If I understand your question, you can set it in the in slurm.conf file, the 
default is:

MailProg = /usr/bin/mail

From: Fanny Pagés Díaz <fpa...@citi.cu<mailto:fpa...@citi.cu>>
Reply-To: slurm-dev <slurm-dev@schedmd.com<mailto:slurm-dev@schedmd.com>>
Date: Wednesday, September 28, 2016 at 11:45 AM
To: slurm-dev <slurm-dev@schedmd.com<mailto:slurm-dev@schedmd.com>>
Subject: [slurm-dev] Send notification email

I need send notification email from Slurm using other mail server which is not 
the standard one. Any can help me?

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