Nick -

I think Bruce just gave a good calibration on this with his great description not only of why or why not to breathe Uranium Hexaflouride (cuz you will have to stand on your head to empty it from your lungs!) but also the relative density of the gasses in question.

Try the analogy of mixed drinks. Every good bartender knows that you put the alcohol into the glass first so that when you add the water-based stuff (tonic, seltzer, juice, etc.) the two mix naturally. If you pour the alcohol *over* the watery things, you risk the alcohol "floating" rather than mixing. We could go into the implications of low and high "proof" alcohol, etc.

But are you surprised that your bottle of wine, beer, or hard liquor hasn't seperated before you even get to pour it?

AS I think Doug mentioned, thermal energy alone is a good mixer... even without the constant stirring of wind and convection...

- Steve

Sorry. Mixed up the weight of N and O. So my question should have been, Why don't we wake up in a layer of oxygen on still nights?

Which brings us to your question about what would make me expect that a mixture would separate out into its lighter and heavier components. You tell me! Other things being equal, don't heavier things tend to sink when mixed with lighter ones?

N

*From:*friam-boun...@redfish.com [mailto:friam-boun...@redfish.com] *On Behalf Of *Douglas Roberts
*Sent:* Tuesday, June 12, 2012 2:43 PM
*To:* The Friday Morning Applied Complexity Coffee Group
*Subject:* Re: [FRIAM] atmospherics

Let's not ignore temperature: my farts are a good 20 degrees F above ambient (at present), and tend to rise before mixing into the unfortunate nearby environs. And, just in case you were wondering what the composition of a fart was:

The major components of the flatus, which are odorless, by percentage are:^[4] <http://en.wikipedia.org/wiki/Flatulence#cite_note-3>

§Nitrogen <http://en.wikipedia.org/wiki/Nitrogen>: 20--90%

§Hydrogen <http://en.wikipedia.org/wiki/Hydrogen>: 0--50%

§Carbon dioxide <http://en.wikipedia.org/wiki/Carbon_dioxide>: 10--30%

§Oxygen <http://en.wikipedia.org/wiki/Oxygen>: 0--10%

§Methane <http://en.wikipedia.org/wiki/Methane>: 0--10%

*4. ^ <http://en.wikipedia.org/wiki/Flatulence#cite_ref-3>*"Human Digestive System" <http://www.britannica.com/eb/article-45361/human-digestive-system#294193.hook>. /Encyclopædia Britannica/. Retrieved 2007-08-22.

--Doug

On Tue, Jun 12, 2012 at 12:33 PM, Roger Critchlow <r...@elf.org <mailto:r...@elf.org>> wrote:

Nick --

N2 weighs 28 gm/mole, O2 weighs 32 gm/mole, Ar weighs 40 gm/mole, CO2 weighs 44 gm/mole, and H2O weighs 18 gm/mole.

Why would anyone expect the lighter components of a mixture to fall down more than the heavier ones? If anything, you'd expect the heavier ones to concentrate toward the bottom.

And why would anyone expect a mixture to spontaneously separate into pure components? That happens in real life like where?

As it happens, CO2 is the heaviest normal component and it does pool in confined spaces often enough that CO2 alarms are available in hardware stores. Propane, C3H8, weighs 44 gm/mole and is notorious for pooling in confined spaces and then exploding, often in the bilge of a boat and spectacularly.

-- rec --

On Tue, Jun 12, 2012 at 10:44 AM, Nicholas Thompson <nickthomp...@earthlink.net <mailto:nickthomp...@earthlink.net>> wrote:

    So, somebody asked me, in my role as a weather nerd, how come the
    nitrogen in the atmosphere doesn't all fall to the bottom on still
    nights and suffocate us all.  I asked the question of
    stupid-answers-to-stupid-questions-asked-by-stupid-people.com
    <http://stupid-answers-to-stupid-questions-asked-by-stupid-people.com>
    and THEY said, well, there's just too much going on.  N molecules
    and the O molecules are just too busy, what with convection and
    windcurrents, and all, to separate, even on still nights.  Now,
    that business doesn't prevent cold molecules of Nitrogen and
    Oxygen to separate  from warm ones, or wet ones (not sure what
    that means) to separate from dry ones. I was hoping that somebody
    on FRIAM could give some sort of a clue what kind of a mixture AIR
    is?  It is suddenly seeming kinda special.

    Nicholas S. Thompson

    Emeritus Professor of Psychology and Biology

    Clark University

    http://home.earthlink.net/~nickthompson/naturaldesigns/
    <http://home.earthlink.net/%7Enickthompson/naturaldesigns/>

    http://www.cusf.org <http://www.cusf.org/>



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