I had initially some authentication issues with my ISP Exchange SMTP host ("530 5.7.1 Client was not authenticated")

If I'm not mistaken that is probably because the host-option doesn't have a label for the credentials table. Your /etc/mail/secrets has to look like this:
label1  user:password

and the host entry has to contain it like this:
action "relay" relay host smtp+tls://label1@exchange.example:587 auth <secrets>


but when I switched to their general purpose SMTP host, it worked fine.

They probably accept everything as long as the sending IP is from their own range.


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