In a message dated 6/12/01 9:59:14 AM EST, [email protected] writes:

<< Subj:     Re: CS>Saline Starter Solutions: Do They Deserve Another Look?
 Date:  6/12/01 9:59:14 AM EST
 From:  [email protected]
 Reply-to:  [email protected]
 To:    [email protected]
 
 In a message dated 6/12/01 9:25:50 AM EST, [email protected] writes:
 
 << Subj:     Re: CS>Saline Starter Solutions: Do They Deserve Another Look?
  Date:  6/12/01 9:25:50 AM EST
  From:  [email protected] (Ode Coyote)
  Reply-to:  [email protected]
  To:    [email protected]
  
   Out on a laymans limb here..seeing vaugely?
   making CS involves adding electrical energy to the electrolyte [charged
  ions in even more highly charged ions or lots of spare electrons going all
  over the place?] and if NaCl in ionic form is present, the electricity
  could strip whatever bonds the salt has and re associated some of the
  chlorine ions with the silver ions. 
 
 Ken: I believe that the affinity of aqueous Na+ for aqueous Cl- is much too 
 great for aqueous silver to strip Cl- away from Na+. Roger
 
  >>

Ken: I think I'd better amend what I just said before I get pilloried. If 
silver, in the form of, say, silver nitrate were added to sodium chloride, 
there is no doubt that silver chloride will form. This is known as a 
substitution reaction, and I guess if one knew the free energies of formation 
of all the species in this reaction (in there standard or, as the case may 
be, nonstandard states), thermodynamics would predict such an outcome. Bottom 
line: I misspoke, or mistyped, or whatever. I think I'll go back to reading 
the funny papers. Roger 


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