Single isotope diamond is 50% better  thermal conductivity of normal diamond.   
It has been  used in laser optics and thermal transfer applications 
(semiconductor heatsinks).   I think the highest reported thermal transfer rate 
used isotopically pure diamond etched with micro-fluidic channels fed with 
coolant.   GE makes the diamond material... it was developed as part of 
Reagan's Star Wars project.

Isotopically pure silicon has 60% better thermal conductivity than natural 
silicon.

Isotopically pure platinum has been used in RTD temperature sensors.
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