unfortunatelly, there is no error. The the last entry in SMTP log (of Exchange server) is successfull authentication and that´s all. Besides, the install script http://localhost/otrs/installer.pl found IMAPS and SMTPS is working fine....
Then the problem is in the list of hosts that that SMTP server(s) are allowed to relay. You may be allowed to authenticate, but that doesn't mean that the SMTP server will relay your mail.
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