To Nenah and others discussing this:

It kinda surprises me that it has come up. 

Back in the early days we were taught to use a "pinch" of salt (NaCl) 
or a drop or two of salt solution in our brew vessels as a "starter" to 
get the process going more quickly. Baking soda was also a suggested 
alternative.

The result was a process that worked at high current and very rapidly,  
producing large particles that often settled out after a few days or 
weeks. In only took a few minutes to produce a batch, and your 
electrodes never had a chance to collect any "fluff." The recipes you 
found online commonly stated that you would get about "1ppm per 
minute." 

It was quite exciting to watch, in fact, with all the bubbling and 
whisps of stuff coming off the electrodes.

A lot of people used this method for a long time, and some still do. It 
was the first process I learned, and I used it for a year or two. It 
worked and was part and parcel of the popularization of Colloidal 
Silver in the modern era.

Generally, people started moving towards using only distilled water 
when they began examining the particle size issue. 

There was some concern that the larger particles presented an increased 
risk of argyria, though that effect was never demonstrated. (Of course, 
now there's Stan, the Senate candidate.)

There was also concern that the use of  a "starter" produced other 
compounds (like silver chloride or carbonate), at least in the early 
stages of the process, that could be harmful in and of themselves. This 
was never proved to be a real concern, given the low toxicity and 
concentration of the likely by-products.  (Except in Stan's case, of 
course! <sigh>)

Nonetheless, people started working to understand the process in pure 
distilled water, leading to countless experiments in current limiting, 
other voltage ranges, AC vs. DC, polarity switching, and so on.

All this is somewhat apart from the issue of pH. Adding buffers to the 
CS *after* production will still effect the ionic portion, likely  
leading to some colorful displays along the way as your silver ions  
precipitate and agglomerate into particles of silver salts. 

Certainly worth study. Perhaps a way can be found to balance the pH 
without compromising the silver component?

One other thing I can suggest, if you're interested in the utility of 
these methods, is that *very low* concentrations of production 
additives were never explored to my satisfaction. They *might* prove 
beneficial to ease-of-production and reproduceability with minimal 
impact on safety or effectiveness. Who knows, eh?

For the sake of the newcomers and lurkers, please understand that for 
now, at least, standard practice is to use only distilled water. 

That's your bed-time story for today. G'night boys and girls! <grin>

Be well,

Mike D.

[Mike Devour, Citizen, Patriot, Libertarian]
[mdev...@eskimo.com                        ]
[Speaking only for myself...               ]


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