url: http://escribe.com/health/thesilverlist/m61932.html
Re: CS>SilverGen specs.
From: Wayne Fugitt
Date: Tue, 12 Aug 2003 19:52:44

  > Evening Mike,

  >> I'll probably continue making that mistake forever:)

  > Real technicians don't worry about that because they make the same
  > mistakes.

  > They read "what you meant", not what you said. <grin>

  > Wayne

  Morning Wayne,

  It used to be called "mho". Everyone thought that was a  stupid name
  and nobody  used it. Then they changed it to  Siemens,  which sounds
  exotic so everyone uses it. They even marked it on  the instruments,
  so I guess we're stuck with it:)

  Anyway, I guess it has a useful purpose. I just ordered some samples
  from Analog  Devices to make a simple A/D converter  to  measure the
  cell voltage during the brew.

  I figure if I plot the conductance during the first half-hour or so,
  it should  show a straight line until the respective ions  reach the
  opposite electrodes.

  Then, when  they start to combine and make oxide, the  slope  of the
  line should change.

  But that's ok. The initial slope shows the conductivity constant for
  the electrode  configuration. We can use it along  with  the Faraday
  equation to tell what the actual ppm is. Here's an attempt to show a
  diagram:

  |\
  | \ Initial Slope
  |  \
  |   \
  |    \
  |     \
  |      \
  |       .  Oxide Formation
  |        - -.
  |            - -.
  |                - -
  --------------------

  Now all we have to do is project the initial slope to  intercept the
  X-axis, and draw a horizontal line from the final  conductance value
  over to the Y-Axis.

  The two lines will intersect. Since we know the current and the cell
  volume, the intercept point should give us the final ppm of the cs.

  The circuit  is  very simple. If you are  interested,  go  to Analog
  Devices, make a nice-sounding business name such as  XYZ Consulting,
  and register for free samples. Their policy is generous, so you are
  not cheating. They want to give you free samples.

  Get two each of the following (The circuit uses one of each, but you
  always need spares:)

  AD7791  24-bit A/D, 19 usable bits
  AD8554  Quad Op Amp. 5nV/C tempco, 20pA input bias current
  ADR381  2.5V 5ppm/C reference

  NOTE: the  samples  link  for the AD7791  points  to  the  AD7788. I
  ordered them  by mistake, and now it won't let me  order  the AD7791
  since I  have  reached the limit. So the first try will  only  be 16
  bits, which is probably good enough.

  When you  go to order the AD7791, you will see a long string  in the
  url that  contains  "AD7788". Just change it to AD7791  and  it will
  take you to the correct page.

  The plan  is to use a cheap optocoupler like the 4N26  for isolation
  and several lines off the parallel port for data transfer.  A simple
  9V wallwart  will supply the power and give isolation  probably good
  to 250V or so.

  I won't  bother getting precision resistors for absolute  accuracy -
  probably 1%  is all that is needed. All we want is the slope  of the
  line and  we can do the rest in software. It will be  in  Pascal and
  run under dos, as usual.

  Time permitting, we should have yet another way to measure the ppm!

Best Regards,

Mike Monett


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