organic, rather than ionic,
 impurities ]. Sound ideal in this instance to me.
 eg: Amberlite 200 or 200C - strong cation resin  .
  Amberlite IRA-93 - weak base anion resin.
  Amberlite IRA-900 - strong base anion resin
 Deodorization, using heat and open steam, under vacuum, following
treatment
 often necessary.

 Production of refined grades of glycerine without distillation:
 Ion exclusion: process developed by Dow Chemical Co and reviewed in paper
by
 D'Souza (1979) using a bed of granular resin such as Dowex WX8 allowed
 partial purification which could then be completed by ion-exchange.
 Ion-exchange process sounds okay but regeneration using hydrochloric or
 sulphuric acids for the cation resins and caustic soda for the anion resin
 dosnt sound really feasible or realistic for a small plant. Would also not
 be economic I believe.
 Lever Bros installed a plant in L.A. designed by Illinois Water Treatment
Co
 in 1951 but would seriously doubt this was still in operation. Dosnt sound
 too promising. Distillation still seems to be the preferred method.
 Reverse Osmosis also dosnt sound too promising although there could have
 been developments in the last 15 years.
 Refs: Sourirajan and Kimura (1967), review Sourirajan and Matsuura (1982).
 B.r.,  David

 - Original Message -
 From: Biofuels [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Monday, May 07, 2001 7:51 AM
 Subject: Re: [biofuel] Re: Enzymes


  This is the famous Fox/Ginosar process - but they won't tell anybody
what
  the permanent catalyst is!
  I do know it involves polymers, but that is all.



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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  David  R,

Cool !  A  cream  separator , ok.

David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 6:03 PM
Subject: Re: [biofuel] Re: Enzymes


 Hi David C,
   A good quality Alfa Laval cream separator might do the
 majority of it and you might then be able to ship it to a more central
point
 for ion-exchange resin treatment and distillation or whatever is required.
 B.r.,  David

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Monday, May 07, 2001 9:10 AM
 Subject: Re: [biofuel] Re: Enzymes


  Hi  David  R..
 
  I  guess  one  of  those  will  cost  about  a
  few  thousand  or  so,  but  I  do  like  this
  one  over  the  lipase  deal.  Anyway  I`m
  hoping  that  it  could  work  for  us  all  and
  open  up  a  better  way. I`ll  try  to  find  out
  if  the  equipment  can  be  put  together  for
  a  reasonable  amount. I  have  a  catalogue
  from  a  chem/ equip  house, and  there  is
  a  lot  on  the  web.



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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi  David R.,

I  agree, glycerol is an opportunity for everyone
to offset some expenses if not make a good profit for the effort. Better
green folks than the big corporate
types, and besides that with a little economic muscle
among the green, we could bring some impact
to the market place. I know and you also that
they have the advantage, but the sun don`t shine
on the same dog`s ass forever ! And I`m not
about to ever give them an inch under any circumstance,
and I ain`t afraid to try my best!

David Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 6:53 PM
Subject: Re: [biofuel] Re: Enzymes


 Hi David,
   Most of the modern synthetic glycerine plants seem to be
based
 on technology similar to the original Shell process based on propylene.
 Woollatt in his book says: Considerable problems were experienced
 initially, particularly as regards purification, but the quality of modern
 synthetic glycerine is very high. Indeed, refiners of natural glycerine
have
 sometimes found it difficult to match. Perhaps this opens up another
avenue
 of research and there may be aspects of the modern technology that could
be
 easily applied to the refining of natural glycerine in small quantities.
 One of the other comments that Woollatt makes in talking about the
 manufacture of synthetic glycerine being outside the scope of this book
is:
 but it can be said that the natural material should always be able to
 compete. He points out because glycerol must be released when fats are
 saponified, or split,  the marginal cost of recovering it is likely to be
 below the cost of making the synthetic equivalent. In this respect I
 believe the rapidly emerging and expanding Biodiesel industry has a golden
 opportunity in its hands which can do nothing but make the product more
 viable.
 Perhaps one ot two of you English guys should try tracking Edgar Woollatt
 (Consultant, British Executive Service Overseas and formerly Development
 Manager, Lever Bros Ltd, Cheshire) down. He is probably in his 70s I
imagine
 and may no longer be up with the play but would be a goldmine of
 information. How about you Simon Wells?
 B.r.,  David

  Distillation does seem to be the way, the
  Gen. Mgr. at OAE says that`s the way they use,
  and they have a million gals. a yr. !
 
  David Cruse
  - Original Message -
  From: David Reid [EMAIL PROTECTED]
  To: biofuel@yahoogroups.com
  Sent: Sunday, May 06, 2001 5:41 PM
  Subject: Re: [biofuel] Re: Enzymes



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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hey  Todd,

That sounds great , and would be fantastic ! Thank
you. I am not in a rural area here so we are going
to have to deal with that by either leasing , or
purchasing a couple of acres to put up a facility.
We want to produce power with the biodiesel
as our fuel, that way we can have the electricity
to use, and put on the grid. The vice president of
our local Electric Membership Coop has given
me the assurance that they will give us a purchase
agreement when we are ready. But that is going
to be a rough go getting  everything together in
the right way so it all works without too many
problems. I`m not trying to take too hugh of a
leap by skipping the standard methods that can
be done on a now basis, but the Ginosar method
sounds like a great way to go if possible! I stress
possible!! Otherwise it would be dumb not to
use what works.

Thanks,
David Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 9:56 PM
Subject: Re: [biofuel] Re: Enzymes


Check the patent further. They may also have meant an
  Ion-exchange column separator. I dont know; I only quickly looked at the
  abstract. Sometimes also patents are deliberately confusing so they
cover
  their ass either way. I just think a cream separator might do it quite
 well
  because of the different S.G.s of Biodiesel and Glycerine.
  Todd your input and comments appreciated here.
  B.r.,  David
 ..

 David,

 Appal's chemist and I discussed Ginosar's methodology when we first saw
the
 article last year. That conversation briefly touched on Lewis acids and
 resin coated polymers. We let it lay, as the process was not very real
 world for our limited startup.

 I've forwarded Ginosar's patent location to him and asked him to review
it.
 He has been researching patents continually over the past months and may
 have already stumbled upon it. We'll see.

 Although the topic of moving away from soluble catalyst keeps surfacing,
we
 continue to pursue the traditional method of manufacture with small
scale
 glycerin refining and potassium phosphate recovery. This seems to be the
 best start up method for a micro-facility in an agricultural setting. That
 is unless something like Ginosar's method becomes even remotely available
 before we can reach the next plateau.

 It's not that far of a reach to pursue the solid catalyst method though.
The
 high boiler heat requirement is already present in a plant that is
 distilling glycerin, as is the familiarity with pressure rated systems.

 Let me see what the good Doctor says.

 Todd
 Appal Energy
 [EMAIL PROTECTED]





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Re: [biofuel] Re: Enzymes

2001-05-07 Thread david e cruse

Hi Todd,

Sorry didn`t look before I replied to your message
to David Reid. Anyway I would have sent it
to you anyway.

David Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, May 06, 2001 9:56 PM
Subject: Re: [biofuel] Re: Enzymes


Check the patent further. They may also have meant an
  Ion-exchange column separator. I dont know; I only quickly looked at the
  abstract. Sometimes also patents are deliberately confusing so they
cover
  their ass either way. I just think a cream separator might do it quite
 well
  because of the different S.G.s of Biodiesel and Glycerine.
  Todd your input and comments appreciated here.
  B.r.,  David
 ..

 David,

 Appal's chemist and I discussed Ginosar's methodology when we first saw
the
 article last year. That conversation briefly touched on Lewis acids and
 resin coated polymers. We let it lay, as the process was not very real
 world for our limited startup.

 I've forwarded Ginosar's patent location to him and asked him to review
it.
 He has been researching patents continually over the past months and may
 have already stumbled upon it. We'll see.

 Although the topic of moving away from soluble catalyst keeps surfacing,
we
 continue to pursue the traditional method of manufacture with small
scale
 glycerin refining and potassium phosphate recovery. This seems to be the
 best start up method for a micro-facility in an agricultural setting. That
 is unless something like Ginosar's method becomes even remotely available
 before we can reach the next plateau.

 It's not that far of a reach to pursue the solid catalyst method though.
The
 high boiler heat requirement is already present in a plant that is
 distilling glycerin, as is the familiarity with pressure rated systems.

 Let me see what the good Doctor says.

 Todd
 Appal Energy
 [EMAIL PROTECTED]





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Re: Solid Catalyst was Re: [biofuel] washing bio-diesel

2001-05-05 Thread david e cruse

Hi  Todd,

Just  found  process  using  lipase  enzymes  as
catalyst  to  make  biodiesel .  Makes  glycerol
recovery  easy,  has  minimal  waste  residues,
you  can  recycle  your  catalyst,  and  you  can
use  high  fatty  acid  feedstock,  low  reaction
temperatures,  and  get  a  high  conversion  rate !
I  haven`t  read  all  of  the  text  yet .  I`m  looking
for  the  process  to  use  soap  as  a  feedstock
also.

David  Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, May 05, 2001 12:26 AM
Subject: Solid Catalyst was Re: [biofuel] washing bio-diesel




  Hi  Folks,
 Could  someone  please  tell
  those  of  us  who  don`t  know.  What  do  you
  use  as  a  solid  catalyst ?  And  explain  the
  way  to  use it .
 
  Thanks,
  David  Cruse
 ...

 David,

 There have been trials using non-dissolvable catalysts that are large
enough
 in size to remain in a screened but open container or to filter easily
and
 return to the reaction phase. Such a process would reduce the wash steps
 considerably and yield a less contaminated glycerin.

 Everything seems to be pretty hush hush, as patents and funding are being
 sought. But just around the corner?

 Todd
 Appal Energy
 [EMAIL PROTECTED]



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Re: Solid Catalyst was Re: [biofuel] washing bio-diesel

2001-05-05 Thread david e cruse

Hi  David  R.

Go  to  www.uspto.gov  and  click  on  patents,
click  on  number,  type  in  5,713,965,  leave
out  the  commas,  and  take  a  look !  It`s  a
14 page  document.  You  can  also  click  on
advanced  boolean  search  under  patents  and
enter  biodiesel  and  see  several  other  docs.
One  item  actually  uses  auto  gasoline  as  the
solvent  in  the  process !!
All  of  you  other  folks  out  there  in  our  group
should  take  a  look  also!!! That  is  if  you
haven`t  seen  this  already !  None  of  this  info
gets  out  to  regular  folks,  but  you  can  bet  your
cash  that  the   bigs   know  about  it !!
I  haven`t  researched  the  costs  of  the  lipase
enzymes  yet,  but  that`s  next.

David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, May 05, 2001 1:50 AM
Subject: Re: Solid Catalyst was Re: [biofuel] washing bio-diesel


 David C,
   Do you have a ref or a title?
 B.r.,  David

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Saturday, May 05, 2001 4:59 PM
 Subject: Re: Solid Catalyst was Re: [biofuel] washing bio-diesel


  Hi  Todd,
 
  Just  found  process  using  lipase  enzymes  as
  catalyst  to  make  biodiesel .  Makes  glycerol
  recovery  easy,  has  minimal  waste  residues,
  you  can  recycle  your  catalyst,  and  you  can
  use  high  fatty  acid  feedstock,  low  reaction
  temperatures,  and  get  a  high  conversion  rate !
  I  haven`t  read  all  of  the  text  yet .  I`m  looking
  for  the  process  to  use  soap  as  a  feedstock
  also.



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Re: [biofuel] Ethanol Distillation

2001-05-04 Thread david e cruse

Craig ( Green Bay )

Yes  those  units  will  work  for  methanol/ethanol
recovery  when  you`re  making  biodiesel.  Cost
would  be  your  only  consideration. I  have  seen
the  same  kind  of  equipment  on  other  websites.

David  Cruse
- Original Message -
From: cpech [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 11:54 PM
Subject: [biofuel] Ethanol Distillation


 I have been looking at a product for distilling ethanol (a solvent
recovery unit) and am not enough of an engineer to tell if it will work -
the salesman assures me it will. See the unit at www.rescience.com. His name
is Tome Graves ([EMAIL PROTECTED]).

 Can any of you people tell me more? If it does what they say it will, it
is a HUGE leap forward. He says someone is using it to make ethanol for
mixing biofuel.

 Craig
 Green Bay, WI


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Re: [biofuel] glycerin

2001-05-04 Thread david e cruse

Hi  David  R.,

Hey  if  they  are  that  far  away,  don`t  worry
about  them.  I`ll  get  around  to  the  Mall,  there  is
a  Borders  Book  store  there  and  it`s  not  a
40 k  hike  to  the  place.

Thanks,
David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 03, 2001 9:40 AM
Subject: Re: [biofuel] glycerin


 Nope sorry changed my mind. No seriously will try and remember. Books are
 held by Auckland Public Library (40 km away) so will try to look next time
I
 go into the city if it is open.
 B.r.,  David

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Friday, May 04, 2001 12:21 AM
 Subject: Re: [biofuel] glycerin


  Hi  David R.
 
  Thank  you , I  will  remind  you  later  on.
 
  Thanks  again,
  David  Cruse



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Re: [biofuel] Re: Stainless Steel Tank Sources

2001-05-04 Thread david e cruse

Thanks  k5,

David  Cruse
- Original Message -
From: [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 03, 2001 11:53 AM
Subject: [biofuel] Re: Stainless Steel Tank Sources


 Another source of SS tanks is most dairy farms that no longer produce
 milk(there are millions of them) most had a bulk tank from 500-5000
 gallon capacity, insulated and chillable. Not much of a cash market,
 so the plate of cookies and ya know.



 --- In [EMAIL PROTECTED], david  e  cruse [EMAIL PROTECTED] wrote:
  Hi  Todd,
 
  Thanks  for  the  info  on  the  tanks.
 
  David  Cruse
  - Original Message -
  From: Appal Energy [EMAIL PROTECTED]
  To: [EMAIL PROTECTED]
  Sent: Wednesday, May 02, 2001 8:22 PM
  Subject: [biofuel] Stainless Steel Tank Sources
 
 
   http://www.upe.com/GetSubCat.html/786
  
   http://www.4tank.com/stainless_tanks1.htm
  
   http://www.winetanks.com/
  
  
   [Non-text portions of this message have been removed]
  
  
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   http://journeytoforever.org/biofuel.html
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Re: [biofuel] glycerin

2001-05-04 Thread david e cruse

Hi  David R.

Thanks  again.

David Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 03, 2001 6:16 PM
Subject: Re: [biofuel] glycerin


 David,
   Normally go into the city once or twice a week anyway to get
 supplies and other things so no problem.
 B.r.,  David


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Re: [biofuel] glycerin

2001-05-04 Thread david e cruse

Hi  David  R.

Thank  you  for  taking  the  time, and  I  agree
on  the  small  plant  scenario.  I  will  try  to  get
the  first  book  you  mention  asap.  There  is  some
good  info  at  www.britannica.com . I  started  out
by  just  entering  glycerol, and  that  is  a  short
entry,  three  paragraphs,  but  at  the  bottom  of
the  paragraphs  it  says  * click  here  for  more
info * . That  takes  you  to   soap  and  detergent 
the  third  paragraph  in  that  is  very  interesting
as  it  tells  how  to  separate  the  glycerin  from  the
soap  with  a  saltwater  solution.  If  you  have  time
check  it  out.  The  people  at  www.arserrc.gov
filed  for  a  patent  ( 08/631,498 )  on  4-12-1996
for  a  process  for  Biodiesel  Production with
Lipases  and  they  also  were  working  on  a
process  for   Soapstock  for  Biodiesel  Production .
I  tried  to  find  the  patent  I  mentioned  at
www.uspto.gov  but  couldn`t  locate  it . The
website  says  that  for  a  fee  you  can  get  a  copy
of  the  patents  and  get  a  license  to  use  them.
I  was  very  aggravated  in  not  being  able  to  find
any  more  info!  The  soapstock  thing  sounded
terrific ! I  also  found  that  the  NREL  in  Colorado
also  has  this  technology,  the  process  with  the
lipase  catalyst . I`m  sure  a  lot  of  us  would  like
to  know  the  details  on  both  these  things,
especially  the  soapstock  process !!

David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Friday, May 04, 2001 5:05 AM
Subject: Re: [biofuel] glycerin



 Hi David C,
   Went to town this afternoon and dug out the books on
 Glyceryn. Couldnt find one of the ones I wanted but found the other which
is
 excellent and I would recommend, Dug out 4 books, 2 on Glycerine, and 2 on
 Fatty acids or Fatty Alcohols, which are related topics, especially when
it
 comes to Biod.
 Titles:
 1) The Manufacture of Soaps, Other Detergents and Glycerine by Edgar
 Woolatt. (formerly Development Manager of Lever Brothers).  Published by
 Ellis Horwood Ltd, and Halstead Press, div of John Wiley and Sons 1985,
ISBN
 0-85312-567-8 (EHL) and ISBN 0-470-20234-3. An excellent and thoroughly
 authoritive text.
 2)Glycerine by S.W. Koppe Translated from the German. Published by Scott,
 Greenwood  Son, London 1915
 A really old book I normally would not have bothered with but has some
 interesting chapters titled: Compounds and decomposition products of
 Glycerine, The production of Glycerine,  The Production of Pure Glycerine,
 and Various applications of Glycerine. Had not seen it before as it was
down
 in the basement so will at least have a quick scan of it.

 3) Industrial Fatty Acids and their Applications edited by E. Scott
 Pattison, and published by Reinhold Publishing Corp 1959
 Some good photos and line drawings of commercial operations in the States
 4)Fatty Alcohols, Raw Materials, Methods, Uses. Published by Henkel,
 Dusseldorf, Germany 1982
 Some good compositional data of various oils etc.

 The first one is the one I would look for and you should learn a lot from
 it.
 I believe the successful design and manufacture of a small mobile plant is
 one of the answers to making biodiesel a feasible product worldwide and
 making it viable from an economic point of view. There is a world wide
 demand for high quality glycerine which fetches good prices. Prices for
the
 glycerine could be used to offset shifts in the base raw materials costs.
If
 a small mobile plant could be put out at realistic cost there would be a
 fairly reasonable demand for it. The secret is a cheap energy source as to
 distill glycerine you need temperatures in the range of 500 to 600 degrees
 and you can imagine how consumptive and expensive this can quickly become
at
 this temperature range.
 I have looked into this before and it is beyond me on a personal level as
it
 needs a reasonable amount of input and also a reasonable cash input. I
 believe the answer is design input from half a dozen people or more and
also
 financial input from others.
 Anyone out there interested in forming a design team and anyone interested
 in becoming a financial backer?.
 Hope this is of some help to you and others. The answers are out there,
the
 solution is digging them out and then combining with others to achieve
your
 goal. Keith, Steve, Aleks, Todd, Ed, and others who add their two cents
 everyday and are getting the word out there have moved this industry
forward
 a long way already but it still has a long way to go.
 B.r., David




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Re: [biofuel] glycerin

2001-05-03 Thread david e cruse

Hey  David R.

If  that  message  was  directed  at  me  (David C.)
That  would  be  kind  indeed !

David Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, May 01, 2001 10:18 PM
Subject: Re: [biofuel] glycerin


 Hi David,
Can dig out a couple of good book titles from the library
if
 you give me time.
 B.r.,  David


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Re: [biofuel] glycerin

2001-05-03 Thread david e cruse

Hi  Todd S

Thanks  for  the  info  on  methanol  recovery.
I  found  a  metal  shop  in  my  area  and  the
man  who  owns  the  place  is  skilled  in
stainless  steel  work.  He  gave  me  some  great
prices  on  building  process  tanks, and  building
what  you  described  for  the  alcohol  recovery.
Thanks  again  for  the  help.

David  Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, May 01, 2001 10:50 PM
Subject: Re: [biofuel] glycerin


  I  want  to  know  about
  the  vacuum/ heat  extraction  method  in  more  detail,
  so  if  you  have  some  good  info  I  would  appreciate
  your  help.  I`m  not  sure  what  VOC  output  is
  so  please  fill  me  in  on  that.
 .

 David,

 Vacuum is not necessary for evaporating and distilling the methanol,
either
 the residual in the biodiesel before washing or the residual in the
 glycerin.

 A closed system is, however, to prevent the escape of the toxic and
 flammable fumes.

 It consists of nothing more than a manner to heat the fluid above the
 boiling point of the alcohol, and a water cooled condenser to recover the
 vapor in liquid form.

 Essentially it is the same process for evaporation and condensing
glycerin,
 except that vacuum is used so that not so much heat energy is required.
This
 is where pressure rated tanks and the like enter into play. Just imagine a
 more industrial image than what is in the following paragraph.

 You could probably evaporate the alcohol out of both the biodiesel and the
 glycerin using a fifty five gallon closed head drum, with the 3/4 bung
 plugged, the 2 bung piped into the condenser, the drum wrapped in R-19
 insulation, all sitting on a double burner electric hotplate, or some
other
 non-open-flame heat source.

 I would separate the biodiesel from the glycerin first and then evaporate
 each medium separately - perhaps a separate drum for both to prevent
 glycerin contamination of the fuel/

 You will also need to remove the glycerin from the drum while still warm
or
 reheat it before removal, as it gets rather thick.

 Todd
 Appal Energy
 [EMAIL PROTECTED]



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Re: [biofuel] Farmers seek boost from veggie fuel

2001-05-03 Thread david e cruse

Hi  Ralph,

Hey  that  would  be  great  wouldn`t  it.
I`m  checking  on  what  it  would  cost  to
build  a  500 gal  stainless  mixing  tank.
Regular  diesel  is  selling  for  $1.39 9/10
in  my  area  today  (Atlanta,Ga.).

David  Cruse
- Original Message -
From: Ralph Chamberlain [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, May 01, 2001 11:38 PM
Subject: Re: [biofuel] Farmers seek boost from veggie fuel


 David thanks for your response. I've been checking into the used oil
market and its at an all time glut. It seems that the mad cow disease has
put a hamper on feed market and now the collection companies are charging
the restaurants to pick up their used oils. This could mean a break in the
price to produce biodiesel in the US.

 I've checked the US gov't documents on production costs of biodiesel and
they state that is costs around $0.67 per gallon to produce diesel compared
to $1.00 per gallon to produce biodiesel. The end cost of a 20% blend is
approx. .736? The gov't indicators have stated that the price of diesel will
be $2.00 per gallon in the next few months.

 I want to know if anyone out there has comparative cost projections to
produce biodiesel. If my calculations are correct can we start to look at
full scale production of renewable energy source?

 Ralph Chamberlain


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Re: [biofuel] Conservation may be a virtue... FAO/Politics/Environment/Social

2001-05-03 Thread david e cruse

Hi  Ed,

 Outstanding  ,  right  on  the  money !

Amen,
David  Cruse
- Original Message -
From: NBT - E. Beggs [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 12:57 PM
Subject: [biofuel] Conservation may be a virtue...
FAO/Politics/Environment/Social




 FYI:

 This century has seen the world become a willing captive to an
 unsustainable future. The economically developed world is addicted to high
 energy consumption and global economic development will be reflected by
the
 ever-expanding use of fossil fuels. The predicted growth in world
 population, supposedly peaking somewhere between 8 to 10 billion people
will
 become a critical issue as the less developed countries of the world
develop
 their economies and strive to enjoy their full and fair measure of the
 biosphere's renewable and non-renewable resources...

 Since oil and coal are extracted from earth sources, supplies are finite
and
 there are considerable concerns over the extent of remaining reserves. Far
 more significant for the quality of our life on this planet are the
 environmental problems associated with oil and coal utilization. Severe
 atmospheric pollution, acid rain and oil spills have defiled the world we
 live in to an unspeakable extent. Of even greater concern is the ceaseless
 buildup of carbon dioxide in our atmosphere and the potential warming
trend
 associated with the Greenhouse effect. However, despite the dual oil price
 shocks of 1973 and 1980, total CO2 emissions into the atmosphere increased
 by more than 40% in the two decades between 1970 and 1990. It is a pattern
 we seem incapable of controlling.

 The struggle we face in the future will not be characterized by a single
 battle or a focused apocalyptic event. If we continue with our current
 lifestyle, we will experience a slow protracted diminution of quality of
 life. In how many capitals cities of the world today do we see traffic
 police wearing masks to protect them from pollution? How many millions of
 new cases of respiratory disease are due to an atmosphere increasingly
 degraded by automobile exhausts and industrial emissions?

 It is clear that the continued utilization of fossil fuels as a dominant
 energy source is not consistent with the long-term sustainability of our
 environment. Other practical forms of commercial industrial energy must be
 developed and in particular, sources that are renewable and pose the
minimum
 risk to our environment.


 Morton Satin
 Chief,
 Agro-Industries and Post-harvest Management Service
 Agricultural Support Systems Division
 FAO

 From the forward to:

 Renewable biological systems for alternative sustainable energy production
 (FAO Agricultural Services Bulletin - 128)

  -

 
  Some of us aim to deter that truth.
 
  Todd Swearingen
  Appal Energy
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Re: [biofuel] glycerol/steam production

2001-05-03 Thread david e cruse

Hi  Dana,

Check  out  these  websites  for  steam stuff.
www.claytonindustries.com (compact steam boilers)
www.trigenewingpower.com
www.coppus.com (steam turbines)
www.tuthill.com (coppus corporate home)
www.ttboilers.com
One  of  these  has  a  10hp unit .  I`m  very
interested  in  using  biosiesel  to  fire  a  boiler,
and  turn  a  steam  turbine for  power  generation.
I  also  like  the  idea  of  using  a  back pressure
steam turbine in  that  situation. I  was  wondering
if  you  could  use the  low  pressure  steam
exiting  the  back pressure turbine  to  turn  a
steam turbine  that  operated on low  pressure steam,
If  so  that  would  be  a  nice combined cycle  set  up!
If  not  you  could  use  that  low  pressure  steam
to  heat  some  of  your  biodiesel tanks.
Anyway  those  are  some  good  websites to  look
at,  and  if  I  see  any  others  I`ll  let  you  know.

David  Cruse
- Original Message -
From: Dana Linscott [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 10:16 AM
Subject: Re: [biofuel] glycerol/steam production


 It seems to me that since the biodiesel process
 requires heat and in many climes home heating is a
 major cost of living the prime use of waste glycerol
 would be energy production/heat.

 Our initial attempts at modifying the flame guns
 used in fuel oil furnaces to burn glycerol are showing
 (as an earlier post from a member of this group
 warned) a build up on the guns and in the combustion
 chambers. We are also noting some corrosive effects on
 the unit pumps which may be due to the glycerol
 quality. Strait WVO seems to work better (as we
 suspected it would) and so would seem to be the prime
 candidate for home heating oil substitution since it
 requires minimal processing.

 Accordingly glycerol would seem to be most useful as a
 heat source for biodiesel production.

 Has anyone accumulated some hours using glycerol in a
 non-injected type fuel oil furnace?
 Some of our older members (myself included) recall a
 drip type fuel oil furnace that was simplicity
 itself but cannot find a source for them. They were
 not thermostatically controlled. The maintenance
 consisted of an annual cleaning of accumulated
 clinker from the combustion chamber.
 In cold climates such as ours in MN a primary furnace
 of this type could be used to provide for a constant
 heat input to a home and the existing furnace could be
 used to provide supplementary heat when the primary
 units capacity is not sufficient.

 I also recall seeing a fuel oil domestic hot water
 heater (several decades ago) which worked on the same
 principal and would adapt beautifully to heating WVO
 for biodiesel production.

 Is anyone aware of a source for either one of these
 products?

 A third, more complicated use for glycerol might be
 electrical production using a steam powered generator.
 In my younger days I was involved in fluid bed reactor
 research and some of our bench test units would
 cleanly combust nearly anything. Combined with a steam
 generator they were actually quite efficient and
 simpler to build than a Biodiesel production unit.


 Is anyone aware of a simple to build steam engine
 design or a source for inexpensive steam
 engines/turbines in the 10 HP range?

 Efficiency would be raised substantially if the
 glycerol could be combusted and used for electrical
 production and the cogenerated heat could be harnessed
 for Biodiesel production use or even home heating.

 Dana Linscott

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Re: [biofuel] washing bio-diesel

2001-05-03 Thread david e cruse

Hi  Folks,

Todd  brought  up  something  interesting  here.
Solid  catalyst !  Could  someone  please  tell
those  of  us  who  don`t  know.  What  do  you
use  as  a  solid  catalyst ?  And  explain  the
way  to  use it .

Thanks,
David  Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 6:51 PM
Subject: Re: [biofuel] washing bio-diesel


  Is it necessary to wash bio-diesel when it will be mixed 50/50 with
 regular
  diesel fuel? Can isoprohyl alcohol be used after the wash instead of
 boiling?
 ...

 Only if you want to preserve your injectors. If they are unimportant to
you,
 feel free to not wash.

 The fuel will have some free floating catalyst in it. Even though small
 amounts, over time it can contribute to injector failure.

 According to the Bio-Dieseler's Home Manual, this factoid should be
 indelibly tatooed on the inside of one's frontal lobe.

 This step will not be eliminated until solid catalysts become the industry
 standard. It's coming.

 As for isopropyl, are you theorizing that it could be used as a drying
 agent?

 Todd
 Appal Energy
 [EMAIL PROTECTED]


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Re: [biofuel] glycerin

2001-05-03 Thread david e cruse

Hi  David R.

Thank  you , I  will  remind  you  later  on.

Thanks  again,
David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 8:05 PM
Subject: Re: [biofuel] glycerin


 David,
  Yes. If I dont get back to you in a week give me a reminder. Both
 books were good but one was excellent.
 B.r., David

 - Original Message -
 From: david e cruse [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com
 Sent: Thursday, May 03, 2001 9:54 AM
 Subject: Re: [biofuel] glycerin


  Hey  David R.
 
  If  that  message  was  directed  at  me  (David C.)
  That  would  be  kind  indeed !



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Re: [biofuel] Stainless Steel Tank Sources

2001-05-03 Thread david e cruse

Hi  Todd,

Thanks  for  the  info  on  the  tanks.

David  Cruse
- Original Message -
From: Appal Energy [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, May 02, 2001 8:22 PM
Subject: [biofuel] Stainless Steel Tank Sources


 http://www.upe.com/GetSubCat.html/786

 http://www.4tank.com/stainless_tanks1.htm

 http://www.winetanks.com/


 [Non-text portions of this message have been removed]


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Re: [biofuel] The Gas Price Hike

2001-05-03 Thread david e cruse

Hi  Keith,

Wouldn`t  it  be  great  if  Americans  started
becoming  more  dependent  on  biodiesel !
This  is  what  I  hope  happens!! Cummins diesel
engines  are  available  in  Dodge  pickup  trucks,
and  Ford  is  putting  their  own  diesel  in  some
pickups.  Now  if  all  the  others  would  follow
suit !

David  Cruse
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Thursday, May 03, 2001 8:23 AM
Subject: [biofuel] The Gas Price Hike


 http://www.alternet.org/story.html?StoryID=10824
 AlterNet --
 The Gas Price Hike
 Michael T. Klare, AlterNet
 May 2, 2001

 Americans are discovering to their dismay that the price of gasoline
 is rising all over the country, foreshadowing a summer of costly fuel
 use. Some experts predict gas prices will rise to $2.50 or even $3.00
 per gallon in some areas of the country -- a level that will put many
 American businesses, and American family budgets, into trouble.
 Typically, politicians and the media are blaming the rise in prices
 on refinery overload and stiff environmental regulations. But it is
 clear that the dramatic spurt in prices is due as much to deep
 structural problems in the U.S. energy supply system.

 Americans use more petroleum products than any other population on
 earth. According to the U.S. Department of Energy (DoE), the United
 States consumed about 7.1 billion barrels of oil in 1999, or
 one-fourth of the world's total consumption. Much of our oil intake
 is devoted to transportation -- especially to road (automobile and
 truck) transportation. To produce sufficient gasoline for this
 purpose, U.S. refineries are now operating at near-capacity levels.

 In the first instance, then, the current hike in gasoline prices is
 caused by increased pressures on America's overburdened refineries.
 With summer coming on, Americans are driving more, and this, in turn,
 is pushing demand ahead of supply -- an automatic impetus for price
 increases. Environmental regulations also mandate a switch to
 cleaner-burning fuels in the summer (so as to reduce the risk of
 smog), and this, too, is contributing to the imbalance between supply
 and demand.

 One can conclude the easy solution to our gas price problem is to
 quickly expand U.S. refinery capacity and to soften or eliminate
 existing environmental regulations. In fact, this is the solution
 favored by many in the Bush Administration. But it will not be
 possible to expedite the construction or expansion of refineries
 without trampling upon many state and local land-use restrictions,
 and a weakening of environmental standards will increase the risk of
 severe pollution. Clearly, this is not the easy solution it might
 appear.

 Furthermore, the construction of new refineries (assuming that all
 regulatory obstacles can be overcome) will only lead to another, more
 complex problem: how to obtain sufficient crude oil to satisfy the
 growing U.S. demand for gasoline and other petroleum products.

 The United States was once self-sufficient in the production of oil,
 but rising demand and declining reserves have long since obliterated
 that happy condition. According to BP Amoco, U.S. oil production
 dropped from 9.2 million barrels per day (mbd) in 1989 to 7.8 mbd in
 1999, a drop of 15 percent. At the same time, U.S. consumption rose
 by 11 percent, from 16.7 to 18.5 mbd. This means the United States
 has had to import an ever increasing share of its petroleum from
 abroad -- jumping from about 45 percent of total consumption in 1989
 to 58 percent in 1999.

 It is likely, moreover, that the share of U.S. oil coming from abroad
 will continue to rise in the years ahead. Although increased drilling
 in Alaska and the Gulf of Mexico may help to slow the decline in U.S.
 production, it will not be possible to prevent a long-term slide as
 most major fields in the United States have already been fully or
 substantially depleted. Like it or not, we will have to import more
 petroleum from Latin America, Africa and the Middle East.

 The problem, of course, is that these areas are subject to recurring
 bouts of instability, thereby jeopardizing the steady flow of oil to
 the United States. President Bush's solution to this dilemma is to
 open Alaskan wilderness areas to oil drilling. While tapping into
 these areas won't make us energy independent, Secretary of Energy
 Spencer Abraham asserted in March, it will help increase America's
 energy security by ensuring a more diverse supply of oil.

 But this is somewhat misleading. Even if the Alaska wildlife refuge
 holds as much oil as some geologists believe (up to 10 billion
 barrels), its total contribution to U.S. petroleum requirements (at,
 say, 1 mbd over a 30 year period) will amount to less than 4 percent
 of anticipated consumption in 2020; most of U.S. demand -- about
 two-thirds of it -- will have to be satisfied from abroad.

 Clearly, if Americans continue to consume more and more oil 

Re: [biofuel] glycerin

2001-05-02 Thread david e cruse

Hi  Ed,

You  may  be  right  about  the  soap !
Only  problem  is  there  are  so  many  people
making  handmade/ hand crafted soap  and
all  the  other  craft  things  that  it  makes  it
difficult  to  find  a  good  market !
Anyway  thanks  for  the  thought.

David  Cruse
- Original Message -
From: NBT - E. Beggs [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, April 30, 2001 8:04 PM
Subject: Re: [biofuel] glycerin


 Soap production sounds  a little more promising.


 - Original Message -
 From: Appal Energy [EMAIL PROTECTED]
 To: biofuel@yahoogroups.com

 
   David  Cruse
  ...
  David,
 
  Here's the skinny on glycerin.
 



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Re: [biofuel] glycerin

2001-05-02 Thread david e cruse

Hi  David,

Thanks  for  the  info.  I  talked  to  the  General
Manager  of  Ocean Air Environmental ( formerly
NOPEC ) in  Florida  and  he  told  me  that  they
have  a  difficult  time  with  glycerin  also.  But  it`s
still  on  my  list  of  things  to  accomplish !

David  Cruse
- Original Message -
From: David Reid [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Monday, April 30, 2001 8:41 PM
Subject: Re: [biofuel] glycerin


 David,
   Unfortunately the only way to purify it properly and get an
 absolutely pure product is with distillation. Commercial processors use
 other screening and filtering processes such as fullers earth which gets
rid
 of some of the gunk but to get it really pure they still need
distillation.
 Unfortunately this type of process really needs to be done on a commercial
 scale to make it truly viable.
 B.r.,  David

  Does  anyone  know  a  process  that  can  be
  used  to  purify  the  glycerin  produced  in  the
  biodiesel  reaction  into  a  pure  or  high  grade
  glycerol ?  High  grade  glycerol  has  a  much
  better  market  value  than  the  crude ( 80-88% )
  glycerin  you  get  with  standard  biodiesel  recipes.
  Any  help  on  this  would  be  greatly  appreciated.
 
  Thanks,
  David  Cruse
  Atlanta, Georgia  metro  area



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Re: [biofuel] Farmers seek boost from veggie fuel

2001-05-02 Thread david e cruse

Ralph,

There  is  a  political  base  for  soybeans  and
other  vegetable  products  that  can  be  used  to  make
biodiesel  because of  the   farm  lobby .  Farmers  get
money  or subsidies  for  crops  they  can`t  grow
and  bring  to  market.  That  is  to  say,  if  you  are  a
farmer  and  have  enough  land  to  grow  an  extremely
large  amount  of  something, but  can`t  grow  it  because
there  wouldn`t  a  market  for  it.  Then  you  are  paid
by  the  Fed. Gov.  a  subsidy ( money ) to  grow a
smaller  amount  of  that  crop  instead  of  growing  the
larger  amount  that  you  could  have  grown, but  would
have  lost  money  if  you  had.  The  farmers  here  in  this  country  see
biodiesel  as  a  market  for  those
crops ( soybeans ) ,  and  our  Government  is  all
for  it  because  that  means  less  subsidies  to  pay
out.  Same  thing  for  Ethanol ( corn )  farmers,
they  want  money  for  corn  they  can`t  grow  and
sell  because  now  soybeans  are  the   darlings 
of  the  moment.  Read  University  of  Idaho,
they  are  behind  the  big  push  for  soybean biodiesel!
Iowa  is  where  the  ethanol  boys  are.  No  offense
meant  to  any  of  you  green  guys  from  those
two  states.  Waste  vegetable  oil  just  doesn`t  have
a  political  base.  Farmers  can`t  grow  it  so  the
Feds  just  don`t  see  any  reason  to  be  in  favor
of  it.  I  mean  no  offense  to  the  farmers  either
because  they  have  to  earn  a  living  also  and
they  have  their  lives  tied  up  in  the  land  and
without  them  we  would  be  chaos  in  no  time  flat!
It`s  a  bad  situation  for  everyone !!
I  still  prefer  WVO  because  otherwise  it  winds
up  as  just  another  pollutant!!!  Hope  I  didn`t  make
a  mess  of  that  attempt  at  an  answer.

David  Cruse
- Original Message -
From: Ralph Chamberlain [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Tuesday, May 01, 2001 11:35 AM
Subject: [biofuel] Farmers seek boost from veggie fuel


 I just read an article in the Sunday paper distributed by Associated Press
about the lobbying efforts of farmers to mandate the use of biodiesel as an
additive in diesel fuel.

 Unfortunately, the press is somewhat bad. It states that biodiesel costs
three times as much to produced as diesel. Is that a right amount? It also
states that that biodiesel is not a cleaner energy than natural gas??? and
that it will slow the switch to natural gas???

 The gang is all there to fight. It seems from the article that truckers,
railroads, environmentalists and the airlines have teamed up to fight
legislation against its mandatory use.

 My question is this, does biodiesel costs three times as much to produce?
(will it drive up the cost of diesel and aviation fuel) Doesn't the
emissions from a 20% biodiesel/diesel mixture reduce pollution?(and
hopefully meet the new standards set for year 2007 EPA regs). Finally what
is the subsidized ethanol pricing?

 Ralph Chamberlain
 [EMAIL PROTECTED]


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