I don't ride in truly hot weather, but here in dryish southern California, I 
find even heavy weight wool to work as well or better than synthetics.  Once 
you sweat through, you get a lot of evaporative cooling.  (At least when 
moving.  I wouldn't recommend wool for just standing around in the sun.). I try 
not to ride in temps over 110°, but I wouldn't hesitate to grab a wool jersey 
in the low 100's.

I can also heartily recommend mesh wicking base layers.  I have ones from 
DeFeet and Craft that both really help in hot as well as cold weather.  
Subjectively, they make it feel ~5° cooler. They also seem to cut down on the 
salt stains on my jerseys, extending the washing intervals. (Doesn't really 
make sense, as salt should just wick right along, but they seem to help.)

Cameron Murphy
San Marcos, CA

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