This is an interesting thread.

According to Wikipedia,

The U.S. Congress passed legislation that would allow U.S. citizens to take
possession of unoccupied
islands containing saltpetre.

 http://en.wikipedia.org/wiki/Guano_Islands_Act

http://upload.wikimedia.org/wikipedia/commons/0/00/Chincha_guano_islands.JPG

Note this is supposedly how we obtained the famous Midway Island.



There is lots of  information info on the web about salt-petre and caves.

For example:

http://www.dmme.virginia.gov/DMR3/dmrpdfs/vamin/VAMIN_VOL47_NO04.pdf

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