First of all, there is a big difference between symbolic and numeric
solvers. Sympy is a symbolic library, and while it has some facilities
to do numerics, if numerics is all that you will be doing (as you
imply) you should use numpy/scipy which are created for that.

For your case check out
http://docs.scipy.org/doc/scipy/reference/generated/scipy.integrate.odeint.html

However, do not forget that you need to rewrite your second order
equation as a vector of two first order equations:

u' = v
v' = u'' = f(v, u)

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