Kevin,
First off I should say that we produce concentrated CS using de-ionized
water, of TDS less than 10.  I am unclear as to just where the
dissociated hydroxide ions are coming from.
Reid

Kevin Nolan wrote:
Silver hydroxide would not be a salt, but rather a base.  IE sodium
hydroxide is lye. Marshall"

Technically speaking, that is true. But silver hydroxide is a very weak
base, and in fact it's pH is lower than many
'genuine' salts. The point is, it exists in solution as dissociated ions
- not as colloidal silver particles. Owing to claims
made on the list that nitrate ion was the main problem with silver
nitrate (even though argyria is a deposited silver
condition), the question arises as to what species or combination of
species potentially does the damage, and under
what conditions. I think there is general agreement that unrealistically
massive doses are required before home brew
'CS' would be a problem. But I got the impression that silver nitrate
could cause trouble at much lower relative dosage -
ie it's not just a matter of silver ion dosage alone. Nitrate is a known
carcinogen (less so than nitrite), and an irritant at
high enough concentration. But is argyria solely due to the high silver
dosage possible with silver nitrate (very high
solubility), or is there some kind of synergy effect as well?  Anything
taken to excess will cause trouble. The gist is
this - do certain anions, innocuous of themselves (eg, acetate, citrate)
somehow significantly and selectively 'promote'
toxicity of silver ion relative to say, silver hydroxide at the same
concentration? Maybe there is simply no definitive
data on that, but if there is it would be a good thing to know.

regards, Kevin Nolan




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