The index.rst file below demonstrates that \newcommand does not work with 
latexpdf.

------------ Below is my conf.py file ------------------------
# For conf.py documentation see
# http://www.sphinx-doc.org/en/master/config
#
project   = 'newcommand'
extensions = [
    'sphinx.ext.mathjax',
]
------------- Below is my index.rst file -------------------------
Problem With \newcommand in latexpdf
####################################
This file builds just file,
and displays as intended, with ``make html``,
but with ``make latexpdf`` it generates and
``Undefined control sequence.`` error for the
macro ``\B``.

Define Latex Macro
******************
``:math: \newcommand{\B}[1]{{\bf #1}}``
:math:`\newcommand{\B}[1]{{\bf #1}}`

Use Latex Macro \B
******************
``:math: f : \B{R} \rightarrow \B{R}``
:math:`f : \B{R} \rightarrow \B{R}`

This File
*********
.. literalinclude:: index.rst

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