Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-18 Thread Ode Coyote



  No two jugs of water are the same. [except by accident]
Distillers have a maintenance cycle.
The best way to clean up a jar is rinse it in hot distilled water to leach 
out whatever may be imbedded in the glass..or buy a brand new jar.
Cleaning the electrodes is likely to grind contaminants into the 
etchthe electrolysis process does a very good job as the surface of the 
electrode dissolves..taking everything on it along with it.
Change electrode position periodically if you are running DC 
output.  [Polarity switching does that every few minutes]


Ode


At 06:48 PM 12/17/2013 -0500, you wrote:
I am using Walmart distilled water.  Was making clear CS but last two 
batches have been slight yellow.  So, this could be water contamination or 
the jar has become contaminated?


What is the best way to clean a jar to make sure that it is not 
contaminated?


If it is the water, do you think Walmart has changed the quality of its 
distilled water?


Could it be the silver rods have contamination on them?


Yellow often means the water has something in it that kicks off oxide 
reactions. When using Food Lion house brand water from SC, I get nothing 
but yellow...but Food Loin house brand from NC, no problem. Water and 
environment is quite variable and who knows what may be a catalyst for what?



Ode



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread Ode Coyote



  The gen shuts down when conductivity reaches ~20 uS..then the 
conductivity starts dropping and averages ~10 uS when it stops dropping.
 At THAT point, uS is about the same **number** as PPM as tested by a 
device that CAN measure PPM.which a PPM meter cannot.
Conductivity and PPM aren't the same thing...but the numbers can be the 
same...or nearly so.


So, at a shut down at 20 uS and a drop back to 10 uS..that means it can be 
run back up to 20 uS and each time that's done, the drop back is about 
40-50% of the difference.
At some point the gen just won't run because the stabilized product is at 
the shut down point where 20 uS = ~20 PPM  total silver, both dissolved 
ionic and unreadable suspended [give or take because of environmental 
variables]
IOW  if the TE is heavy, fudge the PPM number up..light to no TE, fudge the 
PPM number down.


It's like counting grapefruit to see how many oranges you have in a given 
sized basketafter the grapefruit have dried up enough to be about the 
same size.
I can't afford what it takes to actually count oranges and it doesn't need 
to be exact in the 'real world' of eat fruit till you're full.


Ode


At 01:05 PM 12/16/2013 -0500, you wrote:
I thought the Silver Puppy shut down automatically when the ppm hits about 
10 ppm ?  What would cause the Silver Puppy to produce 26-30 ppm when set 
to Auto  SWAP?



On 12/15/2013 2:32 PM, JD wrote:
I made a batch of CS with my Silver Puppy and it had a slight yellow tint 
to it (usually is clear),


Yellow normally means that your ppm is too high.
so I added a little Hydrogen Peroxide to it and it turned cloudy. What 
does this mean?
It means that the ppm is over 26 ppm, so it has exceeded the solubility 
limit for the silver oxide.


I thought adding a little H2O2 is suppose to turn yellow to clear.
It does, if the ppm is below 26 to 30 ppm. Often if you wait 48 hours it 
will still clear, as some of the ionic converts to colloidal, making room 
for the precipitated silver oxide to redissolve.

Marshall



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread Ode Coyote



  It monitors conductivity like a PPM meter.
 A PPM meter cannot detect particles.
If some environmental element is prematurely kicking off reactions to 
produce non-conductive particles, all of that contaminant has to be used up 
before conductivity will go up enough to shut the machine down.

There are many things that can fool a PPM meter, which doesn't measure PPM.

The contaminant can be non-conductive or gradually leach into the water 
from the glass or the air and thus not show up as initial conductivity.
Cold water can contain high amounts of dissolved gasses and also has a 
lower saturation point than warm water which will force ions into becoming 
particles at a lower concentration.

Once formed, particles don't tend to re-dissolve...depends.

Ode




At 01:04 PM 12/16/2013 -0500, you wrote:
I had the Silver Puppy set to Automatic  SWAP.  I thought the Silver 
Puppy was automated and would shut off at the correct time?




Hi JD:

It means that you have way too many larger silver particles in the CS, 
either due to electrode eroding or perhaps a dirty/plated production 
vessel, or even poor quality distilled water. I always quality check my 
batches with a bit of H2O2, even if the batch is completely clear (mine 
are); if it clouds, I either continue adding h2o2 until it clears (and 
then use it for external/cleaning purposes), or I simply discard it.

~Jason



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread Ode Coyote



  There are reactions with electro-chemical byproducts that take a few 
days to complete after power is removed.

You will note that conductivity drops by as much as 40% over a couple of days.
That's why re-re-running a batch can make a meter reading go as high as 20 
uS where the gen shuts down ...and stays there...that % of the total gets 
smaller each time till the gen just won't run.


PPM meters [ measuring conductivity ] are only an approximation, easily 
fooled...not perfect.but they don't cost several thousand dollars and 
aren't as big as a desk.


Dissolved stuff never settles but undergoes 'Stabilization' and the product 
of stablization is whatever particulate that won't stay dissolved and goes 
into suspension.
Only suspended solid stuff can settle and if it does, it's larger than the 
size that defines colloidal

The closer it is to that definition, the longer it takes to settle.
That which meets the definition of colloidal never settles, but stays 
suspended.


BTW  The generator doesn't make particles AT ALL... [none do]   .it makes 
ONLY silver ions and hydroxl anions. [ Ag+ and OH- ]  and some hydrogen and 
oxygen gas.
Particles come later AFTER the gen does what it does...muchly while it's 
doing its thing, but still after.

Think about a car.
Exhaust is a byproduct of combustion that's made just after the act of 
combustion, as a 'result of'and  it's not the engine that's doing the 
combusting...it's the fuel/air mix.
When the byproducts meet the environment, all sorts of possibilities 
arise...like contrails if it's a cool damp day...or smog if ozone levels 
are high.


Ode





At 01:04 PM 12/16/2013 -0500, you wrote:
Just curious, isn't colloidal silver a colloid once it is made?  Why does 
it take 2 days settling?  BTW, it was probably 4-5 hours after the Silver 
Puppy shut down when I added the H2O2.




Often it will turn cloudy if you add it immediately after brewing.  Most

people wait about 2 days after brewing before adding H2O2.



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread Ode Coyote


  Yellow often means the water has something in it that kicks off oxide 
reactions.
When using Food Lion house brand water from SC, I get nothing but 
yellow...but Food Loin house brand from NC, no problem.
 Water and environment is quite variable and who knows what may be a 
catalyst for what?


Ode



At 10:31 AM 12/16/2013 -0500, you wrote:

On 12/15/2013 2:32 PM, JD wrote:
I made a batch of CS with my Silver Puppy and it had a slight yellow tint 
to it (usually is clear),


Yellow normally means that your ppm is too high.

so I added a little Hydrogen Peroxide to it and it turned cloudy.
What does this mean?


It means that the ppm is over 26 ppm, so it has exceeded the solubility 
limit for the silver oxide.

I thought adding a little H2O2 is suppose to turn yellow to clear.


It does, if the ppm is below 26 to 30 ppm.  Often if you wait 48 hours it 
will still clear, as some of the ionic converts to colloidal, making room 
for the precipitated silver oxide to redissolve.


Marshall



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RE: CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread Ode Coyote



  Ions, by definition 'one atom missing or with an excess of electrons'
[in the case of silver, missing one electron ] and have a very strong like 
charge on the electron shell / atomic level...they CANNOT cluster any more 
than you can force like poles of a magnet together.


In order for a silver particle to form, the ion must pick up an electron,
but there are no electrons in a liquid to pick up.
The only places a silver ion can find an electron to become a **metallic
silver** particle is at the air/water interface of the electrodes and the
surface of the container acting as a capacitor whereas electromagnetic
radiation is depositing electrons onto the surface of the glass.

Most particles that form are silver hydroxide  [AgOH], made when the silver
ion Ag[+] finds it's counterpart made in a one to one ratio with the
ion...the Hydroxyl anion OH[-]  [that white mist ]
Another that can form is a silver oxide particle where silver ions react
with the byproduct of electrolysis, oxygen, forming AgO. [that golden
mist..if the current is so high as to force it to form in the water vs on
the electrode]

Particles have no charge, are only held apart by a weak van der waals force
which can easily be overcome and particles be forced together by kinetic
collisions etcand agglomerate into clusters.
 Clusters are often crystalline, forming around a nucleus such as a silver
oxide particle.
H2O2 will destroy an AgO molecule leaving such a crystal without a nucleus 
and it's fractal arms will float away as smaller particles.

http://silverpuppy.com/csh2o2.html

But if H2O2 is used before all the byproducts have done whatever they are
going to do with the silver ions, H2O2 will oxidize some ions forming
[probably  Ag02 ..one of 5 possible configurations of silver oxides,
excluding possibilities of silver peroxides ]

BTW.A yellow color can be BOTH an oxide pigment AND a blue light
absorption due to particle sizeat the same time.

...and if H2O2 is in the brew water while brewing, it can set up things to
donate electrons to the ions, if done to the extreme, making shiny silver
metal flakes.
Likely, if the balance is just right...a high proportion of metallic silver
colloids can be made that way.

Ode


At 07:46 AM 12/17/2013 +1100, you wrote:

I believe the 'colloids' as referred to are ions which have clustered
together in solution, with each ion surrounded by or encased in water
after the ion clusters - particles - are formed.  Example…A bunch of
balloons all touching each other, each balloon is water and inside that
balloon is a pea, in this case the pea would be a silver ion.

Ions are in rapid and constant movement in solution {Brownian Motion}
hence it takes time for the solution to stabilise while ions are colliding
with each other forming ion clusters - bunches of balloons.

N.


--
Date: Mon, 16 Dec 2013 13:04:58 -0500
From: jd_m...@gmx.com
To: silver-list@eskimo.com
Subject: Re: CSCS  Hydrogen Peroxide = Cloudy?

Just curious, isn't colloidal silver a colloid once it is made?  Why does 
it take 2 days settling?  BTW, it was probably 4-5 hours after the Silver 
Puppy shut down when I added the H2O2.




Often it will turn cloudy if you add it immediately after brewing.  Most

people wait about 2 days after brewing before adding H2O2.



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CSCS Hydrogen Peroxide = Cloudy?

2013-12-17 Thread JD
I am using Walmart distilled water.  Was making clear CS but last two 
batches have been slight yellow.  So, this could be water contamination 
or the jar has become contaminated?


What is the best way to clean a jar to make sure that it is not 
contaminated?


If it is the water, do you think Walmart has changed the quality of its 
distilled water?


Could it be the silver rods have contamination on them?


   Yellow often means the water has something in it that kicks off
   oxide reactions. When using Food Lion house brand water from SC, I
   get nothing but yellow...but Food Loin house brand from NC, no
   problem. Water and environment is quite variable and who knows what
   may be a catalyst for what?


   Ode



Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread Ode Coyote


If it went cloudy instantly
  You did it too soon.
Wait a few days.

Ode



At 02:32 PM 12/15/2013 -0500, you wrote:
I made a batch of CS with my Silver Puppy and it had a slight yellow tint 
to it (usually is clear), so I added a little Hydrogen Peroxide to it and 
it turned cloudy.What does this mean?  I thought adding a little H2O2 
is suppose to turn yellow to clear.



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread Marshall

On 12/15/2013 2:32 PM, JD wrote:
I made a batch of CS with my Silver Puppy and it had a slight yellow 
tint to it (usually is clear),


Yellow normally means that your ppm is too high.
so I added a little Hydrogen Peroxide to it and it turned cloudy.
What does this mean?


It means that the ppm is over 26 ppm, so it has exceeded the solubility 
limit for the silver oxide.

I thought adding a little H2O2 is suppose to turn yellow to clear.


It does, if the ppm is below 26 to 30 ppm.  Often if you wait 48 hours 
it will still clear, as some of the ionic converts to colloidal, making 
room for the precipitated silver oxide to redissolve.


Marshall



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread Marshall
Yes, that is correct.  I was assuming that the wait had been done as I 
do it automatically, likely an incorrect assumption.


Marshall

On 12/15/2013 7:38 PM, Dan Nave wrote:
Often it will turn cloudy if you add it immediately after brewing.  
Most people wait about 2 days after brewing before adding H2O2.



On Sun, Dec 15, 2013 at 1:32 PM, JD jd_m...@gmx.com 
mailto:jd_m...@gmx.com wrote:


I made a batch of CS with my Silver Puppy and it had a slight
yellow tint to it (usually is clear), so I added a little Hydrogen
Peroxide to it and it turned cloudy.What does this mean?  I
thought adding a little H2O2 is suppose to turn yellow to clear.


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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread JD
I had the Silver Puppy set to Automatic  SWAP.  I thought the Silver 
Puppy was automated and would shut off at the correct time?



   Hi JD:

   It means that you have way too many larger silver particles in the
   CS, either due to electrode eroding or perhaps a dirty/plated
   production vessel, or even poor quality distilled water. I always
   quality check my batches with a bit of H2O2, even if the batch is
   completely clear (mine are); if it clouds, I either continue adding
   h2o2 until it clears (and then use it for external/cleaning
   purposes), or I simply discard it.

   ~Jason




Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread JD
Just curious, isn't colloidal silver a colloid once it is made?  Why 
does it take 2 days settling?  BTW, it was probably 4-5 hours after the 
Silver Puppy shut down when I added the H2O2.



   Often it will turn cloudy if you add it immediately after brewing.  Most
   people wait about 2 days after brewing before adding H2O2.




Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread JD
I thought the Silver Puppy shut down automatically when the ppm hits 
about 10 ppm ?  What would cause the Silver Puppy to produce 26-30 ppm 
when set to Auto  SWAP?


   On 12/15/2013 2:32 PM, JD wrote:

   I made a batch of CS with my Silver Puppy and it had a slight
   yellow tint to it (usually is clear), 


   Yellow normally means that your ppm is too high.

   so I added a little Hydrogen Peroxide to it and it turned
   cloudy. What does this mean? 


   It means that the ppm is over 26 ppm, so it has exceeded the
   solubility limit for the silver oxide.

   I thought adding a little H2O2 is suppose to turn yellow to clear.

   It does, if the ppm is below 26 to 30 ppm. Often if you wait 48
   hours it will still clear, as some of the ionic converts to
   colloidal, making room for the precipitated silver oxide to redissolve.

   Marshall




RE: CSCS Hydrogen Peroxide = Cloudy?

2013-12-16 Thread Neville
I believe the 'colloids' as referred to are ions which have clustered together 
in solution, with each ion surrounded by or encased in water after the ion 
clusters - particles - are formed.  Example…A bunch of balloons all touching 
each other, each balloon is water and inside that balloon is a pea, in this 
case the pea would be a silver ion.
Ions are in rapid and constant movement in solution {Brownian Motion} hence it 
takes time for the solution to stabilise while ions are colliding with each 
other forming ion clusters - bunches of balloons.
N.

Date: Mon, 16 Dec 2013 13:04:58 -0500
From: jd_m...@gmx.com
To: silver-list@eskimo.com
Subject: Re: CSCS  Hydrogen Peroxide = Cloudy?


  


  
  
Just curious, isn't colloidal silver a colloid once it is made?  Why
does it take 2 days settling?  BTW, it was probably 4-5 hours after
the Silver Puppy shut down when I added the H2O2.






  Often it will turn cloudy if you add it immediately after brewing.  Most
people wait about 2 days after brewing before adding H2O2.


  

CSCS Hydrogen Peroxide = Cloudy?

2013-12-15 Thread JD
I made a batch of CS with my Silver Puppy and it had a slight yellow 
tint to it (usually is clear), so I added a little Hydrogen Peroxide to 
it and it turned cloudy.What does this mean?  I thought adding a 
little H2O2 is suppose to turn yellow to clear.



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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-15 Thread Jason

Hi JD:

It means that you have way too many larger silver particles in the CS, 
either due to electrode eroding or perhaps a dirty/plated production 
vessel, or even poor quality distilled water.


I always quality check my batches with a bit of H2O2, even if the batch 
is completely clear (mine are); if it clouds, I either continue adding 
h2o2 until it clears (and then use it for external/cleaning purposes), 
or I simply discard it.


~Jason


On 12/15/2013 11:32 AM, JD wrote:

I made a batch of CS with my Silver Puppy and it had a slight yellow
tint to it (usually is clear), so I added a little Hydrogen Peroxide to
it and it turned cloudy.What does this mean?  I thought adding a
little H2O2 is suppose to turn yellow to clear.


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Re: CSCS Hydrogen Peroxide = Cloudy?

2013-12-15 Thread Dan Nave
Often it will turn cloudy if you add it immediately after brewing.  Most
people wait about 2 days after brewing before adding H2O2.


On Sun, Dec 15, 2013 at 1:32 PM, JD jd_m...@gmx.com wrote:

 I made a batch of CS with my Silver Puppy and it had a slight yellow tint
 to it (usually is clear), so I added a little Hydrogen Peroxide to it and
 it turned cloudy.What does this mean?  I thought adding a little H2O2
 is suppose to turn yellow to clear.


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