I had one cell go bad early on and I knew it the first day because my voltage 
was lower the next morning after charging.

Sent from my iPhone

> On May 28, 2015, at 1:09 PM, Paul Dove via EV <ev@lists.evdl.org> wrote:
> 
> I've been driving mine for years and several hours after charge the voltage 
> is exactly the same. Like you said self discharge till you reach OCV.
> 
> Sent from my iPhone
> 
>> On May 28, 2015, at 1:01 PM, Cor van de Water via EV <ev@lists.evdl.org> 
>> wrote:
>> 
>> Nope,
>> I have a little experience with charging older style Li-Ion batteries
>> by hand and the resting voltage is typically a rather fixed amount (delta) 
>> below the charging voltage,
>> no matter how high you charged them.
>> If you charge to 3.8V then they rest at say 3.65
>> If you charge to 4.0 then they rest at 3.85
>> If you charge to the max recommended 4.25 edge then they rest at 4.1
>> If you overcharge to 4.5 then they rest at 4.35 (they will self-discharge 
>> faster but not immediately)
>> 
>> So, from measuring the rest voltage it is not clear that they are balanced -
>> you really need to measure each cell to make sure,
>> that is why a BMS is important.
>> 
>> BTW, the only thing that I found different between charging and resting 
>> voltage was
>> the indication of a bad cell with high resistance, but even those were pretty
>> consistent in just a slight larger delta between charge and rest.
>> Hope this clarifies,
>> 
>> Cor van de Water
>> Chief Scientist
>> Proxim Wireless
>> 
>> office +1 408 383 7626        Skype: cor_van_de_water
>> XoIP   +31 87 784 1130        private: cvandewater.info
>> www.proxim.com
>> 
>> 
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>> 
>> 
>> -----Original Message-----
>> From: EV [mailto:ev-boun...@lists.evdl.org] On Behalf Of Paul Dove via EV
>> Sent: Thursday, May 28, 2015 10:54 AM
>> To: Electric Vehicle Discussion List
>> Subject: Re: [EVDL] FW: On the road again.
>> 
>> I disagree. 
>> 
>> Assuming by your example the OCV of the cell is 3.8v and one charges to 4v.
>> 
>> After cycle 1 the OCV will be 22.8v
>> After cycle 2 the OCV will be 19v
>> After cycle 3 the OCV will be 19v
>> Etc.
>> 
>> One can tell if there is a bad cell immediately after every charge because 
>> the OCV will be lower.
>> 
>> Sent from my iPhone
>> 
>>> On May 28, 2015, at 12:44 PM, Lawrence Harris via EV <ev@lists.evdl.org> 
>>> wrote:
>>> 
>>> Just remember to check each cell periodically to ensure they are staying 
>>> together.  If one cell is weak it will drift down each cycle and eventually 
>>> you will overcharge the good ones and destroy the weak one (this is where 
>>> fires come from).
>>> 
>>> A little exaggerated perhaps but this is what happens, maybe not exactly 
>>> cycle by cycle but over time.  Your charger is set to chart to 24v and then 
>>> cut back.
>>> 
>>> cycle 1: 6 x 4v = 24v
>>> cycle 2: 5 x 4.1 + 3.5v = 24v
>>> cycle 3: 5 x 4.2 + 3.0v = 24v
>>> cycle 4: 5 x 4.3 + 2.5 = 24v
>>> :
>>> 
>>> eventually the good ones are being charged over their max values and the 
>>> weak one is being pushed towards zero or negative at the end of each 
>>> discharge cycle.  Now we get heat and overpressure and poof!
>>> 
>>> Lawrence
>>> 
>>>> On May 28, 2015, at 10:18 AM, damon henry via EV <ev@lists.evdl.org> wrote:
>>>> 
>>>> Thanks David...
>>>> for pointing out the forgetfulness factor.  Been there, done that.  There 
>>>> are a couple of fairly simple solutions to that particular problem.  
>>>> First, a charger that is set at a low enough voltage to limit that danger. 
>>>>  So far it has been my experience with this pack that there is not enough 
>>>> of a voltage rise to set a dumb charger up for this function, but I am 
>>>> considering getting a smart charger that will do constant current to a 
>>>> specific voltage then shut off.  Another easy solution is a mechanical 
>>>> timer.  I have an e-meter on the motorcycle so I know how much energy I 
>>>> have taken out.  That makes it pretty easy to set a timer as a fail-safe.  
>>>> I think my e-meter may even have an alarm function that I could use to 
>>>> shut the charger off.
>>>> I thought the joke about the tarp was clever :) Finally, as Cor 
>>>> pointed out, it is my motorcycle which has the 3.4kwh pack on it now.  
>>>> Since I have not done lithium before I brought out the old test mule from 
>>>> under the tarp so that if I do learn from the school of hard knocks, as is 
>>>> often the case, I will be well educated before investing in a much more 
>>>> expensive lithium for my truck.  I don't believe I will do the lithium 
>>>> without a BMS, but that is a decision for some future time.
>>>> I have two normal scenarios.  MWF  - round trip to the gym and back 10 
>>>> miles - opportunity charge for an hour while I get ready for work then 8 
>>>> miles to the office where I have the full day to charge if I like.  Then 
>>>> back home 8 miles.  The other two days of the week I do not do the gym 
>>>> first, so overall this pack is getting very light duty.  In fact, I think 
>>>> the hardest thing for me to get used to is not fully charging it.  I'm so 
>>>> used to charging as much as I can whenever I can that it is a hard habit 
>>>> to break.  In this case though, why get close to the danger points?  Bad 
>>>> things usually happen to batteries when they are nearing full or empty.  
>>>> Keeping them away from those danger zones makes a lot of sense.  The most 
>>>> stress I am likely to put on them will be if I go to visit my good friend 
>>>> John Wayland who lives 17 miles of mostly freeway from me.  It's no 
>>>> problem picking up a charge at his house before I head back home, though, 
>>>> so even that should not be too bad. 
>>>> damon
>>>> 
>>>>> To: ev@lists.evdl.org
>>>>> Date: Wed, 27 May 2015 15:52:20 -0400
>>>>> Subject: Re: [EVDL] On the road again.
>>>>> From: ev@lists.evdl.org
>>>>> 
>>>>>> On 27 May 2015 at 9:23, damon henry via EV wrote:
>>>>>> 
>>>>>> After 5 years under the tarp, I put my EV motorcycle back on the 
>>>>>> road this week.
>>>>> 
>>>>> You must have been awfully bored, living under that tarp for all 
>>>>> those years! ;-)
>>>>> 
>>>>>> I purchased 16 Calb CA60ah cells which fit well in my existing 
>>>>>> battery boxes.
>>>>> 
>>>>> So if my math is right, ~3.4 kWh.  That's the equivalent of about 
>>>>> four T-125 golf car batteries (useful capacity 900Wh each).  I'm 
>>>>> thinking this is going to be a short-range truck, and probably 
>>>>> short-lived batteries from working so hard.
>>>>> 
>>>>>> I do not have any BMS installed, but on such a small pack with good 
>>>>>> access it is easy to be my own BMS
>>>>> 
>>>>> As long as you don't get busy with something else and forget.  I 
>>>>> know of a guy around here who destroyed an entire set of rare and 
>>>>> expensive Saft STM5-
>>>>> 180 NiCd batteries when he forgot he was charging them.
>>>>> 
>>>>> I wouldn't even do an E-bike lithium battery without a BMS.  But 
>>>>> that's me, and I know how forgetful I can be!
>>>>> 
>>>>> David Roden - Akron, Ohio, USA
>>>>> EVDL Administrator
>>>>> 
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