When it comes to "power-assist" for the bicycle, even
in the range of 300 watts...

A viable option to batteries - for could be:

... surprise, surprise: compressed natural gas (or
propane) !

And as for the emissions, CNG (compressed natural gas)
could actually be less polluting, overall, than
batteries charged with grid power, given the
line-losses and inefficiency. The key would be the
direct conversion of heat to electricity in a small
fuel cell.

Here is an actual model of a FC bike made by Gore and
Aprilla in 2005. It failed miserably and for good
reason. The design was beyond-stupid: brain dead, you
might say. It was way overpowered, way, way
overpriced, and used unavailable hydrogen instead of
CNG. Three strikes and your out, even if your name is
Gore.

Here is a table of energy density:

CNG              3,100 Wh/l     12,100 Wh/kg
NiMH Battery       280 Wh/l        100 Wh/kg
Li-Ion Battery     200 Wh/l        150 Wh/kg
Lead-Acid Battery   40 Wh/l         25 Wh/kg
Propane             26 Wh/l     13,900 Wh/kg

As you can see- compared to the best battery, CNG has
about a 60,000:1 advantage !!

Time to revisit this concept, but 
1) Forget H2
2) Forget the Gore Fuel-cell, go with SOFC
3) Mistubishi has been running SOFC fuel cells on CNG
for the past 15 years. This is not new

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