> one of web.de's sender IPs is listed into zen.spamhaus.org as the following 
> info.
> 
> 554 5.7.1 Service unavailable; Client host [82.165.159.35] blocked using z
> en.spamhaus.org; https://www.spamhaus.org/sbl/query/SBL175032

Try to send your email via web.de (browser), which might use servers with
better reputation. See https://postmaster.web.de/en/email-server

Mails classified as spam or external forwards seemingly take another route
via mout-xforward.web.de. These servers are SBL-listed by intention, most
likely because the spam probability is higher in this context. This separation
helps mout.web.de to maintain a better reputation.

Only web.de can tell why your email was routed that way.


> $ dig -x 82.165.159.35 +short
> mout-xforward.web.de.
> 
> Can anyone from web.de help with this?

The mail operators' list is better suited for this kind of question
as an alternative to the contact form link provided by Viktor:
https://www.mailop.org/

Best regards
Gerald
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