[biofuel] Testing of Biodiesel

2004-05-14 Thread canros_uk

Hello

Go here to find a very blantant attempt to stop UK small biodiesel 
production:

http://www.greenergy.com/company/downloads/Submission_2004_Budget.pdf


Box 1. Substandard biodiesel product
Greenergy has serious concerns about the supply of substandard 
biodiesel in
the UK. Greenergy defines substandard biodiesel as any product 
produced
and sold without each production batch being subject to a full 
quality analysis
determined in an ISO quality certified laboratory (the norm for ULSD).
Quality analysis is fundamental to the production of safe, fit for 
purpose
biodiesel. Greenergy considers that any product sold without such 
analysis is
not fit for purpose and therefore substandard because its quality is 
unknown.
This is irrespective of whether that biodiesel would have met pr 
EN14214 if
tested or not.

What can we do to stop these parasites?

Stuart




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Re: [biofuel] Testing of biodiesel

2003-08-28 Thread Bob Allen

Hello Kieth and Jay et al.   First an introduction:  I am an organic 
chemist with a long time interest in environmental issues, particularly 
resource conservation.  In the past I have organized and operated a 
community recycling center, served on the Arkansas State Alternative 
fuels commission, and generally "beat the drum" in any venue available 
to me.  A few years ago I began very small scale production of biodiesel 
as a demonstration in my organic labs (about 20 ml at a time- ironically 
the demonstration was to show large scale production relative to the 
amounts of stuff my students usually handle.)


  Somewhere along the way I thought I should "walk the talk", so last 
spring I bought a 81 MB 300SD This summer I made a few one gallon 
batches from virgin oil, and am currently operating on the same scale 
with used fry oil from the food service here on campus- about 140 
gallons a week available for the taking.


One interest in particular is the issue of waste disposal/utilization, 
the strongly alkaline glycerol remainder in particular.  What do both 
small and large producers do?  I guess large producers can give/sell the 
stuff off but I can't imagine much of a market for a gallon or two at a 
time.  So here is my idea- more fuel.


One ought to be able to react the "left overs" with dimethyl sulfate or 
maybe a methyl halide to form a product- 1,2,3-trimethoxy propane which 
ought to serve as an oxygenated gasoline additive.  Lots of ought to's 
and maybes, but hey its research.



boy, this is a busy list...

later.

--
Bob Allen, Professor of Chemistryhttp://ozarker.org/bob
---
"Some scientists claim that Hydrogen, because it is so plentiful, is
the basic building block of the universe. I dispute that. I say there
is more stupidity than Hydrogen, and that is the basic building block
of the universe." - Frank Zappa

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Re: [biofuel] Testing of biodiesel

2003-08-27 Thread Pedro M.V.

If you want, we can talk to convert your testing like official Spanish 
Biodiesel Association tests (send email to me). This would be a very good help 
for new biodiesellers. The user could recieve the results by email.

I have in mind at least two persons in different places of the country.

Regards.



Elabore caseramente biodiesel para su actual motor de gasoil petrol’fero
La soluci—n a sus problemas energŽticos.

http://www.enlazando.com/energia
http://journeytoforever.org/energiaweb/

  - Original Message - 
  From: [EMAIL PROTECTED] 
  To: [EMAIL PROTECTED] ; [EMAIL PROTECTED] 
  Sent: Tuesday, August 26, 2003 4:43 PM
  Subject: Re: [biofuel] Testing of biodiesel


  In a message dated 8/25/03 11:14:26 PM Pacific Daylight Time, 
  [EMAIL PROTECTED] writes:

  > Is there any lab that will test a sample of hombrewed bioD to see if it
  > meets specs?  I appreciate it
  > J.D.

  I can analyze it for you by infrared spectroscopy.  Send a sample plus a 
  sample of the spec fuel.  All I need is one drop of each.  Normal cost is 
  $60/sample.  I'll do this one for you for free.  Future samples will be at 
the stated 
  price.

  -- Jay


  [Non-text portions of this message have been removed]



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Re: [biofuel] Testing of biodiesel

2003-08-27 Thread DokDream

In a message dated 8/26/03 12:37:58 PM Pacific Daylight Time, [EMAIL PROTECTED] 
writes:

> Bob Allen, Professor of Chemistry http://ozarker.org/bob

PS, Bob.  You did know that I was teasing you, right?

-- Jay


[Non-text portions of this message have been removed]



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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread DokDream

In a message dated 8/26/03 2:39:24 PM Pacific Daylight Time, 
[EMAIL PROTECTED] writes:

> Bob Allen wrote:
> 
> >Just curious, what will you be measuring by IR spectroscopy?  I ran
> >virgin vegetable oil, pure FAME, and used vegetable oil and they are
> >essentially indistinguishable.
> 
> A chemist, who quotes Frank Zappa to boot! Welcome! :-) And all this 
> time I thought it was excentrifugal forz. Tut.
> 
> Anyway, do you know about all this?
> 

Measurement of normalized peak heights with comparison between standard and 
sample addresses your point.  Vegetable oil thet has been hydrogenated or 
oxidized will have a different spectrogaphic profile than "virgin" -- as you 
put it 
-- vegetable oil.   This isn't rocket science here, folks.  Well, on second 
thought, maybe it is.  At any rate, I cut my teeth, so to speak, on IR 
spectroscopy of Green River Oil Shale while getting my MSChE.  I've been using 
IR 
throughout my career and love it as an analytical tool.  Perhaps some component 
separation would be necessary, first.  If so, TLC (no, not "tender, loving, 
care," but Thin Layer Chromatography)  probably would be the means of choice.  

Anyhow, don't look a gift horse in the mouth, Bob!  I'm going to analyze the 
stuff for J.D. gratis, for zero, ziltch.  (Hey, if it helps eliminate fossil 
fuel powered vehicles, I'm in favor of it.)

-- Jay


[Non-text portions of this message have been removed]



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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Keith Addison

Bob Allen wrote:

>Just curious, what will you be measuring by IR spectroscopy?  I ran
>virgin vegetable oil, pure FAME, and used vegetable oil and they are
>essentially indistinguishable.

A chemist, who quotes Frank Zappa to boot! Welcome! :-) And all this 
time I thought it was excentrifugal forz. Tut.

Anyway, do you know about all this?

NIR Helps Turn Vegetable Oil into High-Quality Biofuel -- ARS News 
Release, June 15, 1999
http://journeytoforever.org/biofuel_library/NIR.html

Rapid Monitoring of Transesterification and Assessing Biodiesel Fuel 
Quality by Near-infrared Spectroscopy Using a Fiber-Optic Probe, by 
Gerhard Knothe, ARS, JAOCS 76, 795-800 (July 1999)
http://journeytoforever.org/biofuel_library/NIR1.html

Monitoring a Progressing Transesterification Reaction by Fiber-Optic 
Near Infrared Spectroscopy with Correlation to 1H Nuclear Magnetic 
Resonance Spectroscopy, by Gerhard Knothe, ARS, JAOCS 77, 489-493 
(May 2000)
http://journeytoforever.org/biofuel_library/NIR2.html

Best

Keith



>[EMAIL PROTECTED] wrote:
>
>
> >
> > I can analyze it for you by infrared spectroscopy.  Send a sample plus a
> > sample of the spec fuel.  All I need is one drop of each.  Normal cost is
> > $60/sample.  I'll do this one for you for free.  Future samples 
>will be at the stated
> > price.
> >
> > -- Jay
> >
> >
>
>--
>--
>Bob Allen, Professor of Chemistryhttp://ozarker.org/bob
>- 
>--
>"Some scientists claim that Hydrogen, because it is so plentiful, is
>the basic building block of the universe. I dispute that. I say there
>is more stupidity than Hydrogen, and that is the basic building block
>of the universe." - Frank Zappa


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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Bob Allen

Just curious, what will you be measuring by IR spectroscopy?  I ran 
virgin vegetable oil, pure FAME, and used vegetable oil and they are 
essentially indistinguishable.

[EMAIL PROTECTED] wrote:


> 
> I can analyze it for you by infrared spectroscopy.  Send a sample plus a 
> sample of the spec fuel.  All I need is one drop of each.  Normal cost is 
> $60/sample.  I'll do this one for you for free.  Future samples will be at 
> the stated 
> price.
> 
> -- Jay
> 
> 

-- 
--
Bob Allen, Professor of Chemistryhttp://ozarker.org/bob
---
"Some scientists claim that Hydrogen, because it is so plentiful, is
the basic building block of the universe. I dispute that. I say there
is more stupidity than Hydrogen, and that is the basic building block
of the universe." - Frank Zappa

---
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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Pedro M.V.

About gas chromatography : 

http://www.wikipedia.org/wiki/Chromatography#Gas_chromatography

  - Original Message - 
  From: Andreas W Ohnsorge 
  To: biofuel@yahoogroups.com 
  Sent: Tuesday, August 26, 2003 9:02 AM
  Subject: Re: [biofuel] Testing of biodiesel




  I found some in Germany - they are usually testing large biodiesel batches
  and are quite expensive (around 800 Euros for a full test). If you don't
  want to sell the stuff you should consider testing only the really
  important variables (glycerides,...) which is a gaschromatography test and
  that was about 120 Euros here.

  I found those laboratories by asking some of the biodiesel producers where
  they let test their biodiesel...

  Andreas Ohnsorge

  CSC Ploenzke AG
  Abraham-Lincoln-Park 1
  65189 Wiesbaden
  Germany
  Phone: +49.611.142.20020
  Fax: +49.611.142.980028
  Mobile:+49 172 - 8 43 30 32
  e-Mail: [EMAIL PROTECTED]
  Internet: http://www.de.csc.com

  100 Jahre Tour de France: Herzlichen GlŸckwunsch dem Team CSC zum 1. Platz
  in der Team-Gesamtwertung http://www.csc-cycling.com/.


  


  This is a PRIVATE message. If you are not the intended recipient, please
  delete without copying and kindly advise us by e-mail of the mistake in
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   To:  
  
 cc:
 
26.08.2003 04:39 Subject: [biofuel] Testing of 
biodiesel 
Please respond  
 
to biofuel  
 

 

 




  Is there any lab that will test a sample of hombrewed bioD to see if it
  meets specs?  I appreciate it
  J.D.





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Re: [biofuel] Testing of biodiesel II

2003-08-26 Thread Pedro M.V.

How does one call the more complete industrial biodesel test???

Regards.

Elabore caseramente biodiesel para su actual motor de gasoil petrol’fero
La soluci—n a sus problemas energŽticos.

http://www.enlazando.com/energia
http://journeytoforever.org/energiaweb/

  - Original Message - 
  From: [EMAIL PROTECTED] 
  To: biofuel@yahoogroups.com 
  Sent: Tuesday, August 26, 2003 4:39 AM
  Subject: [biofuel] Testing of biodiesel


  Is there any lab that will test a sample of hombrewed bioD to see if it
  meets specs?  I appreciate it
  J.D.




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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Pedro M.V.

Good idea. But I think standard (petrol) bodies includes difficult and 
expensive test to obstruct homebrewed  biodiesel  ( the best test it«s the 
engine test and clean cylinders from time to time).

For small industrial production is another think. One could analize in 
different ways the produced biodiesel and give advice ( clean more the oil, and 
so on...).

Regards.


Elabore caseramente biodiesel para su actual motor de gasoil petrol’fero
La soluci—n a sus problemas energŽticos.

http://www.enlazando.com/energia
http://journeytoforever.org/energiaweb/

  - Original Message - 
  From: [EMAIL PROTECTED] 
  To: biofuel@yahoogroups.com 
  Sent: Tuesday, August 26, 2003 4:39 AM
  Subject: [biofuel] Testing of biodiesel


  Is there any lab that will test a sample of hombrewed bioD to see if it
  meets specs?  I appreciate it
  J.D.




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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread DokDream

In a message dated 8/25/03 11:14:26 PM Pacific Daylight Time, 
[EMAIL PROTECTED] writes:

> Is there any lab that will test a sample of hombrewed bioD to see if it
> meets specs?  I appreciate it
> J.D.

I can analyze it for you by infrared spectroscopy.  Send a sample plus a 
sample of the spec fuel.  All I need is one drop of each.  Normal cost is 
$60/sample.  I'll do this one for you for free.  Future samples will be at the 
stated 
price.

-- Jay


[Non-text portions of this message have been removed]



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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Neoteric Biofuels Inc

Check ASTM for listings of local labs equipped to do some or all of the  
tests for the ASTM biodiesel standards, then contact them for quotes.

This may help:

http://www.astm.org/cgi-bin/SoftCart.exe/LABS/ 
search.html?L+mystore+xbff5197



On Monday, August 25, 2003, at 07:39 PM, [EMAIL PROTECTED] wrote:

> Is there any lab that will test a sample of hombrewed bioD to see if it
> meets specs?  I appreciate it
> J.D.
>
>
>
>
>  Yahoo! Groups Sponsor  
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>



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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Neoteric Biofuels Inc

http://www.astm.org/ 
verity_hist.cgi?UserQuery=BIODIESEL&SEARCH_COLLECTION=ACTIVE_REDLINE&SEA 
RCH_STATUS=ALL&MARKETING_CODE=GP1&NS-search-type=Free+text&NS-max- 
records=5&NS-search-type=boolean&NS- 
query=BIODIESEL+AND+NOT+%28STATUS+%3CNEAR%2F1%3E+REPLACED%29&CART_NAME=x 
bff5197&STORE_NAME=mystore&NS-collection=ASTM_ACTIVE_REDLINE&NS- 
collection2=ASTM_HISTORICAL&NS-collection3=ASTM_WITHDRAWN&NS- 
collection4=ASTM_WORKITEMS

Very long URL, but perhaps you can copy and paste the whole thing into  
your browser. Leads to publications from ASTM, tests, test methods,  
standards, etc.


On Monday, August 25, 2003, at 07:39 PM, [EMAIL PROTECTED] wrote:

> Is there any lab that will test a sample of hombrewed bioD to see if it
> meets specs?  I appreciate it
> J.D.
>
>
>
>
>  Yahoo! Groups Sponsor  
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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Jack Kenworthy

Analytical Testing Services in Franklin, PA will test it for you if you send 
them a 1 gallon sample, to meet ASTM 6751-03, for $972.00 all inclusive - it 
ain't cheap.  
their contact:  814-432-9424
[EMAIL PROTECTED]

cheers,
Jack

Jack Kenworthy
Sustainable Systems Director
The Cape Eleuthera Island School
242-359-7625 ph. 954-252-2224 fax
www.islandschool.org
  - Original Message - 
  From: Andreas W Ohnsorge 
  To: biofuel@yahoogroups.com 
  Cc: biofuel@yahoogroups.com 
  Sent: Tuesday, August 26, 2003 3:02 AM
  Subject: Re: [biofuel] Testing of biodiesel




  I found some in Germany - they are usually testing large biodiesel batches
  and are quite expensive (around 800 Euros for a full test). If you don't
  want to sell the stuff you should consider testing only the really
  important variables (glycerides,...) which is a gaschromatography test and
  that was about 120 Euros here.

  I found those laboratories by asking some of the biodiesel producers where
  they let test their biodiesel...

  Andreas Ohnsorge

  CSC Ploenzke AG
  Abraham-Lincoln-Park 1
  65189 Wiesbaden
  Germany
  Phone: +49.611.142.20020
  Fax: +49.611.142.980028
  Mobile:+49 172 - 8 43 30 32
  e-Mail: [EMAIL PROTECTED]
  Internet: http://www.de.csc.com

  100 Jahre Tour de France: Herzlichen GlŸckwunsch dem Team CSC zum 1. Platz
  in der Team-Gesamtwertung http://www.csc-cycling.com/.


  


  This is a PRIVATE message. If you are not the intended recipient, please
  delete without copying and kindly advise us by e-mail of the mistake in
  delivery. NOTE: Regardless of content, this e-mail shall not operate to
  bind CSC to any order or other contract unless pursuant to explicit written
  agreement or government initiative expressly permitting the use of e-mail
  for such purpose.
  






 
   To:  
  
 cc:
 
26.08.2003 04:39 Subject: [biofuel] Testing of 
biodiesel 
Please respond  
 
to biofuel  
 

 

 




  Is there any lab that will test a sample of hombrewed bioD to see if it
  meets specs?  I appreciate it
  J.D.





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  http://journeytoforever.org/biofuel.html

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Re: [biofuel] Testing of biodiesel

2003-08-26 Thread Andreas W Ohnsorge



I found some in Germany - they are usually testing large biodiesel batches
and are quite expensive (around 800 Euros for a full test). If you don't
want to sell the stuff you should consider testing only the really
important variables (glycerides,...) which is a gaschromatography test and
that was about 120 Euros here.

I found those laboratories by asking some of the biodiesel producers where
they let test their biodiesel...

Andreas Ohnsorge

CSC Ploenzke AG
Abraham-Lincoln-Park 1
65189 Wiesbaden
Germany
Phone: +49.611.142.20020
Fax: +49.611.142.980028
Mobile:+49 172 - 8 43 30 32
e-Mail: [EMAIL PROTECTED]
Internet: http://www.de.csc.com

100 Jahre Tour de France: Herzlichen GlŸckwunsch dem Team CSC zum 1. Platz
in der Team-Gesamtwertung http://www.csc-cycling.com/.




This is a PRIVATE message. If you are not the intended recipient, please
delete without copying and kindly advise us by e-mail of the mistake in
delivery. NOTE: Regardless of content, this e-mail shall not operate to
bind CSC to any order or other contract unless pursuant to explicit written
agreement or government initiative expressly permitting the use of e-mail
for such purpose.






   
 To:  
  
   cc:  
   
  26.08.2003 04:39 Subject: [biofuel] Testing of 
biodiesel 
  Please respond
   
  to biofuel
   

   

   




Is there any lab that will test a sample of hombrewed bioD to see if it
meets specs?  I appreciate it
J.D.





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http://journeytoforever.org/biofuel.html

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[biofuel] Testing of biodiesel

2003-08-26 Thread kline

Is there any lab that will test a sample of hombrewed bioD to see if it
meets specs?  I appreciate it
J.D.




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