Re: [biofuels-biz] Greenhouse gas 'plan B' gaining support

2003-12-13 Thread dcande01

Heard it here first?  Those of you familiar with Levi's Goat of Mendez  
have read it on his arms
Solve  Coagula
Fred

On Friday, Dec 12, 2003, at 06:49 US/Eastern, Keith Addison wrote:

 Contraction  Convergence - you read it here first, folks, three  
 years ago:

 http://infoarchive.net/sgroup/BIOFUEL/1539/
 Subject: climate change, 10 Dec 2000

 http://infoarchive.net/sgroup/BIOFUEL/27393/
 Subject: Contraction and Convergence, 23 Aug 2003

 Check out Aubrey Meyer's Global Commons Institute (GCI):
 http://gci.org.uk/

 For an introduction to the ideas behind Contraction and Convergence,  
 see:
 http://www.gci.org.uk/contconv/cc.html

 Some info about the book, Contraction  Convergence - The Global
 Solution to Climate Change:
 http://www.gci.org.uk/ccbook.html

 -

 http://www.newscientist.com/news/news.jsp?id=ns4467
 New Scientist

 Greenhouse gas 'plan B' gaining support

 19:00 10 December 03

 The Kyoto protocol is dying a death of a thousand cuts. Last week,
 the US reiterated that it wants nothing to do with the sole
 international agreement designed to save the world from runaway
 global warming.

 The European Union, Kyoto's main promoter, revealed that most of its
 members will not meet their treaty's obligations. And Russia once
 again seemed to be on the point of wrecking the protocol completely.

 These blows follow a history of bureaucratic squabbling and political
 posturing by the protocol's signatories, and many observers now fear
 that it has been damaged beyond repair. So does the world have a plan
 B for bringing the emissions of greenhouse gases under control?


   Contraction  Convergence model

 The answer is yes, and it goes by the name contraction and
 convergence, or CC. The idea has been around for a decade, but
 lately it has been gaining ever more influential converts, such as
 the UK's Royal Commission on Environmental Pollution, the UN
 Environment Programme, the European Parliament and the German
 Advisory Council on Global Change, which last week released a report
 supporting the idea.

 A source within the German delegation in Milan said this week that
 his government was taking the idea very seriously indeed. Even
 observers outside the environmental establishment, such as the World
 Council of Churches, back the proposal.

 Simple and fair

 For the past two weeks, representatives from around the world have
 been in Milan, Italy, for COP9, the ninth annual meeting of
 signatories to the 1992 Framework Convention on Climate Change. Many
 of them now privately admit that CC is what we have been waiting for.

 While Kyoto has become a convoluted, arbitrary and short-term measure
 to mitigate climate change, CC could provide a simple, fair,
 long-term solution. And above all, it is based on science rather than
 politics.

 The contraction in CC is shorthand for reducing the total global
 output of greenhouse gases. At the Earth Summit in Rio in 1992, the
 world's governments agreed to act to prevent dangerous climatic
 change. The Kyoto treaty was their first fumbling attempt to meet
 that pledge, and if implemented would set emissions targets for
 industrialised nations for the period 2008 to 2012.

 But increasing numbers of delegates are viewing Kyoto as part of the
 problem, not part of the solution. Its labyrinthine rules allow
 nations to offset emissions with devices such as carbon-sink
 projects, and are so complex they are virtually unenforceable. Even
 if Kyoto becomes international law, it cannot be the blueprint for
 future deals beyond 2012. A new start is needed.

 These delegates argue that it is time to get back to first principles
 to find a formula to fight the dangerous climate change mentioned
 in the Rio treaty. And there is an emerging consensus that
 dangerous means any warming in excess of 2 ¡C above pre-industrial
 levels; so far temperatures have risen by 0.6 ¡C.

 Drastic cuts

 To keep below the 2 ¡C ceiling will mean keeping global atmospheric
 concentrations of carbon dioxide, the most important greenhouse gas,
 below about 450 parts per million. But because CO2 and other
 greenhouse gases linger in the atmosphere for a century or more,
 staying below that ceiling will mean drastic cuts in emissions over
 the next 50 years.

 The Royal Commission on Environmental Pollution has decided that a 60
 per cent cut in global emissions by 2050 is needed, which the British
 government has adopted as its national target. But if the world is to
 manage such a transformation, then hard choices will have to be made.

 And that is where the convergence part of CC comes in.
 Industrialised nations have so far done most of the polluting. The US
 emits 25 times as much CO2 per head as India, for example, but if
 pollution is to be rationed, that cannot carry on.

 So under the CC proposals, national emissions will converge year by
 year towards some agreed target based upon each country's population
 (see graph). In effect, by a target 

Re: [biofuels-biz] Fwd: RE: [solar-ac] Solar Geothermal

2003-12-13 Thread Brian Kelly

Solar electric is becoming a little more efficient.
Sharp has a 185 watt panels that has cells w/ an
efficiency of 17.48% (the whole module is 14.23%
though) (yeah, I'm a solar electric installer). 
Do any of you consider geothermal for heating and
cooling??? Relies on the constant temperature(about 55
degreesF in NJ) that exists just a few feet in the
ground. In terms of energy input, the systems
advertise that they are 300% efficient. 
--- Hakan Falk [EMAIL PROTECTED] wrote:
 
 
 David,
 
 The last 20 years I bought an AC unit per year on
 average here in Spain,
 always reversible to heat pump. I am a little bit
 lazy and found a very
 good dimensioning method. Instead of calculating, I
 have used the known
 margin of error in existing methods.
 
 I ask the sales person what he recommends. He will
 do some sort of
 calculation and look in tables, then he would look
 at me with the expert
 look and suggest for example 3,000 watt (never
 smaller), then I will look
 equally seriously and buy the 1,000 Watt. He will
 always say that in that
 case he cannot guarantee that it will work and I
 will always reply that it
 doesn't matter.
 
 In the 20 cases I have never had a capacity
 problem. I had some problems
 with functionality, but that is expected with AC
 units who have an average
 life span of 8 years (rotary compressors).
 
 Hakan
 
 
 At 20:15 12/12/2003, you wrote:
  Hi Hakan,
  
  I'm not familiar with any companies succeeding in
 this field.  (except
  special projects companies working on gov't
 subsidized systems)
  
  I would like to see solar ac find some
 economically feasible
  markets.  Will take some good engineering and
 creative thinking (to find
  the right market)
  
  David B.
  
 
 
 
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[biofuels-biz] Re: Help for new bio fuel plant?

2003-12-13 Thread girl_mark_fire

Hello!
For small-scale information,  www.journeytoforever.org has the 
best info.

For commercial production, please have a look at the 'technical 
papers'  and other information at www.me.iastate.edu/biodiesel 
for information from Iowa State University.
 
If I understand correctly, there is no plant in the United States 
which uses animal tallow exclusively (other than whatever 
animal fats are in waste edible oils from restaurants). The Iowa 
State University research focuses partly on waste animal fats as 
a feedstock. I would like to hear if this is done in Europe.
mark


--- In biofuels-biz@yahoogroups.com, Bozidar Hojan 
[EMAIL PROTECTED] wrote:
 
 
 
 
 Hi, 
 
 I got curious about bio-fuels,especially bio-diesel as we began 
to discuss about it on a state level here at us.
 So I would ask for help from someone experienced in 
bio-fuels, who would be interested in helping me to start up a 
new energy production facility.I am interested in bio-diesel, could 
start with cattle tallow,used edible oil and then organize oil 
rapeseed, as raw materials. For start I would like equipment for 
smaller quantities,to collect experience and later on that could 
be a bigger plant with up to 5.000 t/yearly.
 Thanks for help with equipment for start,for help with your 
experience with producing bio-diesel,ideas how to start with 
experimental equipment complet/plant.
 
 Regards from Zagreb,Croatia,Europe
 
 [EMAIL PROTECTED]
 
 
 Yahoo! Groups Sponsor
 Biofuels at Journey to Forever
 http://journeytoforever.org/biofuel.html
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Re: [biofuels-biz] Fwd: RE: [solar-ac] Solar Geothermal

2003-12-13 Thread Hakan Falk


Brian,

PV is getting more efficient and the 8-10% efficiency cheaper, so let us 
hope that we get the 60% price reduction on PV that is necessary for it to 
really take off. It should of course be combined wit easy no frill grid 
connections. It will make a lot of difference, but maybe not that much on 
solar AC with PV cells, that must be a low priority and thermal solar will 
be interesting.

Did you read this that I posted a short while ago,

Plug-in HVAC Cogeneration.
http://energy.saving.nu/plugin/hvacpump.shtmlhttp://energy.saving.nu/plugin/hvacpump.shtml
 


I also did this, which has to be revised and improved. It was written in a 
haste and need to be more descriptive,

Moving energy/temperatures for HVAC.
http://energysavingnow.com/hvac/energymove.shtmlhttp://energysavingnow.com/hvac/energymove.shtml
 


Did not have too much feedback on it, other than the fair comment, of that 
the latter was unclear and not good. Geothermal, as you define it, is heat 
pump technology and the geothermal is only one part of this and because 
that the constant earth temperature is often at this optimum temperatures 
for heat pumps. It is a question of cost effective and balance. In an area 
like Florida or most of Spain, the air temperatures are most of the time in 
that range and to use the earth temperatures might not be cost efficient. 
In Sweden, you have to use geothermal for heat pumps, otherwise the heat 
pumps are not effective a large part of the year.

As a solar installer, I like your comments on this,

Plug-in Solar power.
http://energy.saving.nu/plugin/pluginsolar.shtml

and this,

The Grid.
http://energy.saving.nu/thegrid/

Sorry if I take the opportunity, but it is always interesting with feedback 
that is other than my natural deficiencies in English, even if they are 
very valuable also.


Hakan

At 03:12 13/12/2003, you wrote:
Solar electric is becoming a little more efficient.
Sharp has a 185 watt panels that has cells w/ an
efficiency of 17.48% (the whole module is 14.23%
though) (yeah, I'm a solar electric installer).
Do any of you consider geothermal for heating and
cooling??? Relies on the constant temperature(about 55
degreesF in NJ) that exists just a few feet in the
ground. In terms of energy input, the systems
advertise that they are 300% efficient.
--- Hakan Falk [EMAIL PROTECTED] wrote:
 
  
  David,
  
  The last 20 years I bought an AC unit per year on
  average here in Spain,
  always reversible to heat pump. I am a little bit
  lazy and found a very
  good dimensioning method. Instead of calculating, I
  have used the known
  margin of error in existing methods.
  
  I ask the sales person what he recommends. He will
  do some sort of
  calculation and look in tables, then he would look
  at me with the expert
  look and suggest for example 3,000 watt (never
  smaller), then I will look
  equally seriously and buy the 1,000 Watt. He will
  always say that in that
  case he cannot guarantee that it will work and I
  will always reply that it
  doesn't matter.
  
  In the 20 cases I have never had a capacity
  problem. I had some problems
  with functionality, but that is expected with AC
  units who have an average
  life span of 8 years (rotary compressors).
  
  Hakan
  
  
  At 20:15 12/12/2003, you wrote:
   Hi Hakan,
   
   I'm not familiar with any companies succeeding in
  this field.  (except
   special projects companies working on gov't
  subsidized systems)
   
   I would like to see solar ac find some
  economically feasible
   markets.  Will take some good engineering and
  creative thinking (to find
   the right market)
   
   David B.
   
  
  
  
  Yahoo! Groups Sponsor
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Re: [biofuels-biz] Re: Help for new bio fuel plant?

2003-12-13 Thread Bozidar Hojan


 Thanks for help! I go on,have more informations every day!
 Regards
 Theodor(Bozidar) 

girl_mark_fire [EMAIL PROTECTED] wrote:
Hello!
For small-scale information,  www.journeytoforever.org has the 
best info.

For commercial production, please have a look at the 'technical 
papers'  and other information at www.me.iastate.edu/biodiesel 
for information from Iowa State University.

If I understand correctly, there is no plant in the United States 
which uses animal tallow exclusively (other than whatever 
animal fats are in waste edible oils from restaurants). The Iowa 
State University research focuses partly on waste animal fats as 
a feedstock. I would like to hear if this is done in Europe.
mark


--- In biofuels-biz@yahoogroups.com, Bozidar Hojan 
[EMAIL PROTECTED] wrote:
 
 
 
 
 Hi, 
 
 I got curious about bio-fuels,especially bio-diesel as we began 
to discuss about it on a state level here at us.
 So I would ask for help from someone experienced in 
bio-fuels, who would be interested in helping me to start up a 
new energy production facility.I am interested in bio-diesel, could 
start with cattle tallow,used edible oil and then organize oil 
rapeseed, as raw materials. For start I would like equipment for 
smaller quantities,to collect experience and later on that could 
be a bigger plant with up to 5.000 t/yearly.
 Thanks for help with equipment for start,for help with your 
experience with producing bio-diesel,ideas how to start with 
experimental equipment complet/plant.
 
 Regards from Zagreb,Croatia,Europe
 
 [EMAIL PROTECTED]
 
 
 Yahoo! Groups Sponsor
 Biofuels at Journey to Forever
 http://journeytoforever.org/biofuel.html
 List messages are archived at the Info-Archive at NNYTech:
 http://archive.nnytech.net/
 Please do NOT send Unsubscribe messages to the list 
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[biofuel] bad news about EPA registration Re: Commercial production

2003-12-13 Thread skillshare

Hi Keith and others,

I've got more info about the EPA registration issue and it's not 
good. I sent the info that Keith compiled  ( 
http://archive.nnytech.net/sgroup/BIOFUEL/27488/ ) to Jon Van 
Gerpen of Iowa State University who then contacted the EPA 
about the discrepancy in their registration process (I'm not sure 
who exactly he spoke with).  

I didn't get full details yet from Dr Van Gerpen (especially the 
question of whom it was that he spoke with, but Ill try and find 
out next week) , but here's what he wrote to me:

Quote: Regarding my email exchange with EPA.  It was pretty 
much a bust.  I  explained to them my understanding of the 
registration process and then asked them for the rationale they 
use to categorize biodiesel as an atypical fuel.  In the response I 
received, they confirmed that my understanding of the process 
was correct but ignored my request for the rationale.

I can't fault them too much for not being responsive.  We're all 
busy.   However, I still think there is no sound technical basis for 
not  including biodiesel as a non-baseline fuel.  This would 
allow it to qualify  for the small business exemptions.  I think the 
most likely path to  getting this would be to find a friendly senator 
who might be willing to push the EPA to loosen up. 
(end quote)


We have been organising here this fall in Northern California to 
talk about forming a statewide B100 consumers' association, as 
a sort of partnership with the several small biodiesel 
distributors, 'small business users' (ie people like Thanksgiving 
Coffee who run a few vehicles on B100 but aren't considered a 
fleet in the traditional sense), and passenger car biodiesel 
consumers- underserved markets, and ones hard-hit by IWP's 
quality problems this fall. 

  The first item on the agenda besides 'how to greet the industry 
when it comes here for it's winter convention' is
'how to do a legal challenge to the EPA registration rules so we 
can have legal local production'.

 I agree with Dr Van Gerpen's suggestion about finding a 
politician to take it up, but we're still in the beginning stages of 
debating strategy on this in our area, and more importantly trying 
to raise awareness about this issue locally. More info coming 
shortly.
.
 I think a legal challenge would have to hinge partly on a 
re-definition of 'small producer'. Currently the small business 
exemption for non-baseline fuel is for operators making less 
than 50 million dollars a year. That would leave the NBB high 
and dry, as no one is making that much from biodiesel 
production in the US. 

My personal proposal for redefining 'small producer' is someone 
making a half million gallons a year or less. This is considered 
pilot plant scale for the industry- but it's a reasonable scale for 
local sourcing and production. I think it'd be less threatening to 
the industry than demanding the current non-baseline 
registration rules, which would exempt everyone in the industry 
big and small from the Tier 1/Tier 2 testing, if followed to the 
letter. 


Also another heads-up: someone whom I know in the NBB 
contacted me about their winter convention- they're having a 
'small producer panel'  discussion in the convention. They're 
trying to get Jim Caldwell to be one of the speakers,and didn't 
know yet who the others would be. 

My acquaintance in the NBB read the official statement about the 
panel to me- and it said something like 'while we recognise that 
small producers have a role to play in the development of the 
biodiesel market (which I read rather cynically!),   but  [I 
paraphrase here cause I can't remember the actual language]  
the issues of quality need to be addressed' or something like 
that.

Now this was amusing to me to hear. We've had serious 
problems with bad quality substandard non-spec biodiesel 
coming out of NBB member Imperial Western Products' plant 
this summer and fall, with drivers having big repair bills as a 
result, but the NBB has no clue that this is happening and still 
believes that small producers would have quality control 
problems. I asked my acquaintance in the NBB if he had any 
idea about this issue and of course no one had  told them. As 
usual the NBB is somewhat out of touch on B100 issues.

 Amusingly, the next thing scheduled on the NBB convention 
agenda right after the small producer discussion is suposed to 
be a tour of the IWP plant. I realy think they all have no idea that 
this sort of thing has been happening. Remember it also 
happened with World Energy this spring, causing some 
consumers to question 'yellow grease'-sourced B100 after 
THEIR repair bills occurred. ALso remember that those who 
cught the problem were basically watchdog grassroots people- if 
no one was watching, or everyone was getting their B100 from a 
regular gas station, it would have taken a lot longer to figure out 
that there was a problem.

By the way my reading of the above NBB statement is that the 
NBB lumps 

Re: [biofuel] A Tale of Two Countries

2003-12-13 Thread Keith Addison

Hi Alan

Keith Addison wrote:
  http://www.alternet.org/story.html?StoryID=17333
 
  A Tale of Two Countries
 
  By David Morris, AlterNet
  December 8, 2003

This brings to mind an old saying about the difference between American
and Japanese car companies.

When a new standard is imposed American car companies will hire lawyers
to figure out how to get around or tear down the new standard.

Japanese car companies will hire engineers to figure out how to meet or
exceed the standard.

The Japanese manufacturers' statement that selling their first
generation hybrids at a loss was an investment in the future was
absolutely correct.  The buyers of the first few years of hybrids were,
effectively, beta testers, and the manufacturers were paying them for
the research data by taking a loss on the cars.


AP

Do you remember this news item about suppliers and quality? 
Interesting comparison between US and Japanese automakers.

Best

Keith


Study: Suppliers skimp on quality to meet automakers' cost-cutting demands

July 25, 2001

BY ED GARSTEN
ASSOCIATED PRESS

DETROIT -- A little thinner coating on the trim, a few less stitches 
on seating -- just some examples of how automotive suppliers are 
skimping on quality in order to meet cost-cutting demands of U.S. 
automakers, a study found.

HIGHLIGHTS OF THE STUDY
Some of the highlights of a study performed by Birmingham, 
Mich.-based Planning Perspectives on how cost cutting has effected 
quality among 261 major suppliers to the automotive industry:

QUALITY: 7 percent to 9 percent lowered quality to meet automakers' 
price cut demands; 20 percent improved quality; 75 percent maintained 
current quality standards.

TECHNOLOGY REDUCTION: 20 percent withheld some new technology from automakers.

SERVICE REDUCTION: 7 percent to 18 percent reduced services to 
automakers, such as consulting engineers.

PRICE VS. QUALITY: General Motors Corp., Ford Motor Co. and 
DaimlerChrysler AG place two to three time greater emphasis on price 
than quality when choosing suppliers, while Toyota and Honda balance 
price with quality.

Suppliers who were pressed by automakers to lower their prices to the 
point where it was difficult to turn a profit either maintained or 
lowered the quality of their products, according to the 2001 North 
American Automotive Supplier Survey, performed by Birmingham, 
Mich.-based Planning Perspectives.

The study looked at responses from 261 suppliers received between 
March and May.

Only 20 percent of the suppliers said they were improving quality. 
Seventy-five percent said they're keeping quality as it is now, said 
John Henke, president of Planning Perspectives and the author of the 
study released this week.

Faced with a slowing automotive market coming off the record sales 
pace of 2000, automakers have put price reduction edicts of from 3 
percent to 8 percent or more on their suppliers.

The challenge has been for suppliers to cut prices enough to hang 
onto their contracts while remaining profitable. The answer, 
according to the study, has been to cut corners.

The study found the situations were consistent with suppliers 
regardless of their size. But Henke said occupant safety has not 
suffered.

The goods are still at a very high quality, Henke said. They look 
for areas where you can reduce quality without jeopardizing safety.

Henke said as other cost-cutting tactics, suppliers are cutting back 
support and services to the automakers, and withholding certain new 
technologies and extra testing.

Both extra services and technology almost always have a relationship 
to the quality of the product, Henke said. They're meeting the 
specifications of the automakers but not moving forward on quality.

Delphi Automotive Systems, the largest supplier in North America, 
took issue with the study and said its quality has steadily improved.

Delphi is committed to providing our global customers with 
industry-leading technology and high quality and cost-effective 
products. We strive to achieve this through the Delphi manufacturing 
system which is our approach to lean manufacturing and by partnering 
with our customers to meet their objectives, Delphi said in a 
statement.

The study concluded that suppliers must abandon the past practice of 
applying one business plan to all their customers and adapt the 
practice of developing individual plans appropriate to each automaker.

General Motors Corp., Ford Motor Co. and DaimlerChrysler AG place 
two to three times greater emphasis on price than quality when 
selecting suppliers, while Toyota and Honda, the quality leaders, 
virtually balance price with quality, the study said.

Toyota and Honda provide the most help to suppliers to reduce 
internal cost and maintain quality, Henke said. In that way, he 
said, suppliers' profit margins are protected.

Before Toyota grants a supplier contract it requires the company to 
jump an enormous number of hoops to decide if it's qualified, Henke 
said. If 

Re: [biofuel] What's the true story on ethanol?

2003-12-13 Thread murdoch

On Fri, 12 Dec 2003 02:41:35 +0900, you wrote:

Hi MM

Although I am not buying that production of ethanol requires more 
energy than it
produces,

It could do - did you see this thread?

Expert pans ethanol
http://infoarchive.net/sgroup/biofuel/30146/1/


Well, I liked your dissection of Patzek's research, as you point out the
non-sustainability of the types of agriculture he's looking at, and the
irrelevance of his work to sustainable methods for growing things and making
fuels.

Aside: I do want to say that awhile back you shot down my interest in
completely-different non-natural production of biofuels and ethanol and
what-not, from such schemes as PV-to-H2-to-C2H6O, or whatever, and I did not
agree at all with this, but it didn't seem important to argue it at length at
that time.  I know what I think on the matter.  If it can be done sustainably
then I'm for taking a look at it, whether it fits with the way things were done
in the past or not.  This to me is relevant in the sense that, basically,
ethanol is ethanol.  It's a chemical.  What is not the same is the derivation
method and the analysis of the sustainability of those methods.


http://infoarchive.net/sgroup/biofuel/30217/1/

Brazil used subsidies very effectively. Hoagy posted some great links 
on ethanol in Brazil recently, interesting discussion, check previous 
posts.

I'll have to look around for that.  I think this is what Im getting at.  99% of
ethanol debates in the US at the national news-journal level are framed in
terms of ADM and others and big-farm subsidies.  There is virtually no coverage
of the idea that there are different ways to look at this.  Really, no
mainstream coverage at all, in any way, that I'm aware.

So, I think what I'm fishing for is to have a better idea of what I'm for, here,
and not just an idea of what I'm against.  As to Brazil, in addition to what
you've said in one of those links, I'll be wanting to look at the extent to
which they use plant waste in the making of ethanol.  This is just an
under-emphasized aspect of biofuels, doubtless thoroughly covered by those here,
but not so much in the NYT.

MM

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[biofuel] Fwd: Re: [solar-ac] Markets

2003-12-13 Thread Hakan Falk


Thought that this could be interesting for the biofuel group also.

Hakan

Cornelius,

I agree with you, but found something that is very interesting and that I
would like to explain. The cardboard soaked with water is a version of a
more than 2000 year old method to cool the air and even more important to
dry it. It is a version of the rope curtains in the entrance door of the
house, which often had a pipe from a stream of water keeping it wet with
fresh new cold water. You still find this in many developing countries. To
work, the water temperature must be lower than the air temperature,
otherwise it could have the opposite effect.  When the air passes the
curtain, it will cool down and if it is very humid, it will also lose a lot
of its water content, according to the laws of relative humidity
(Molliere). After it has passed the curtain, it will again warm up and also
according to the laws of humidity, it will have a lower relative humidity
than it was before it entered the curtain. Very smart and a good example of
that people was much smarter engineers in the past, than we educated
engineers many times belive.

Of course, if you do it wrong and the water is warmer than the air and or
not renewed from a cold source, the effect is the opposite and then we
prove how little the modern engineers really know or understand. Made in
the right way, the curtain is actually a traditional version of the modern
cooling tower in an AC system and very environment friendly. When you
understand how it works, it is possible to tweak the efficiency a little
bit or at least not make mistakes that worsen the situation.

By the way, the old Arabian, Greek and Roman gardens, with its large number
of fountains, worked the same way. They provided shadow and was drying the
air. You only have to visit the gardens of Alhambra, Spain. in a hot August
day and the effect is obvious.

However, the higher efficiency of a solar heated cooling system would make
a difference in the situations that you describe and result in a better
production of poultry. I do not think that it is much more to say about it
and you are right. I only wanted to add some Arab engineering history to it.

Hakan

At 15:22 13/12/2003, you wrote:
 There is no shortage of markets for effective airconditioning with an
 economical operating cost.  I hardly know where to begin.  Third world
 counties are in dire need of economical cooling even if only for the
 daylight hours.  But leave this aside for now.  Look at the farming
 industry.  Large scale poultry houses are about 20,000 sq. ft each.  They
 are cooled by pulling air the length of the building (500') after it has
 passed through a cardboard wall panel soaked with water.  If the humidity
 outside is already 90% what good do you suppose it does to rehumidify it?
 
 A solar AC unit could pull moisture from the air as it passed a heat
 exchanger.  Birds die with the humidity inside the building reaches 95%
 when the air temp inside is over 90F.  I have seen 60 tons of birds die in
 45 minutes in July.  Your expertise could dramatically improve the
 livability of these birds.
 
 We work with the Native American populations on reservations in the
 USA.  They reject many modern conveniences on principle but also on
 environmental grounds.  A nonpolluting and inoffensive cooling system
 could be very attractive to them.
 
 Lets build some of these units and I bet the market will come to us.
 
 Cornelius A. Van Milligen
 Kentucky Enrichment Inc.
 www.kentuckyenrichment.com
 [EMAIL PROTECTED]



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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Thomus Patton

Hello
 
I'm a chemical engineering student working on a biodiesel production facility 
design project with my senior design group at NCSU.  We are only in the initial 
stages and do not have a lot of kinetic data yet, but I would think that 
removing methanol would certainly be detrimental to your yield.  I do not know 
if the resulting equilibrium shift towards reactants would be more than you 
were willing to give up or not, but something tells me it would certainly be 
noticeable based on the fact that most recipes suggest using a large excess of 
alcohol to push equilibrium towards the products (biodiesel and glycerin).

lagonisa [EMAIL PROTECTED] wrote:
Hello to all:

I have read some contributions to this group about methanol recovery 
and the different options. I would like to try the recovery before 
separation of bio and glycerol using a condenser that would receive 
the methanol fumes after finishing the reaction. I have a processor 
were I get 75¼C-80¼C as it is pressurized to 0,7 bar. The problem is 
that I have also read that due to the reversibility of the reaction, 
if after finishing my reaction I remove the methanol by reducing the 
pressure and directing the vapours through a condenser, or even I 
apply vacuum after despressurizing to do it faster, I can get a 
reduction of the conversion transforming some biodiesel into oil 
again. My question is: has anyone in this group measured or 
experienced this fact? Is there a real decrease of the yield or 
conversion?

Lagonisa



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[biofuel] ARIANA 796iEV + 5 Mins Super Chaerger ARIANA iEV Commuter System

2003-12-13 Thread Tricia Liu

This Malaysian EV company is looking for dealers, they will have their US sales 
very soon.
Interested parties can contact 
Youhana Jafari
deputy manager 
Arian Motors corp.
to get dealership! 
The retail price  for ARIANA 796 iEV is 18400 USD.
I don't have full spec, it's about 75MPH, 170miles range. 
Members in Malaysia, anyone has more info?  Please send or post!



We are setting up this company in California, United States at present, and in 
the middle of 2004,we would start 
our vehicles' sale with our specific charger. (ARIANA iEV Commuter system).

We have registered this charger and have patent for it, and until mass 
production of this product, we can not give 
it's technical specification.Generally, the operation of this charger is as 
following : All batteries' cells are charged in a 
specific method, simultaneously and separately,during 5 minutes ,by controlling 
battery's temperature and 
considering it's specifications.

By considering that we want to mass-produce this product in California!

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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Ken Provost


On Saturday, December 13, 2003, at 12:02  PM, Thomus Patton wrote:

 I would think that removing methanol would certainly be detrimental
 to your yield.

So would I. Most of the methanol goes into the aqueous (glycerine)
layer anyway, so you can recover that portion by distilling the glyc
layer alone, after separating.  -K


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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Appal Energy

Lagonisa,

 The problem is
 that I have also read that due to the reversibility of the reaction,

The reaction is not exactly reversible. Reversability would require the
three glycerides and the glycerol recombining. That doesn't happen. Once the
glycerol is cleaved it is out of the picture.

You're suggesting MeOH recovery at the point where the reaction is complete
and the glycerol has yet to settle out. However, that's not altogether
adisable due to the continual mixing of excess catalyst with the methyl
ester.

If you reduce the volume of alcohol via evaporation at this point there
would be a propensity for some of the ester to fracture (back crack) into
FFAs and then convert to soap. Mind you that back cracking can only occur
up to the point that all the catalyst is consumed in soap making.

If you can monitor the reaction and insure that the balance of catalyst is
infintesimally small beyond what is required to guarantee 100% completion,
erego yielding but a small and controlled amount of extra soap production,
then there might be some merit in extracting the alcohol prior to the
glycerin cocktail settling.

Otherwise? Probably none.

Todd Swearingen

 Hello to all:

 I have read some contributions to this group about methanol recovery
 and the different options. I would like to try the recovery before
 separation of bio and glycerol using a condenser that would receive
 the methanol fumes after finishing the reaction. I have a processor
 were I get 75¼C-80¼C as it is pressurized to 0,7 bar. The problem is
 that I have also read that due to the reversibility of the reaction,
 if after finishing my reaction I remove the methanol by reducing the
 pressure and directing the vapours through a condenser, or even I
 apply vacuum after despressurizing to do it faster, I can get a
 reduction of the conversion transforming some biodiesel into oil
 again. My question is: has anyone in this group measured or
 experienced this fact? Is there a real decrease of the yield or
 conversion?

 Lagonisa



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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Maud Essen

Todd, is the amount of methanol remaining in the methyl ester 
considered negligible? Is it possible to determine what percentage 
remains in the methyl ester and what percentage in the glycerol? Maud

Lagonisa,

  The problem is
  that I have also read that due to the reversibility of the reaction,

The reaction is not exactly reversible. Reversability would require the
three glycerides and the glycerol recombining. That doesn't happen. Once the
glycerol is cleaved it is out of the picture.

You're suggesting MeOH recovery at the point where the reaction is complete
and the glycerol has yet to settle out. However, that's not altogether
adisable due to the continual mixing of excess catalyst with the methyl
ester.

If you reduce the volume of alcohol via evaporation at this point there
would be a propensity for some of the ester to fracture (back crack) into
FFAs and then convert to soap. Mind you that back cracking can only occur
up to the point that all the catalyst is consumed in soap making.

If you can monitor the reaction and insure that the balance of catalyst is
infintesimally small beyond what is required to guarantee 100% completion,
erego yielding but a small and controlled amount of extra soap production,
then there might be some merit in extracting the alcohol prior to the
glycerin cocktail settling.

Otherwise? Probably none.

Todd Swearingen

  Hello to all:

  I have read some contributions to this group about methanol recovery
  and the different options. I would like to try the recovery before
  separation of bio and glycerol using a condenser that would receive
  the methanol fumes after finishing the reaction. I have a processor
  were I get 75¼C-80¼C as it is pressurized to 0,7 bar. The problem is
  that I have also read that due to the reversibility of the reaction,
  if after finishing my reaction I remove the methanol by reducing the
  pressure and directing the vapours through a condenser, or even I
  apply vacuum after despressurizing to do it faster, I can get a
  reduction of the conversion transforming some biodiesel into oil
  again. My question is: has anyone in this group measured or
  experienced this fact? Is there a real decrease of the yield or
  conversion?

  Lagonisa



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[biofuel] EPA registration

2003-12-13 Thread Edward Mendoza


Mark, do you know how the new EPA registration might affect running a car on
100% veggie oil?

How does a person go about paying the fuel tax for these alt fuels?

Best,

Edward Mendoza
[EMAIL PROTECTED]
707.537.7392
211 Hayman Court
Santa Rosa, CA 95409


Date: Sat, 13 Dec 2003 08:13:56 -
   From: skillshare [EMAIL PROTECTED]
Subject: bad news about EPA registration Re: Commercial production

Hi Keith and others,

I've got more info about the EPA registration issue and it's not
good. I sent the info that Keith compiled
http://archive.nnytech.net/sgroup/BIOFUEL/27488
to Jon Van Gerpen of Iowa State University who then contacted the EPA about
the discrepancy in their registration process (I'm not sure who exactly he
spoke with).




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[biofuel] Ariana EV 796i web link

2003-12-13 Thread Tricia Liu

http://ariana-ev.com/ariana796i.htm

And you will have to use their
ARIANA 796 iEV Commuter Charging System, charge up 
Li-ion battery pack in 5 minutes(85% of capacity)

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[biofuel] Re: methanol recovery before separation

2003-12-13 Thread skillshare

I'd like to know what you base this statement on. 
mark

-- In biofuel@yahoogroups.com, Appal Energy [EMAIL PROTECTED] 
wrote:
 Once the
 glycerol is cleaved it is out of the picture.
 



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[biofuel] Re: EPA registration

2003-12-13 Thread skillshare

hi edward,
The vegoil issue has been addressed here in the recent past. I 
think if you search for 'detrick' you will get to the post about SVO 
and the EPA. 

the biodiesel registratin issue is completely different, though, as 
the EPA knows that they're very different fuels.

Fuel tax- search here for death and taxes' for some info aobut 
federal excise tax (or an exemption to it) for small users of svo or 
homebrew biodiesel. the state of California still wants their 18 
cents a gallon regardles of what you use and the department in 
charge of collecting it is called the Board of Equalization I think.

take care,
mark


--- In biofuel@yahoogroups.com, Edward Mendoza 
[EMAIL PROTECTED] wrote:
 
 Mark, do you know how the new EPA registration might affect 
running a car on
 100% veggie oil?
 
 How does a person go about paying the fuel tax for these alt 
fuels?
 
 Best,
 
 Edward Mendoza
 [EMAIL PROTECTED]
 707.537.7392
 211 Hayman Court
 Santa Rosa, CA 95409
 
 
 Date: Sat, 13 Dec 2003 08:13:56 -
From: skillshare [EMAIL PROTECTED]
 Subject: bad news about EPA registration Re: Commercial 
production
 
 Hi Keith and others,
 
 I've got more info about the EPA registration issue and it's not
 good. I sent the info that Keith compiled
 http://archive.nnytech.net/sgroup/BIOFUEL/27488
 to Jon Van Gerpen of Iowa State University who then contacted 
the EPA about
 the discrepancy in their registration process (I'm not sure who 
exactly he
 spoke with).


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Re: [biofuel] EPA registration

2003-12-13 Thread Keith Addison

Mark, do you know how the new EPA registration might affect running a car on
100% veggie oil?

It has nothing to do with the new EPA registration. SVO-WVO are not 
legal fuels for on-road use in the US. In other words they're 
illegal. What seems most weird is that apart from the Biofuel list 
member who uncovered this, Detrick Merz, nobody in the SVO community 
seems to be working to change this, including the vendors of SVO 
kits/plans, though according to the EPA it's mainly their 
responsibility. For more info see:
http://infoarchive.net/sgroup/biofuel/?keywords=detricktime=allusert 
ime=2002-12-31

How does a person go about paying the fuel tax for these alt fuels?

Biodiesel has two taxes, federal and state. State laws vary. Either 
the vendor or the user has to pay the tax. You can't pay fuel tax on 
SVO-WVO because it's not a regiustered fuel for on-road use.

Best

Keith Addison

Best,

Edward Mendoza
[EMAIL PROTECTED]
707.537.7392
211 Hayman Court
Santa Rosa, CA 95409


Date: Sat, 13 Dec 2003 08:13:56 -
   From: skillshare [EMAIL PROTECTED]
Subject: bad news about EPA registration Re: Commercial production

Hi Keith and others,

I've got more info about the EPA registration issue and it's not
good. I sent the info that Keith compiled
http://archive.nnytech.net/sgroup/BIOFUEL/27488
to Jon Van Gerpen of Iowa State University who then contacted the EPA about
the discrepancy in their registration process (I'm not sure who exactly he
spoke with).





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[biofuel] Re: NBB convention - was bad news about EPA registration

2003-12-13 Thread Keith Addison

Hi again Mark

Hi Keith and others,

snip (see previous)

Also another heads-up: someone whom I know in the NBB
contacted me about their winter convention- they're having a
'small producer panel'  discussion in the convention. They're
trying to get Jim Caldwell to be one of the speakers,and didn't
know yet who the others would be.

My acquaintance in the NBB read the official statement about the
panel to me- and it said something like 'while we recognise that
small producers have a role to play in the development of the
biodiesel market (which I read rather cynically!),

We can be useful and are worth coopting for such worthy issues as 
pushing for the continuance of the soy subsidy, the passing of the 
Energy Handout, er, Energy Bill, and so on, and also we generate more 
good publicity for biodiesel for free than all those expensive PR 
agencies they employ seem to do.

 From actual discussions on collaboration between industry and the 
grassroots movement:

- We are extremely eager to get involved in the grassroots movement 
for biofuels. I would be highly interested in discussing further a 
collaborative effort to pressure the ultimate decision makers from 
the flanks.
- We want to corral the efforts of these advocates. Note corral.
- While we have the supply, we can only go as far as demand will 
take us. We believe that a grassroots effort will generate this 
needed demand. You need us, but do we need you?

but  [I
paraphrase here cause I can't remember the actual language]
the issues of quality need to be addressed' or something like
that.

I think they must be programmed that way or something, probably by 
Microsoft. Despite hell and high water they're STILL saying that, at 
least since this, from an ex-President of the NBB, relayed to me 
privately, date Dec 1999:

One word of caution, however. When dealing with the biofuels 
industry it is very important to always speak of fuels that have been 
certified to meet the specifications as set by testing and standards 
organizations, e.g., ASTM, or that is warrantied by engine 
manufacturers. Proponents of make-it-yourself fuel or not looked 
upon as serious because there is no way to ensure consistent fuel 
quality. Of course, these groups can be very helpful when approaching 
government to demonstrate community-wide support.

- and on and on, through the Perils of Homebrew BS that's STILL 
posted at their site, through the whole Graham Noyes of World Energy 
saga where Graham was finally forced to retract his claims of actual 
cases of sub-spec homebrew causing widespread damage and wrecking 
the market, admitting it was baseless industry rumour-mongering, and 
that we can and do make quality fuel, through his then undertaking to 
inform industry that we are indeed to be looked upon as serious, 
through repeated instances of sub-spec industry/NBB brew causing 
widespread damage and wrecking the market (and you say they haven't 
noticed it yet!!), down to this foolish letter to the editor written 
by an NBB flunky following Tom Leue's accident:

http://www.gazettenet.com/story.cfm?id_no=11170004
GazetteNET.com | Opinion

Homemade biodiesel fuel not a good idea

Monday, November 17, 2003 -- To the editor:

Backyard biodiesel producers should heed Tom Leue's advice in an 
Oct. 20 article to shut up shop. After an explosion in his backyard 
operation, he said he would not try producing biodiesel again, and 
wouldn't recommend others make homemade biodiesel.
Biodiesel, a cleaner-burning alternative to diesel that can be made 
from any fat or vegetable like soybean oil, is the safest fuel to 
use, handle and store. However, the production process involves 
reacting methanol and is not something that should be taken lightly. 
Additionally, fuel quality is critical.

The only way for consumers to know they are getting biodiesel that 
meets the national standard is to buy it from a reputable, 
commercial facility whose biodiesel product is registered with the 
Environmental Protection Agency and meets the quality standards set 
forth by the American Society of Testing and Materials.

It is difficult to maintain consistent quality control with homemade 
biodiesel. Usually, it is not properly tested and often does not 
meet commercial-grade quality standards. More than 350 fleets 
nationwide use commercial biodiesel successfully in their diesel 
vehicles.

Biodiesel is a great way to reduce pollution, contribute to the US 
economy and protect domestic energy security. Consumers just need to 
protect themselves by buying it from reputable producers.

Paul Nazzaro
Representative
National Biodiesel Board
Lynnfield , MA

As if that was the point!!! - as you remarked at the time:
http://infoarchive.net/sgroup/BIOFUEL/29955/

And now they're including (are they?) the small fry in their 
convention with the same proviso. I think we can give up on them, 
don't you?

Now this was amusing to me to hear.

I guess that's the right response by now, what the hell. I find I 

Re: [biofuel] bad news about EPA registration Re: Commercial production

2003-12-13 Thread Keith Addison

Hi Mark

I'll write two responses to this, since it's about two different issues.

First on the EPA registration issue.

Hi Keith and others,

I've got more info about the EPA registration issue and it's not
good. I sent the info that Keith compiled  (
http://archive.nnytech.net/sgroup/BIOFUEL/27488/ ) to Jon Van
Gerpen of Iowa State University who then contacted the EPA
about the discrepancy in their registration process (I'm not sure
who exactly he spoke with).

I didn't get full details yet from Dr Van Gerpen (especially the
question of whom it was that he spoke with, but Ill try and find
out next week) , but here's what he wrote to me:

Quote: Regarding my email exchange with EPA.  It was pretty
much a bust.  I  explained to them my understanding of the
registration process and then asked them for the rationale they
use to categorize biodiesel as an atypical fuel.

It is not so categorised - why does he think that? See below.

In the response I
received, they confirmed that my understanding of the process
was correct but ignored my request for the rationale.

I can't fault them too much for not being responsive.  We're all
busy.   However, I still think there is no sound technical basis for
not  including biodiesel as a non-baseline fuel.

It is so included, according to an EPA ruling reffed below, which the 
EPA's previous (please note) policy (?) on this issue apparently 
ignored. They have since acknowledged it, and changed their policy 
accordingly.

This would
allow it to qualify  for the small business exemptions.

It does so qualify.

I think the
most likely path to  getting this would be to find a friendly senator
who might be willing to push the EPA to loosen up.
(end quote)

It's kind of critical who he spoke to. Look at the kind of thing 
you're finding - the NBB is out of touch on B100 issues, on 
small-producers, on the sub-spec fuel their members have been 
supplying, and, despite Graham Noyes' work and more, about the FACT 
that the bad press they give - STILL give - homebrewers is baseless 
BS which they should perhaps apply to themselves, where they might 
find it's far from baseless. The one hand doesn't know what the other 
hand's doing. Same in most bureaucracies.

Biofuels-biz members did a lot of work identifying the issues and 
finding the relevant rules regs and docs, and then confronting EPA 
officials with their own rules. As it unfolded you could see a 
sequence of changing statements from the EPA, moving from one side to 
exactly the other. This was the result:

... According to this, biodiesel (either as a fuel or an additive) 
doesn't meet Baseline or Non-Baseline because its made from 
non-petroleum sources.

Joe Sopata of the EPA has stated that any blend of 6% biodiesel or 
less was considered a non-baseline fuel, and anything over 6% was 
considered atypical, and therefore not subject to the Tier 1 
exemption. But we could not find these definitions in any EPA 
documents.

What we did find in an EPA document is this: An exception is 
biodiesel, which is one group, even though it consists of mixed 
alkyl esters of plant and/or animal origin.
http://www.epa.gov/icr/icrs/icrpages/1696ss03.htm

This makes biodiesel a non-baseline diesel group, and thus exempt 
from Tier I and Tier II testing for producers with total annual 
sales of less than $50 million.

For more on this, see Thor Skov's post below.

Joe Sopata has since said, in answer to enquiries, that producers 
who sell less than $10,000,000 annually are exempt from Tier I and 
Tier II as long as their fuel meets the ASTM standard (ASTM D-6751).

This is what I was told:

Joe Sopata again stated that fuels meeting all ASTM standards for 
biodiesel are eligible for the exemptions.

Jim Caldwell at EPA stated the same. Also that the test for being a 
non-baseline fuel is meeting the standards. Not meeting the 
standards puts fuel in the atypical category and comes with 
requirements for Tier I. Further,  he stated that the problems 
associated with yellow grease biodiesel were meeting the standard 
for viscosity.

That is clear enough. I think Jon van Gerpen's trying to reinvent the 
wheel - why go through all that work again? And perhaps risk a 
different outcome? He absolutely needs to discuss it with first Joe 
Sopata and second Jim Caldwell, or preferably both, and cite the 
previous discussions with the Biofuels-biz members. Joe Sopata and 
Jim Caldwell made statements and undertakings, they can and must be 
held to them. Some of the discussion material is in the compilation I 
did, the rest can easily be found in the Biofuels-biz archives. I'm 
sure if Jon van Gerpen contacted those concerned they'd be more than 
happy to work with him on it.

As it it, it seems to me he's largely ignoring this invaluable work 
that's already been done, quite probably dealing with someone who 
doesn't know of it (one hand...), getting a negative response, and 
concluding, wrongly, that it all has to be done all over again, or 

Re: [biofuel] Re: methanol recovery before separation

2003-12-13 Thread Appal Energy

That portion of the reaction is in all practicality uni-directional. The
energy required to attach a MeOH molecule to the fatty acid is considerably
less than the energy required to re-attach the glycerol.

The reason for keeping a reaction severely agitated is not to keep the
cleaved glycerol involved in the reaction, as it no longer plays a direct
role, but to keep the remaining alcohol and catalyst fractions in continual
contact, which in the majority would migrate more freely to the glycerol
(indirect role) and settle out along with it prior to a reaction's
completion.

Todd Swearingen

- Original Message - 
From: skillshare [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, December 14, 2003 12:06 AM
Subject: [biofuel] Re: methanol recovery before separation


 I'd like to know what you base this statement on.
 mark

 -- In biofuel@yahoogroups.com, Appal Energy [EMAIL PROTECTED]
 wrote:
  Once the
  glycerol is cleaved it is out of the picture.
 
 



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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Keith Addison

Lagonisa,

  The problem is
  that I have also read that due to the reversibility of the reaction,

The reaction is not exactly reversible. Reversability would require the
three glycerides and the glycerol recombining. That doesn't happen. Once the
glycerol is cleaved it is out of the picture.

You're suggesting MeOH recovery at the point where the reaction is complete
and the glycerol has yet to settle out. However, that's not altogether
adisable due to the continual mixing of excess catalyst with the methyl
ester.

If you reduce the volume of alcohol via evaporation at this point there
would be a propensity for some of the ester to fracture (back crack) into
FFAs and then convert to soap. Mind you that back cracking can only occur
up to the point that all the catalyst is consumed in soap making.

If you can monitor the reaction and insure that the balance of catalyst is
infintesimally small beyond what is required to guarantee 100% completion,
erego yielding but a small and controlled amount of extra soap production,
then there might be some merit in extracting the alcohol prior to the
glycerin cocktail settling.

Otherwise? Probably none.

Todd Swearingen

Hi Todd

Yet that's what Dale Scroggins does, apparently with good results.
The touchless processor
http://journeytoforever.org/biodiesel_processor.html#touchfree

http://home.swbell.net/scrof/Biod_Proc.html

Michael Allen and Gumpon Prateepchaikul's set-up at Prince of Songkla 
University in Thailand also reclaims the methanol at the end of the 
processing stage, though differently, and with high efficiency and a 
high-quality product (they test it).

I wonder if this isn't somewhat theoretical, as with the idea that 
using acid in the wash will definitely backsplit biodiesel to FFAs 
and must definitely be avoided. If properly done - which of course 
shouldn't be merely so solve an emulsion problem (improve the 
process!) - it has the advantage of thoroughly neutralizing the 
catalyst, at the cost of traces of FFA which remain well within the 
standard specs.

So here the same perhaps applies, as you indicate - a well-controlled 
process with the right amount of catalyst and the right amount of 
everything else too.

Needs and economics will differ from case to case, and I think 
methanol recovery should be an option at each of the three possible 
stages it can be done - straight after processing, using the existing 
heat (to start with), recovering excess methanol from both the ester 
and the by-product; recovering the excess methanol from the 
by-product cocktail (that is most of it), which leaves the balance to 
be accounted for (in the first wash water); recovering the excess 
methanol from the glycerine itself after separating the by-product 
components (which still leaves the balance in the first wash water).

Best

Keith



  Hello to all:
 
  I have read some contributions to this group about methanol recovery
  and the different options. I would like to try the recovery before
  separation of bio and glycerol using a condenser that would receive
  the methanol fumes after finishing the reaction. I have a processor
  were I get 75¼C-80¼C as it is pressurized to 0,7 bar. The problem is
  that I have also read that due to the reversibility of the reaction,
  if after finishing my reaction I remove the methanol by reducing the
  pressure and directing the vapours through a condenser, or even I
  apply vacuum after despressurizing to do it faster, I can get a
  reduction of the conversion transforming some biodiesel into oil
  again. My question is: has anyone in this group measured or
  experienced this fact? Is there a real decrease of the yield or
  conversion?
 
  Lagonisa


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Re: [biofuel] methanol recovery before separation

2003-12-13 Thread Appal Energy

Maud,

I wouldn't consider the MeOH content in the biodiesel to be negligible. Not
at all.

Unfortunately, many others consider it so.

Simplest method to determine the volume of MeOH that resides in the
biodiesel and glycerol, as well as the volume that was consumed in reaction,
is to measure the volumes of alcohol laden biodiesel and glycerol, evaporate
the MeOH and then measure the remaining volumes of each.

The easiest way, IMNSHO, to determine if the MeOH volume in the biodiesel
fraction is negligible is to stick one's nose over a container and huff it.
(Not advised, but the point being made should be easy enough to decipher.)
Without removing the alcohol you've got a fluid that has a flashpoint
essentially the same as methanol, rather than the rather safe flashpoint of
biodiesel.

To test that theory, take a piece of cotton wick, anchor it in a 6 ounce
metal tomato paste can as if you're going to make a candle. Fill the can
with MeOH laden biodiesel. Light the wick as if the can were an oil candle.
Sit back and watch. Everything goes fine for a bit, that is until the fuel
heats up to the boiling point of alcohol. Then you have a runaway alcohol
torch.

That's the same alochol that would normally get washed down someone's
drain or flushed out into the back forty. The same stuff that a lot of
people consider insignificant.

We haven't yet taken any time to quantify the average volume of MeOH that
remains in the biodiesel. But it is a safe bet that the ratio is consistent
between the biodiesel and glycerol fractions no matter how much alcohol is
originally used. The more alcohol used in the reaction, the more alcohol
will remain in the biodiesel and end up in the wastewater stream if
evaporation is not conducted prior.

Most people have probably noticed that MeOH and biodiesel are completely
miscible in each other in any volume.

If a person is worried about the energy inputs required to recover the
alcohol from the biodiesel, then they should be looking at insulation, heat
recovery and renewable fuels for the energy inputs.

Todd Swearingen

- Original Message - 
From: Maud Essen [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Saturday, December 13, 2003 7:08 PM
Subject: Re: [biofuel] methanol recovery before separation


Todd, is the amount of methanol remaining in the methyl ester
considered negligible? Is it possible to determine what percentage
remains in the methyl ester and what percentage in the glycerol? Maud

Lagonisa,

  The problem is
  that I have also read that due to the reversibility of the reaction,

The reaction is not exactly reversible. Reversability would require the
three glycerides and the glycerol recombining. That doesn't happen. Once
the
glycerol is cleaved it is out of the picture.

You're suggesting MeOH recovery at the point where the reaction is complete
and the glycerol has yet to settle out. However, that's not altogether
adisable due to the continual mixing of excess catalyst with the methyl
ester.

If you reduce the volume of alcohol via evaporation at this point there
would be a propensity for some of the ester to fracture (back crack) into
FFAs and then convert to soap. Mind you that back cracking can only occur
up to the point that all the catalyst is consumed in soap making.

If you can monitor the reaction and insure that the balance of catalyst is
infintesimally small beyond what is required to guarantee 100% completion,
erego yielding but a small and controlled amount of extra soap production,
then there might be some merit in extracting the alcohol prior to the
glycerin cocktail settling.

Otherwise? Probably none.

Todd Swearingen

  Hello to all:

  I have read some contributions to this group about methanol recovery
  and the different options. I would like to try the recovery before
  separation of bio and glycerol using a condenser that would receive
  the methanol fumes after finishing the reaction. I have a processor
  were I get 75¼C-80¼C as it is pressurized to 0,7 bar. The problem is
  that I have also read that due to the reversibility of the reaction,
  if after finishing my reaction I remove the methanol by reducing the
  pressure and directing the vapours through a condenser, or even I
  apply vacuum after despressurizing to do it faster, I can get a
  reduction of the conversion transforming some biodiesel into oil
  again. My question is: has anyone in this group measured or
  experienced this fact? Is there a real decrease of the yield or
  conversion?

  Lagonisa



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