thanks much Marshall

--- On Wed, 9/8/10, Marshall Dudley <mdud...@king-cart.com> wrote:

From: Marshall Dudley <mdud...@king-cart.com>
Subject: Re: CS>U/S to Silver Strength Reading
To: silver-list@eskimo.com
Date: Wednesday, September 8, 2010, 2:27 PM

http://www.bghydro.com/mmbgh/Others/How%20do%20I%20calibrate%20my%20TDS%20meter.pdf
 shows that the Hanna TDS meter is calibrated 2:1 between uS and TDS.  This is 
my understanding of the physics and why you have to double the reading for ppm 
of ionic silver solution:.

1. TDS meters are set for sodium chloride.  Sodium has an atomic weight of 23 
and chlorine has an atomic weight of 35.5.  They both contribute to the 
conductivity.  Now ionic silver is Ag2O with an ion weight of 215 and 16.  The 
silver thus has a mobility that is 23/215 or about 1/10 of that of sodium, and 
the oxygen has a mobility that is about 2.2 times that of the Chlorine.  If you 
compute the total mobilities of the two you would get 1/23 + 1/35.5 = 0.07 and 
1/215 + 1/16 = 0.067.  So at first look it would appear that the calibrations 
are almost identical, but you will note that the Silver ion carries a charge of 
2, but the Sodium only a charge of one.  Thus the silver will have a mobility 
of the electrons of twice that of the ions, and thus must be multiplied by 2 
which give .134.  When that is ratioed with the mobility of sodium chloride you 
get a ratio of 1.91.  If you add 5% colloidal component you get 2.01 to one, 
which is very close to
 the 2:1 ratio given. If my analysis is correct, then EIS with a colloidal 
component more than 5% will actually be slightly higher ppm than using a TDS 
meter and multiply by two or using the result of the conductivity meter. This 
is easily seen by the drop off of the conductivity as the solution ages and 
some of the ionic converts to colloid.

Marshall

j petras wrote:
> Trem:
> 
> So you're differentiating the microsiemen meter (1:1) from the TDS meter, 
> which you say should be converted at half the value...do I understand that 
> correctly? They are functionally different? 
> The distinction in meters, if I am correct, is that the microsiemen meter 
> reads solution conductivity; and the tds reads just that - dissolved solids.
> 
> Can you (or someone else) please send a link for reference, because in my 
> cursory research thus far, I have heard different things - thanks. 
> John
> 
>  
> --- On *Wed, 9/8/10, Trem /<t...@silvergen.com>/* wrote:
> 
> 
>     From: Trem <t...@silvergen.com>
>     Subject: Re: CS>U/S to Silver Strength Reading
>     To: silver-list@eskimo.com
>     Date: Wednesday, September 8, 2010, 12:56 PM
> 
>     It's 1 to 1   TDS readings are 1/2 the PPM
> 
>     Trem
> 
> 
>     ----- Original Message -----
>     From: "nessie" <nes...@shaw.ca </mc/compose?to=nes...@shaw.ca>>
>     To: <silver-list@eskimo.com </mc/compose?to=silver-l...@eskimo.com>>
>     Sent: Wednesday, September 08, 2010 9:33 AM
>     Subject: CS>U/S to Silver Strength Reading
> 
> 
>     >  Hi Group:
>     >            I think this has been discussed  before. But I forget the
>     > outcome.
>     >           Basically,  what is the mathematical adjustment when     going
>     > from U/S (Microsemens) measurement
>     >           to PPM  for measuring silver strength/concentration .
>     Seems
>     > to me  the  silver strength/concentration  in PPm was half of the
>     > microsemens reading?
>     >           Is that correct or was it 2/3 the  microsemen reading?
>     >                                                             
>thanks...nessie
>     >
>     >
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