The easiest way is try something simple without profound theories
is to employ an insulator-spaced stack of 100  stainless steel Fender Washers
(1.5 inch diameter) on a nylon rod using 120 volts rectified with a full-wave bridge placed in
a horizontal water filled  and capped 2.0 inch diameter PVC with the
rectified voltage applied to each end washer. That should divide
each "cell" to about 1.5 volts.
 
http://www.boltdepot.com/material.aspx?cc=12&cs=63
 
Vapor out one end, make-up water in the other.
 
With or without voltage applied the metal-water interface
Helmholtz Double Layer is a "supercapacitor".

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