Hello, Maz,

A lot depends on whether the EIS generator is
commercially manufactured (e.g. by Ode, Trem et al)
or home made.
I personally use a homemade generator with a
current limiting rheostat to prevent runaway, and a
3-inch separation of bullion coin electrodes. For such
a setup, a multimeter can be quite useful. I use a
multimeter to measure the resistance between the
electrodes when fresh DW is in the vessel. Then I
adjust the current-limiting rheostat to match the
inter-electrode resistance.
The multimeter can then be used during the electrolysis
process to exhibit the brewing rate. With experience,
this gives a good indication of the quality of the brew.
The multimeter could then be used either as a microammeter
(if it has the proper range) in series with the electrolysis
cell, or as a voltmeter in parallel with the current-limiting
rheostat or the cell electrodes.

The multimeter could also be used to measure
conductivity of EIS in a container outside the brewing
vessel, if the wetted probes' length and spacing were
kept constant. Even then, the reading would be only
be relative. That is, ratios of such readings for different
EIS batches would have meaning. Single readings
would not, unless the probes' geometry were calibrated
using a standard conductivity cell technique. This
technique is well-known in college courses in
Physical Chemistry or Electrochemistry. Commercially
made meters such as the Hanna TDS have been
pre-calibrated for a fixed-geometry conductivity
measurement, and then calibrated for ionic concentration
as proportional to the conductivity.

A multimeter is definitely a handy tool to keep around
for various purposes in making and checking EIS.
I get by, however,with just an analog microammeter (no
batteries to wear out) and a Hanna TDS.

Best regards,

Matthew