Re: [Biofuel] best oil to make BD

2005-10-26 Thread bob allen

My biodiesel comes from cooking oil that is about half saturated and 
half unsaturated:  methyl palmitate, methyl oleate, methyl linoleate.

It is good down to at least -3 celcius (this morning on the way to 
school) If it gets much colder I get in trouble so for lower temps, I 
start blending in fossil diesel.


Keith Addison wrote:
> The answer is No. Paul O'Brien of Biofuel Systems says about their 
> Wintron cloud-point depressant: "There are still some types of biodiesel 
> that can't be winterised (such as tallow biodiesel and palm oil 
> biodiesel due to the fact they are so saturated -- double bonds are 
> needed to modify the viscosity and pour point etc.)."
> 
> I think that's a general principle. It says this at our "Biodiesel in 
> winter" page:
> 
> "To make WVO biodiesel for winter, heat the oil first, then cool it to 
> near 0 deg C (32 deg F); the saturated fats will crystallise out and 
> sink to the bottom. Use the clear oil off the top to make winter 
> biodiesel, keep the stuff at the bottom for summer. But even this 
> "winterized" biodiesel still won't go much below -5 deg C (23 deg F) 
> without gelling."
> 
> http://journeytoforever.org/biodiesel_winter.html
> Biodiesel in winter
> 
> We imported Wintron from the UK to Japan without any difficulty, it 
> wasn't expensive, it works well.
> 
> Winterisers/pour-point depressants are not so easy to make. We're 
> working with a company here in Japan on veg-oil based pour-point 
> depressants, works very well, but not with high-melting point oils.
> 
> Best
> 
> Keith
> 
> 
> Hi Tony,
> 
> 
> I recall reading about them in the archives. I remember them being a
> tad on the pricy side. I cannot get them in my location unless I
> become an importer. I suppose one could make them. Hmmm, yet another
> thing to research but much later.
> 
> 
>     Tom Irwin
> 
> 
> *From:* tony [mailto:[EMAIL PROTECTED]
> *To:* Biofuel@sustainablelists.org
> *Sent:* Tue, 25 Oct 2005 14:15:28 -0300
> *Subject:* Re: [Biofuel] best oil to make BD
> 
> Hi,
> Are there additives or chemicals that can be added to biodiesels made
> with oils of low iodine values to lower its melting point for use in
> colder climates?
> 
> Tony
> 
> On 10/25/05, Tom Irwin wrote:
>  >
>  > The Biodiesel made from animal fat (beef) begins to solidify at
> about 14 C
>  > and completely solidifies at 10 C. Other animal fats or any mixes
> I have not
>  > worked with as yet. This information is in table form on the JTF
> site.
>  >
>  > Tom Irwin
> 
> 
> 
> 



-- 
Bob Allen
http://ozarker.org/bob

"Science is what we have learned about how to keep
from fooling ourselves" — Richard Feynman

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Re: [Biofuel] best oil to make BD

2005-10-26 Thread Keith Addison

The answer is No. Paul O'Brien of Biofuel Systems says about their
Wintron cloud-point depressant: "There are still some types of
biodiesel that can't be winterised (such as tallow biodiesel and palm
oil biodiesel due to the fact they are so saturated -- double bonds are
needed to modify the viscosity and pour point etc.)."


I think that's a general principle. It says this at our "Biodiesel in
winter" page:


"To make WVO biodiesel for winter, heat the oil first, then cool it to
near 0 deg C (32 deg F); the saturated fats will crystallise out and
sink to the bottom. Use the clear oil off the top to make winter
biodiesel, keep the stuff at the bottom for summer. But even this
"winterized" biodiesel still won't go much below -5 deg C (23 deg F)
without gelling."


http://journeytoforever.org/biodiesel_winter.html

Biodiesel in winter


We imported Wintron from the UK to Japan without any difficulty, it
wasn't expensive, it works well.


Winterisers/pour-point depressants are not so easy to make. We're
working with a company here in Japan on veg-oil based pour-point
depressants, works very well, but not with high-melting point oils. 


Best


Keith 



Hi Tony,

 

I recall reading about them in the archives. I remember them being a
tad on the pricy side. I cannot get them in my location unless I become
an importer. I suppose one could make them. Hmmm, yet another thing to
research but much later.

 

Tom Irwin 


right,left

From: tony [mailto:[EMAIL PROTECTED]

To: Biofuel@sustainablelists.org

Sent: Tue, 25 Oct 2005 14:15:28 -0300

Subject: Re: [Biofuel] best oil to make BD


Hi,

Are there additives or chemicals that can be added to biodiesels made

with oils of low iodine values to lower its melting point for use in

colder climates?


Tony


On 10/25/05, Tom Irwin wrote:

>

> The Biodiesel made from animal fat (beef) begins to solidify at about
14 C

> and completely solidifies at 10 C. Other animal fats or any mixes I
have not

> worked with as yet. This information is in table form on the JTF
site.

>

> Tom Irwin






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Re: [Biofuel] best oil to make BD

2005-10-26 Thread Tom Irwin




Hi Tony,
 
I recall reading about them in the archives. I remember them being a tad on the pricy side. I cannot get them in my location unless I become an importer. I suppose one could make them. Hmmm, yet another thing to research but much later.
 
Tom Irwin 


From: tony [mailto:[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Tue, 25 Oct 2005 14:15:28 -0300Subject: Re: [Biofuel] best oil to make BDHi,Are there additives or chemicals that can be added to biodiesels madewith oils of low iodine values to lower its melting point for use incolder climates?TonyOn 10/25/05, Tom Irwin <[EMAIL PROTECTED]>wrote:>> The Biodiesel made from animal fat (beef) begins to solidify at about 14 C> and completely solidifies at 10 C. Other animal fats or any mixes I have not> worked with as yet. This information is in table form on the JTF site.>> Tom Irwin___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/


 
 
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Re: [Biofuel] best oil to make BD

2005-10-25 Thread tony

Hi,
Are there additives or chemicals that can be added to biodiesels made
with oils of low iodine values to lower its melting point for use in
colder climates?

Tony

On 10/25/05, Tom Irwin <[EMAIL PROTECTED]> wrote:
>
> The Biodiesel made from animal fat (beef) begins to solidify at about 14 C
> and completely solidifies at 10 C. Other animal fats or any mixes I have not
> worked with as yet. This information is in table form on the JTF site.
>
> Tom Irwin

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Re: [Biofuel] best oil to make BD

2005-10-25 Thread Tom Irwin




The Biodiesel made from animal fat (beef) begins to solidify at about 14 C and completely solidifies at 10 C. Other animal fats or any mixes I have not worked with as yet. This information is in table form on the JTF site.
 
Tom Irwin 


From: Bernie Hunsche [mailto:[EMAIL PROTECTED]To: 'Biofuel@sustainablelists.org' [mailto:[EMAIL PROTECTED]Sent: Mon, 24 Oct 2005 22:31:48 -0300Subject: Re: [Biofuel] best oil to make BDIs it the animel fat or the Biodiesel that starts to solidify at around10deg C?> -Original Message-> From: [EMAIL PROTECTED]> [SMTP:[EMAIL PROTECTED]] On Behalf Of Tom Irwin> Sent: Thursday, 20 October 2005 8:40 > To: Biofuel@sustainablelists.org> Subject: Re: [Biofuel] best oil to make BD> > Hello Juan,> > I have found animal fat converts really easy to biodiesel. The main> obstacle is that it is primarily a summer only fuel as it solidifies at> about 10-14 C. A lot depends on what resources you have and your local> climate. If you have a farm with animals that need feed, perhaps canola> (non-GM variety) is a good candidate. It has a good oil yield per hectare> and a reasonably low iodine value. You can feed the crushed seedcake to> your livestock. If you are in a good sized town or city, waste vegetable> oil is usually available from restaurants. It's quite variable and more> difficult to convert than unused oil but you can usually get it for just> your transport costs. If you live in a poorer area then look for wild> castor beans. They're have large yields and are generally free for the> picking but you can't use the seedcake for animal feed. It composts rather> well for a garden or farm soil amendment. It takes a stronger stomach> than mine to deal with the aroma. Castor oil was once used an an emetic to> cause vomiting. Other I'm sure have their favorites.> > Tom Irwin> > > > > _ > > From: Mike Weaver [mailto:[EMAIL PROTECTED]]> To: Biofuel@sustainablelists.org> Sent: Tue, 18 Oct 2005 21:28:27 -0300> Subject: Re: [Biofuel] best oil to make BD> > Free is the best oil to use ;-)> > Juan B wrote: > > Hello Everyone, > > I Would like to know what is the best vegetable oil that can> be use to get the most biodiesel ? or it would be better to get animal> fat?> > I looked at the tables in the website but I did not> completely understand . > thanks> Juan> > > _ > > ___ Biofuel> mailing list Biofuel@sustainablelists.org> > > > Biofuel at Journey to Forever:> Search the combined Biofuel> and Biofuels-biz list archives (50,000 messages):> > > > > < > ___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/


 
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Re: [Biofuel] best oil to make BD

2005-10-24 Thread Bernie Hunsche
Is it the animel fat or the Biodiesel that starts to solidify at around
10deg C?

> -Original Message-
> From: [EMAIL PROTECTED]
> [SMTP:[EMAIL PROTECTED] On Behalf Of Tom Irwin
> Sent: Thursday, 20 October 2005 8:40 
> To:   Biofuel@sustainablelists.org
> Subject:  Re: [Biofuel] best oil to make BD
> 
> Hello Juan,
>  
> I have found animal fat converts really easy to biodiesel. The main
> obstacle is that it is primarily a summer only fuel as it solidifies at
> about 10-14 C. A lot depends on what resources you have and your local
> climate. If you have a farm with animals that need feed, perhaps canola
> (non-GM variety) is a good candidate. It has a good oil yield per hectare
> and a reasonably low iodine value. You can feed the crushed seedcake to
> your livestock. If you are in a good sized town or city, waste vegetable
> oil is usually available from restaurants. It's quite variable and more
> difficult to convert than unused oil but you can usually get it for just
> your transport costs. If you live in a poorer area then look for wild
> castor beans. They're have large yields and are generally free for the
> picking but you can't use the seedcake for animal feed. It composts rather
> well for a garden or farm soil amendment.  It takes a stronger stomach
> than mine to deal with the aroma. Castor oil was once used an an emetic to
> cause vomiting. Other I'm sure have their favorites.
>  
> Tom Irwin
>  
>  
> 
> 
>   _  
> 
>   From: Mike Weaver [mailto:[EMAIL PROTECTED]
>       To: Biofuel@sustainablelists.org
>   Sent: Tue, 18 Oct 2005 21:28:27 -0300
>   Subject: Re: [Biofuel] best oil to make BD
>   
>   Free is the best oil to use ;-)
>   
>   Juan B wrote: 
> 
>   Hello Everyone, 
>   
>   I Would like to know what is the best vegetable oil that can
> be use to get the most biodiesel ? or it would be better to get animal
> fat?
>   
>   I looked at the tables in the website but I did not
> completely understand . 
>   thanks
>   Juan
>   
>
>   _  
> 
>___ Biofuel
> mailing list  Biofuel@sustainablelists.org
> <mailto:Biofuel@sustainablelists.org>
> <http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org
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> <http://journeytoforever.org/biofuel.html>  Search the combined Biofuel
> and Biofuels-biz list archives (50,000 messages):
> <http://www.mail-archive.com/biofuel@sustainablelists.org/>
> 
> 
>  
>   << File: ATT89996.txt >> 

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Re: [Biofuel] best oil to make BD

2005-10-21 Thread Tom Irwin




Hello Mr. Burgos,
 
I agree with Keith. It's the ethanol. Try a small batch with methanol at 20% of your oil volume and add 6.5 to 7 g per liter of KOH. You should get separation of glycerine with only an hour or so of heating at 50 C. and 12 hours of settling. In most cases I can see the glycerine begin to separate out after an hour of settling.
 
Tom Irwin
 



From: francisco j burgos [mailto:[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Fri, 21 Oct 2005 11:35:37 -0300Subject: Re: [Biofuel] best oil to make BD

Dear Mr. Tom Irwin:
thanks for your prompt replay and valuable information.
I am having a rough time in trying to transesterify tallow using ethanol and KOH, could you be kind enough and make me any process suggestions?.
I  have tryed: a tallow with ony 2.5% of FFA; 50ºC; 1% KOH;  molar fraction basis , ethanol: tallow  6:1,  up to 12 hours and obtained practically zero reaction ( none visible separation of glycerol out of gluk). Weird, dont you think?.
Yours truly,
Mr. F.J. Burgos

- Original Message - 
From: Tom Irwin 
To: Biofuel@sustainablelists.org 
Sent: Friday, October 21, 2005 10:37 AM
Subject: Re: [Biofuel] best oil to make BD

Hello  Mr. Burgos,
 
Animal fat was a natural first choice as we produce a fair amount of beef here in Uruguay. From my reading on the JTF site, I found that it was a viable candidate and there are several papers available there for using it. It made sense from a chemical standpoint as fat is essentially all saturated hydrocarbon. With only single bonded carbons I knew that polymerization at temperature is not likely. I tried about 10 or 15 small batches and never had a single bad batch with methoxide as a cataylst. Then I shifted to ethoxide and had a few successes and many failures. I shifted back to methoxide to check if my technique had gone bad. It hadn't. I still got very good separation of glycerine and all washed batches passed density, wash, chemical, and motor testing. I'm currently working on waste vegetable oil which is extraordinarily variable here. Titration testing is a must do task with each new supplier and sometimes with each batch from each supplier but I get the material for free. For me this is methoxide only territory but I'm still very curious as to why I had mostly failure but some success with ethoxide. I probably go back to it once I'm producing enough for my home and farm needs.
 
Tom Irwin
   


From: francisco j burgos [mailto:[EMAIL PROTECTED]]To: Biofuel@sustainablelists.orgSent: Wed, 19 Oct 2005 19:14:40 -0300Subject: Re: [Biofuel] best oil to make BD
Dear Mr. Tom Irwin:
Did you find by your own experience that tallow is a good raw material for producing biodiesel? or there is any bibliography that you can indicate me on the subject?.
Your help will be the most appreciated, thanks in advance.
Cordially, Mr. F.J. Burgos

- Original Message - 
From: Tom Irwin 
To: Biofuel@sustainablelists.org 
Sent: Wednesday, October 19, 2005 3:39 PM
Subject: Re: [Biofuel] best oil to make BD

Hello Juan,
 
I have found animal fat converts really easy to biodiesel. The main obstacle is that it is primarily a summer only fuel as it solidifies at about 10-14 C. A lot depends on what resources you have and your local climate. If you have a farm with animals that need feed, perhaps canola (non-GM variety) is a good candidate. It has a good oil yield per hectare and a reasonably low iodine value. You can feed the crushed seedcake to your livestock. If you are in a good sized town or city, waste vegetable oil is usually available from restaurants. It's quite variable and more difficult to convert than unused oil but you can usually get it for just your transport costs. If you live in a poorer area then look for wild castor beans. They're have large yields and are generally free for the picking but you can't use the seedcake for animal feed. It composts rather well for a garden or farm soil amendment.  It takes a stronger stomach than mine to deal with the aroma. Castor oil was once used an an emetic to cause vomiting. Other I'm sure have their favorites.
 
Tom Irwin
 
 


From: Mike Weaver [mailto:[EMAIL PROTECTED]]To: Biofuel@sustainablelists.orgSent: Tue, 18 Oct 2005 21:28:27 -0300Subject: Re: [Biofuel] best oil to make BDFree is the best oil to use ;-)Juan B wrote: 
Hello Everyone, I Would like to know what is the best vegetable oil that can be use to get the most biodiesel ? or it would be better to get animal fat?I looked at the tables in the website but I did not completely understand . thanksJuan  ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.

Re: [Biofuel] best oil to make BD

2005-10-21 Thread Keith Addison
>Dear Mr. Tom Irwin:
>thanks for your prompt replay and valuable information.
>I am having a rough time in trying to transesterify tallow using 
>ethanol and KOH, could you be kind enough and make me any process 
>suggestions?.
>I  have tryed: a tallow with ony 2.5% of FFA; 50ºC; 1% KOH;  molar 
>fraction basis , ethanol: tallow  6:1,  up to 12 hours and obtained 
>practically zero reaction ( none visible separation of glycerol out 
>of gluk). Weird, dont you think?.
>Yours truly,
>Mr. F.J. Burgos

Not very weird. It's the ethanol that's causing the problems more 
than the tallow, tallow isn't a problem. With ethanol FFA levels have 
to be  low, less than 1 ml 0.01% NaOH solution titration, and no 
water content in anything. You probably will not achieve a reliable 
process without using some methanol at least with the ethanol (which 
must be absolute). I think ethanol:tallow 6:1 on a molar basis isn't 
nearly enough.

Best wishes

Keith


>- Original Message -
>From: <mailto:[EMAIL PROTECTED]>Tom Irwin
>To: <mailto:Biofuel@sustainablelists.org>Biofuel@sustainablelists.org
>Sent: Friday, October 21, 2005 10:37 AM
>Subject: Re: [Biofuel] best oil to make BD
>
>Hello  Mr. Burgos,
>
>Animal fat was a natural first choice as we produce a fair amount of 
>beef here in Uruguay. From my reading on the JTF site, I found that 
>it was a viable candidate and there are several papers available 
>there for using it. It made sense from a chemical standpoint as fat 
>is essentially all saturated hydrocarbon. With only single bonded 
>carbons I knew that polymerization at temperature is not likely. I 
>tried about 10 or 15 small batches and never had a single bad batch 
>with methoxide as a cataylst. Then I shifted to ethoxide and had a 
>few successes and many failures. I shifted back to methoxide to 
>check if my technique had gone bad. It hadn't. I still got very good 
>separation of glycerine and all washed batches passed density, wash, 
>chemical, and motor testing. I'm currently working on waste 
>vegetable oil which is extraordinarily variable here. Titration 
>testing is a must do task with each new supplier and sometimes with 
>each batch from each supplier but I get the material for free. For 
>me this is methoxide only territory but I'm still very curious as to 
>why I had mostly failure but some success with ethoxide. I probably 
>go back to it once I'm producing enough for my home and farm needs.
>
>Tom Irwin
>
>
>
>From: francisco j burgos [mailto:[EMAIL PROTECTED]
>To: Biofuel@sustainablelists.org
>Sent: Wed, 19 Oct 2005 19:14:40 -0300
>Subject: Re: [Biofuel] best oil to make BD
>
>Dear Mr. Tom Irwin:
>Did you find by your own experience that tallow is a good raw 
>material for producing biodiesel? or there is any bibliography that 
>you can indicate me on the subject?.
>Your help will be the most appreciated, thanks in advance.
>Cordially, Mr. F.J. Burgos
>
>----- Original Message -
>From: <mailto:[EMAIL PROTECTED]>Tom Irwin
>To: <mailto:Biofuel@sustainablelists.org>Biofuel@sustainablelists.org
>Sent: Wednesday, October 19, 2005 3:39 PM
>Subject: Re: [Biofuel] best oil to make BD
>
>Hello Juan,
>
>I have found animal fat converts really easy to biodiesel. The main 
>obstacle is that it is primarily a summer only fuel as it solidifies 
>at about 10-14 C. A lot depends on what resources you have and your 
>local climate. If you have a farm with animals that need feed, 
>perhaps canola (non-GM variety) is a good candidate. It has a good 
>oil yield per hectare and a reasonably low iodine value. You can 
>feed the crushed seedcake to your livestock. If you are in a good 
>sized town or city, waste vegetable oil is usually available from 
>restaurants. It's quite variable and more difficult to convert than 
>unused oil but you can usually get it for just your transport costs. 
>If you live in a poorer area then look for wild castor beans. 
>They're have large yields and are generally free for the picking but 
>you can't use the seedcake for animal feed. It composts rather well 
>for a garden or farm soil amendment.  It takes a stronger stomach 
>than mine to deal with the aroma. Castor oil was once used an an 
>emetic to cause vomiting. Other I'm sure have their favorites.
>
>Tom Irwin
>
>
>
>
>From: Mike Weaver 
>[mailto:[EMAIL PROTECTED] 
>.net]
>To: 
>[EMAIL PROTECTED] 
>nablelists.org
>Sent: Tue, 18 Oct 2005 21:28:27 -0300
>Subject: Re: [Biofuel] best oil to make BD
>
>Free is the best oil to use ;-)
>
>Juan B wrote:
>
>>Hello Everyone,
>>
>>I Would like to know what is the best vegetable oil th

Re: [Biofuel] best oil to make BD

2005-10-21 Thread francisco j burgos



Dear Mr. Tom Irwin:
thanks for your prompt replay and valuable 
information.
I am having a rough time in trying to transesterify tallow 
using ethanol and KOH, could you be kind enough and make me any process 
suggestions?.
I  have tryed: a tallow with ony 2.5% of FFA; 
50ºC; 1% KOH;  molar fraction basis , ethanol: tallow  6:1,  up 
to 12 hours and obtained practically zero reaction ( none visible separation of 
glycerol out of gluk). Weird, dont you think?.
Yours truly,
Mr. F.J. Burgos

  - Original Message - 
  From: 
  Tom Irwin 

  To: Biofuel@sustainablelists.org 
  
  Sent: Friday, October 21, 2005 10:37 
  AM
  Subject: Re: [Biofuel] best oil to make 
  BD
  
  Hello  Mr. Burgos,
   
  Animal fat was a natural first choice as we produce a fair amount of beef 
  here in Uruguay. From my reading on the JTF site, I found that it was a 
  viable candidate and there are several papers available there for using it. It 
  made sense from a chemical standpoint as fat is essentially all saturated 
  hydrocarbon. With only single bonded carbons I knew that polymerization at 
  temperature is not likely. I tried about 10 or 15 small batches and never had 
  a single bad batch with methoxide as a cataylst. Then I shifted to ethoxide 
  and had a few successes and many failures. I shifted back to methoxide to 
  check if my technique had gone bad. It hadn't. I still got very good 
  separation of glycerine and all washed batches passed density, wash, chemical, 
  and motor testing. I'm currently working on waste vegetable oil which is 
  extraordinarily variable here. Titration testing is a must do task with each 
  new supplier and sometimes with each batch from each supplier but I get the 
  material for free. For me this is methoxide only territory but I'm still very 
  curious as to why I had mostly failure but some success with 
  ethoxide. I probably go back to it once I'm producing enough for my home and 
  farm needs.
   
  Tom Irwin
     
  

From: francisco j burgos [mailto:[EMAIL PROTECTED]To: 
Biofuel@sustainablelists.orgSent: Wed, 19 Oct 2005 19:14:40 
    -0300Subject: Re: [Biofuel] best oil to make BD
Dear Mr. Tom Irwin:
Did you find by your own experience that tallow is a 
good raw material for producing biodiesel? or there is any bibliography that 
you can indicate me on the subject?.
Your help will be the most appreciated, thanks in 
advance.
Cordially, Mr. F.J. Burgos

  - Original Message - 
  From: 
  Tom Irwin 
  
  To: Biofuel@sustainablelists.org 
  
  Sent: Wednesday, October 19, 2005 
  3:39 PM
  Subject: Re: [Biofuel] best oil to 
  make BD
  
  Hello Juan,
   
  I have found animal fat converts really easy to biodiesel. The main 
  obstacle is that it is primarily a summer only fuel as it solidifies at 
  about 10-14 C. A lot depends on what resources you have and your local 
  climate. If you have a farm with animals that need feed, perhaps canola 
  (non-GM variety) is a good candidate. It has a good oil yield per hectare 
  and a reasonably low iodine value. You can feed the crushed seedcake to 
  your livestock. If you are in a good sized town or city, waste vegetable 
  oil is usually available from restaurants. It's quite variable and 
  more difficult to convert than unused oil but you can usually get 
  it for just your transport costs. If you live in a poorer area 
  then look for wild castor beans. They're have large yields and are 
  generally free for the picking but you can't use the seedcake for animal 
  feed. It composts rather well for a garden or farm soil 
  amendment.  It takes a stronger stomach than mine to deal with the 
  aroma. Castor oil was once used an an emetic to cause vomiting. Other I'm 
  sure have their favorites.
   
  Tom Irwin
   
   
  

From: Mike Weaver [mailto:[EMAIL PROTECTED]]To: 
Biofuel@sustainablelists.orgSent: 
Tue, 18 Oct 2005 21:28:27 -0300Subject: Re: [Biofuel] best 
oil to make BDFree is the best oil to use 
;-)Juan B wrote: 
Hello Everyone, I Would like to know what is the 
  best vegetable oil that can be use to get the most biodiesel ? or it 
  would be better to get animal fat?I looked at the tables in 
  the website but I did not completely understand . 
  thanksJuan  ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
   
   
  
  

  __

Re: [Biofuel] best oil to make BD

2005-10-21 Thread Tom Irwin




Hello  Mr. Burgos,
 
Animal fat was a natural first choice as we produce a fair amount of beef here in Uruguay. From my reading on the JTF site, I found that it was a viable candidate and there are several papers available there for using it. It made sense from a chemical standpoint as fat is essentially all saturated hydrocarbon. With only single bonded carbons I knew that polymerization at temperature is not likely. I tried about 10 or 15 small batches and never had a single bad batch with methoxide as a cataylst. Then I shifted to ethoxide and had a few successes and many failures. I shifted back to methoxide to check if my technique had gone bad. It hadn't. I still got very good separation of glycerine and all washed batches passed density, wash, chemical, and motor testing. I'm currently working on waste vegetable oil which is extraordinarily variable here. Titration testing is a must do task with each new supplier and sometimes with each batch from each supplier but I get the material for free. For me this is methoxide only territory but I'm still very curious as to why I had mostly failure but some success with ethoxide. I probably go back to it once I'm producing enough for my home and farm needs.
 
Tom Irwin
   


From: francisco j burgos [mailto:[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Wed, 19 Oct 2005 19:14:40 -0300Subject: Re: [Biofuel] best oil to make BD
Dear Mr. Tom Irwin:
Did you find by your own experience that tallow is a good raw material for producing biodiesel? or there is any bibliography that you can indicate me on the subject?.
Your help will be the most appreciated, thanks in advance.
Cordially, Mr. F.J. Burgos

- Original Message - 
From: Tom Irwin 
To: Biofuel@sustainablelists.org 
Sent: Wednesday, October 19, 2005 3:39 PM
Subject: Re: [Biofuel] best oil to make BD

Hello Juan,
 
I have found animal fat converts really easy to biodiesel. The main obstacle is that it is primarily a summer only fuel as it solidifies at about 10-14 C. A lot depends on what resources you have and your local climate. If you have a farm with animals that need feed, perhaps canola (non-GM variety) is a good candidate. It has a good oil yield per hectare and a reasonably low iodine value. You can feed the crushed seedcake to your livestock. If you are in a good sized town or city, waste vegetable oil is usually available from restaurants. It's quite variable and more difficult to convert than unused oil but you can usually get it for just your transport costs. If you live in a poorer area then look for wild castor beans. They're have large yields and are generally free for the picking but you can't use the seedcake for animal feed. It composts rather well for a garden or farm soil amendment.  It takes a stronger stomach than mine to deal with the aroma. Castor oil was once used an an emetic to cause vomiting. Other I'm sure have their favorites.
 
Tom Irwin
 
 


From: Mike Weaver [mailto:[EMAIL PROTECTED]]To: Biofuel@sustainablelists.orgSent: Tue, 18 Oct 2005 21:28:27 -0300Subject: Re: [Biofuel] best oil to make BDFree is the best oil to use ;-)Juan B wrote: 
Hello Everyone, I Would like to know what is the best vegetable oil that can be use to get the most biodiesel ? or it would be better to get animal fat?I looked at the tables in the website but I did not completely understand . thanksJuan  ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/
 
 



___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the combined Biofuel and Biofuels-biz list archives (50,000 messages):http://www.mail-archive.com/biofuel@sustainablelists.org/


 
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Re: [Biofuel] best oil to make BD

2005-10-19 Thread francisco j burgos



Dear Mr. Tom Irwin:
Did you find by your own experience that tallow is a good 
raw material for producing biodiesel? or there is any bibliography that you can 
indicate me on the subject?.
Your help will be the most appreciated, thanks in 
advance.
Cordially, Mr. F.J. Burgos

  - Original Message - 
  From: 
  Tom Irwin 

  To: Biofuel@sustainablelists.org 
  
  Sent: Wednesday, October 19, 2005 3:39 
  PM
  Subject: Re: [Biofuel] best oil to make 
  BD
  
  Hello Juan,
   
  I have found animal fat converts really easy to biodiesel. The main 
  obstacle is that it is primarily a summer only fuel as it solidifies at about 
  10-14 C. A lot depends on what resources you have and your local climate. If 
  you have a farm with animals that need feed, perhaps canola (non-GM variety) 
  is a good candidate. It has a good oil yield per hectare and a reasonably low 
  iodine value. You can feed the crushed seedcake to your livestock. If you are 
  in a good sized town or city, waste vegetable oil is usually available from 
  restaurants. It's quite variable and more difficult to convert than 
  unused oil but you can usually get it for just your transport costs. If 
  you live in a poorer area then look for wild castor beans. 
  They're have large yields and are generally free for the picking but you 
  can't use the seedcake for animal feed. It composts rather well for a 
  garden or farm soil amendment.  It takes a stronger stomach than 
  mine to deal with the aroma. Castor oil was once used an an emetic to cause 
  vomiting. Other I'm sure have their favorites.
   
  Tom Irwin
   
   
  

From: Mike Weaver [mailto:[EMAIL PROTECTED]To: 
Biofuel@sustainablelists.orgSent: Tue, 18 Oct 2005 21:28:27 
-0300Subject: Re: [Biofuel] best oil to make 
BDFree is the best oil to use ;-)Juan B wrote: 
Hello Everyone, I Would like to know what is the best 
  vegetable oil that can be use to get the most biodiesel ? or it would be 
  better to get animal fat?I looked at the tables in the website but 
  I did not completely understand . thanksJuan  ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/

  
   
   
  
  

  ___Biofuel mailing 
  listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel 
  at Journey to 
  Forever:http://journeytoforever.org/biofuel.htmlSearch the 
  combined Biofuel and Biofuels-biz list archives (50,000 
  messages):http://www.mail-archive.com/biofuel@sustainablelists.org/
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Re: [Biofuel] best oil to make BD

2005-10-19 Thread Tom Irwin




Hello Juan,
 
I have found animal fat converts really easy to biodiesel. The main obstacle is that it is primarily a summer only fuel as it solidifies at about 10-14 C. A lot depends on what resources you have and your local climate. If you have a farm with animals that need feed, perhaps canola (non-GM variety) is a good candidate. It has a good oil yield per hectare and a reasonably low iodine value. You can feed the crushed seedcake to your livestock. If you are in a good sized town or city, waste vegetable oil is usually available from restaurants. It's quite variable and more difficult to convert than unused oil but you can usually get it for just your transport costs. If you live in a poorer area then look for wild castor beans. They're have large yields and are generally free for the picking but you can't use the seedcake for animal feed. It composts rather well for a garden or farm soil amendment.  It takes a stronger stomach than mine to deal with the aroma. Castor oil was once used an an emetic to cause vomiting. Other I'm sure have their favorites.
 
Tom Irwin
 
 


From: Mike Weaver [mailto:[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Tue, 18 Oct 2005 21:28:27 -0300Subject: Re: [Biofuel] best oil to make BDFree is the best oil to use ;-)Juan B wrote: 
Hello Everyone, I Would like to know what is the best vegetable oil that can be use to get the most biodiesel ? or it would be better to get animal fat?I looked at the tables in the website but I did not completely understand . thanksJuan  ___ Biofuel mailing list Biofuel@sustainablelists.org http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org  Biofuel at Journey to Forever: http://journeytoforever.org/biofuel.html  Search the combined Biofuel and Biofuels-biz list archives (50,000 messages): http://www.mail-archive.com/biofuel@sustainablelists.org/


 
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Re: [Biofuel] best oil to make BD

2005-10-18 Thread Mike Weaver




Free is the best oil to use ;-)

Juan B wrote:
Hello Everyone, 
  
I Would like to know what is the best vegetable oil that can be use to
get the most biodiesel ? or it would be better to get animal fat?
  
I looked at the tables in the website but I did not completely
understand . 
thanks
Juan
  

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[Biofuel] best oil to make BD

2005-10-18 Thread Juan B
Hello Everyone, 

I Would like to know what is the best vegetable oil that can be use to
get the most biodiesel ? or it would be better to get animal fat?

I looked at the tables in the website but I did not completely understand . 
thanks
Juan
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