url: http://escribe.com/health/thesilverlist/m63380.html
CS>CS particle size
From: Gaston 
Date: Sat, 11 Oct 2003 06:47:41

  > To anyone that wishes to comment pls.

  > Here  is   a   comment   taken   from   the   following   web  site:
  > http://www.elixa.com/silver/lindmn.htm

  >   "It's In The Water

  >   ... Another  variable that influences particle size  is  the water
  >   temperature. The  warmer the water, the faster  the  reaction will
  >   take place, and the smaller the particles will be. "

  > Is this  correct:  The warmer the water, the  smaller  the particles
  > will be ? or am I reading this incorreclty ?

  > I understand  that  the  reaction  will  be  faster  but  what about
  > particle size ?

  > Thank you.

  > Gaston

  Hi Gaston,

  As Ken pointed out, increasing the temperature results  in increased
  particle size.

  You can  see  the  effect in Reid  Harvey's  work  on  ceramic water
  purifiers using silver oxide. A picture is on his web page at

    http://www.purifier.com.np/CS.html

  One of  the reasons this happens is the cs  generator  uses constant
  voltage. With no current limiting, the current can increase  to high
  values as more silver ions enter the solution from the anode.

  The hydroxyl  ion, OH-, forms at the at the  cathode  where hydrogen
  accepts electrons  to  form  hydrogen gas. So we  have  a  supply of
  silver ions, Ag+, and hydroxyl ions, OH-, in the solution.

  These ions spread by thermal diffusion and by convection currents to
  arrive at the opposite electrode from where they were generated.

  Each electrode  has  the  highest  concentration  of  ions  near the
  surface where  they are formed. This is called the  Nernst diffusion
  layer.

  When the  opposite  ion  reaches this thin layer,  there  is  a high
  probability of forming silver oxide and silver hydroxide.

  The probability  increases   with   current,   temperature,  and the
  concentration of ions already in solution.

  These initial particles are too small to see, but they can  meet and
  be held  together  by  van Der Waals forces.  In  other  words, they
  agglomerate.

  High temperatures  cause   the   current   and  thermal  velocity to
  increase. This means higher production of silver oxides.

  With more  oxides  present  in   the  solution,  there  is  a higher
  probability they will meet and join and become bigger. The resulting
  solution is a different color than the normal yellow tint you see at
  room temperature, indicating the particles are larger.

  So, unfortunately, the statement at the elixa page is  incorrect, as
  is so much of the published information about cs.

Best Regards,

Mike Monett


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