Marshall Dudley <mdud...@king-cart.com> wrote:

>Mike Monett wrote:

[...]

>> Bleach  is  a good
>>   substitute for  canning salt, and gives a similar  white dispersion.
>>   Ammonia dissolves  it just like the silver chloride  dispersion from
>>   salt, but I did a quick search and couldn't find any equations.

>That is sodium hypochlorite, which I think ends up forming silver chloride
>and releasing oxygen.  In that case it should behave like sodium chloride
>for doing a "aslt test".
>
>Marshall

OK, thanks. I got NaOCl and NaClO2 mixed up.

For the "alst test" using NaOCl, I couldn't find any equations but it looks
like it is probably

  2Ag(+) + 2NaOCl --> 2Na(+) + O2 + 2AgCl

So the oxygen is just stuck on like O3 and H2O2, which is why household
bleach decomposes fairly rapidly. You can see graphs here or download
software to do the calculation at different temperatures:

  http://www.powellfab.com/technical_information/tools/decompsoftware.asp

Mike M


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