Re: CS>fish aquarium air bubbler

2002-01-25 Thread Ode Coyote

 I associate this flavor with a "metallic" taste. If it is very intense, it
can be perceived as bitter.
Ken
>
>I think there is silver oxide when the process is run too long.  First when
>that happens the CS will get a bitter taste which I associate with being
>alkaline.  With silver, hydrogen and oxygen as the only elements present,
>silver oxide and silver hydroxide are the only compounds I know of that can
>do this.  Theoretically silver hydroxide could be made at the cathode, and
>silver oxide at the anode, where there is lots of free monoatomic hydrogen
>or oxygen.  Silver hydroxide spontaneously degrades to silver oxide rather
>quickly, so I believe that there can be trace amounts of it present in CS
>that is "overdone", and that is what contributes the bitter taste.
>
>Marshall
>
>
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RE: CS>fish aquarium air bubbler

2002-01-25 Thread I Anderson
Marshall D,

Thanks for your reply, and thanks for the informative link 

Try this, for an insight to the process of electrolysis, just
substitute Ag (0.79V) for chlorine at the anode.
http://scifun.chem.wisc.edu/chemweek/cl2&naoh/Cl2&NaOH.html

Silver hydroxide can only degrade if it is a compound and not
dissolved ions Ag+ and OH- . If water is being reduced to H2 gas at
the cathode (0.83V) then most likely silver is not (0.79V). H2 gas is
formed at the start of the process when no silver ion are available
for  reduction, and intermittently throughout the generating process
when Ag+ concentration is low in the cathode vicinity, or so I
theorise.

Regards
Ivan.


> -Original Message-
> From: Marshall Dudley [mailto:mdud...@execonn.com]
> Sent: Saturday, 26 January 2002 4:58 a.m.
> To: *Silver-List* (E-mail)
> Subject: Re: CS>fish aquarium air bubbler
>
>
> I Anderson wrote:
>
> > Marshall,
> >
> > You seem so sure that silver oxide exists in CS solutions ...why?
> >
> > There is little, if any, molecular oxygen atoms in d.
> water, and none
> > produced at the anode,
>
> Hun?  Electrolysis produces oxygen at the anode.
> http://webhome.idirect.com/~famistew/hydrogen/electro.htm
>
> > if silver is being ionised there as silver
> > ionises at 0.79V as opposed to the 1.6V (or there abouts)
> required to
> > rip oxygen from water molecules.
> >
>
> In the later stages of production, if the current is allowed
> to go way up, I
> have seen bubbles produced at both electrodes.  If hydrogen is being
> produced at the cathode, then 1/2 as much oxygen HAS to be
> produced at the
> anode. You can't produce one without the other beyond the
> absorption level
> of water.
>
> >
> > It is my understanding that the colour of CS solutions is a
> result of
> > the particle size.
> >
>
> Absolutely.
>
> >
> > The greyish build up on the cathode is simply reduced
> silver ions, ie
> > silver metal fluff.
>
> I think there is silver oxide when the process is run too
> long.  First when
> that happens the CS will get a bitter taste which I associate
> with being
> alkaline.  With silver, hydrogen and oxygen as the only
> elements present,
> silver oxide and silver hydroxide are the only compounds I
> know of that can
> do this.  Theoretically silver hydroxide could be made at the
> cathode, and
> silver oxide at the anode, where there is lots of free
> monoatomic hydrogen
> or oxygen.  Silver hydroxide spontaneously degrades to silver
> oxide rather
> quickly, so I believe that there can be trace amounts of it
> present in CS
> that is "overdone", and that is what contributes the bitter taste.
>
> Marshall


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Re: CS>fish aquarium air bubbler

2002-01-25 Thread Marshall Dudley
I Anderson wrote:

> Marshall,
>
> You seem so sure that silver oxide exists in CS solutions ...why?
>
> There is little, if any, molecular oxygen atoms in d. water, and none
> produced at the anode,

Hun?  Electrolysis produces oxygen at the anode.
http://webhome.idirect.com/~famistew/hydrogen/electro.htm

> if silver is being ionised there as silver
> ionises at 0.79V as opposed to the 1.6V (or there abouts) required to
> rip oxygen from water molecules.
>

In the later stages of production, if the current is allowed to go way up, I
have seen bubbles produced at both electrodes.  If hydrogen is being
produced at the cathode, then 1/2 as much oxygen HAS to be produced at the
anode. You can't produce one without the other beyond the absorption level
of water.

>
> It is my understanding that the colour of CS solutions is a result of
> the particle size.
>

Absolutely.

>
> The greyish build up on the cathode is simply reduced silver ions, ie
> silver metal fluff.

I think there is silver oxide when the process is run too long.  First when
that happens the CS will get a bitter taste which I associate with being
alkaline.  With silver, hydrogen and oxygen as the only elements present,
silver oxide and silver hydroxide are the only compounds I know of that can
do this.  Theoretically silver hydroxide could be made at the cathode, and
silver oxide at the anode, where there is lots of free monoatomic hydrogen
or oxygen.  Silver hydroxide spontaneously degrades to silver oxide rather
quickly, so I believe that there can be trace amounts of it present in CS
that is "overdone", and that is what contributes the bitter taste.

Marshall


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RE: CS>fish aquarium air bubbler

2002-01-25 Thread I Anderson

Marshall,

You seem so sure that silver oxide exists in CS solutions ...why?

There is little, if any, molecular oxygen atoms in d. water, and none
produced at the anode, if silver is being ionised there as silver
ionises at 0.79V as opposed to the 1.6V (or there abouts) required to
rip oxygen from water molecules.

It is my understanding that the colour of CS solutions is a result of
the particle size.

The greyish build up on the cathode is simply reduced silver ions, ie
silver metal fluff.

Ivan.


-Original Message-
From: Marshall Jeffus [mailto:marshalljef...@yahoo.com]
Sent: Thursday, 24 January 2002 1:08 p.m.
To: silver-list@eskimo.com
Subject: Re: CS>fish aquarium air bubbler


Thanks for the excellent suggestion.  Perhaps the bubbler whisks away
silver before it has a chance to burn.  If that's the case, it's the
movement of water that's important.  Burnt silver - that's silver
oxide, of course, which adds color to CS.  The darker the color, the
more of it, so I understand.  Also, what do you notice in the way of
oxide buildup on the electrode: the grayish solid stuff.  Less or
none?
What is your generator type?  LVDC or otherwise, what
voltage/amperage.  I'm new to all this and trying to find out what is
the best setup.
One other thing: what is your concentration (ppm).  My understanding
is that the clearer the liquid, the finer the particles.
Thanks for replying.  Like I said, I'm new to all this and am really
grateful for any input any of you may have out there on getting a
quality generator up and running.
Thanks,
Marshall
PS Melvin Wolf says that adding a very small drop of honey in
distilled water helps a lot.  Something about how it "fixes" the
electrical/magnetic properties of the water and allows for good
conduction without adding electrolyte.  Saw this on a web site.  What
do you know about this?
  Tel Tofflemire  wrote:
Marshall Jeffus ,
I use a small fish tank bubbler,  in a 2 qt glass jar. I get crystal
clear CS using the bubblier, and it stays clear. I put the bubblier in
the bottom of the jar, I use oxygen rated hose designed for breathing
bottled ox. with a stone defuser on bottom to slow the flow and make
tiny bubbles.  Some on the list said it was not the best way to do it,
so I tested for 2 days 48 hrs. using bubblier and not , my best CS was
using the bubbler...with out I got particles so large you could see
them , with bubblier, crystal clear.good luck...
Tel Tofflemire
Phoenix
Marshall Jeffus wrote:
 Please, more info on this aquarium air bubbler.  How is it used in
the process?  Do the air bubbles run over the silver electrodes?
  DJG  wrote:
I have heard this affects the CS while making it. Any comments?



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Re: CS>fish aquarium air bubbler

2002-01-23 Thread Marshall Jeffus

 Thanks for the excellent suggestion.  Perhaps the bubbler whisks away silver 
before it has a chance to burn.  If that's the case, it's the movement of water 
that's important.  Burnt silver - that's silver oxide, of course, which adds 
color to CS.  The darker the color, the more of it, so I understand.  Also, 
what do you notice in the way of oxide buildup on the electrode: the grayish 
solid stuff.  Less or none?
What is your generator type?  LVDC or otherwise, what voltage/amperage.  I'm 
new to all this and trying to find out what is the best setup.  
One other thing: what is your concentration (ppm).  My understanding is that 
the clearer the liquid, the finer the particles.  
Thanks for replying.  Like I said, I'm new to all this and am really grateful 
for any input any of you may have out there on getting a quality generator up 
and running.
Thanks,
Marshall
PS Melvin Wolf says that adding a very small drop of honey in distilled water 
helps a lot.  Something about how it "fixes" the electrical/magnetic properties 
of the water and allows for good conduction without adding electrolyte.  Saw 
this on a web site.  What do you know about this?
  Tel Tofflemire  wrote: Marshall Jeffus , 
I use a small fish tank bubbler,  in a 2 qt glass jar. I get crystal clear CS 
using the bubblier, and it stays clear. I put the bubblier in the bottom of the 
jar, I use oxygen rated hose designed for breathing bottled ox. with a stone 
defuser on bottom to slow the flow and make tiny bubbles.  Some on the list 
said it was not the best way to do it, so I tested for 2 days 48 hrs. using 
bubblier and not , my best CS was using the bubbler...with out I got particles 
so large you could see them , with bubblier, crystal clear.good luck... 
Tel Tofflemire 
Phoenix 
Marshall Jeffus wrote:  Please, more info on this aquarium air bubbler.  How is 
it used in the process?  Do the air bubbles run over the silver electrodes? 
  DJG  wrote: I have heard this affects the CS while making it. 
Any comments?


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Re: CS>fish aquarium air bubbler

2002-01-22 Thread Tel Tofflemire
Marshall Jeffus ,
I use a small fish tank bubbler,  in a 2 qt glass jar. I get crystal
clear CS using the bubblier, and it stays clear. I put the bubblier in
the bottom of the jar, I use oxygen rated hose designed for breathing
bottled ox. with a stone defuser on bottom to slow the flow and make
tiny bubbles.  Some on the list said it was not the best way to do it,
so I tested for 2 days 48 hrs. using bubblier and not , my best CS was
using the bubbler...with out I got particles so large you could see them
, with bubblier, crystal clear.good luck...
Tel Tofflemire
Phoenix

Marshall Jeffus wrote:

>  Please, more info on this aquarium air bubbler.  How is it used in
> the process?  Do the air bubbles run over the silver electrodes?
>
>   DJG  wrote:
>
>  I have heard this affects the CS while making it. Any
>  comments?
>
>
> ---
> Do You Yahoo!?
> Send FREE video emails in Yahoo! Mail.


Re: CS>fish aquarium air bubbler

2002-01-22 Thread Marshall Jeffus

 Please, more info on this aquarium air bubbler.  How is it used in the 
process?  Do the air bubbles run over the silver electrodes?
  DJG  wrote: I have heard this affects the CS while making it. 
Any comments?


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