Instead of intercalating, the ions end up plating the surface of the anode. 
Charging in freezing temps can cause plating, which reduces battery capacity 
and increases Resistance 


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On Sunday, April 3, 2022, 7:21 PM, Peri Hartman via EV <ev@lists.evdl.org> 
wrote:

Well, then, why is the range substantially less in cold weather ? The 
charger nor the battery don't know the discharge rate while charging.

I understand that charging needs to be slower. But how does that affect 
capacity ?

As a matter of example, during 20F weather last december, I was getting 
20 miles range on the Leaf at full charge. Yesterday, charging while 
50F, I went 30 miles and still had about 1/3 bars left.

<< Annoyed by leaf blowers ? https://quietcleanseattle.org/ >>

------ Original Message ------
From: "Cor van de Water" <cor.vandewa...@gmail.com>
To: "Peri Hartman" <pe...@kotatko.com>; "Electric Vehicle Discussion 
List" <ev@lists.evdl.org>
Sent: 03-Apr-22 16:32:59
Subject: Re: [EVDL] kWh versus charging temperature

>Peri,
>It is the *speed*, not the *capacity* that suffers in very cold weather.
>Think of it as ions moving sluggish through the lattice that makes up
>the active material.
>The colder, the more sluggish.
>Forcing too much current into this can even cause faults to develop,
>which *are* reducing the capacity permanently, not because of the cold
>but because of the fault blocking the path of current in that section
>of the lattice, taking a little bit of the total capacity out of the
>picture.
>That is why charging must be slow in the cold, to avoid creating those
>faults, so that the capacity of the battery remains, albeit at lower
>*power* (=speed of current in or out of the battery).
>Hope this clarifies,
>Cor.
>
>On Sun, Apr 3, 2022 at 3:50 PM Peri Hartman via EV <ev@lists.evdl.org> wrote:
>>
>>  As I understand, with most Li-ion cells, the colder the cell, the less
>>  charge it will take on. Correct ?
>>  But what happens if a warm battery is charged and then cools off ? It
>>  still has all its kWh, right ? And further, the temperature of the
>>  battery does not affect how many kWh you can get *out* of it, though the
>>  rate may change a bit.
>>
>>  My 2011 Leaf has abysmal range at this point. I'm wondering if I were to
>>  charge during the warmest part of the day, would I get a bit more range
>>  ? I'm going to guess it won't make that much difference since the
>>  battery is in the shade (under the car) and won't warm up much over a
>>  few hours. But I'm still curious if the theory holds truth.
>>
>>  Peri
>>
>>  << Annoyed by leaf blowers ? https://quietcleanseattle.org/ >>
>>
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