Ken is this because it has a high total alkalinity?  Say like we get in 
a swimming pool as the total alkalinity goes up it is harder to change 
the Ph?

Jim

Ken Provost wrote:

>On May 15, 2006, at 1:42 PM, Thomas Kelly wrote:
>  
>
>
>  
>
>>Do we simply have to neutralize the mix or do we
>>have to achieve a particular pH?
>>I suspect that many people do not split the mix
>>because it's a bit  confusing or sounds difficult.
>>    
>>
>
>
>The  FFA-soap system is a "buffer", which means
>that the combination of ingredients  tends to resist
>a change in its pH. As you add acid, the pH doesn't
>change much -- you add more, it's still pH 10. You
>add more, now it's pH 9.5. A little more, suddenly
>it's pH 4 and the FFA is floating to the top.
>
>Typically, you'll tend to overshoot with the acid before
>you get a good FFA split. Once you  remove the FFA
>from off the top, the aqueous phase below loses its
>buffering properties, and you can bring it back to
>neutrality in a straightforward (linear) fashion with
>ammonia or some such base. Confusing?  Naah :-)
>
>-K
>
>
>
>
>
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