Mike Monett wrote:

> Re: CS>Answer to Catherine, warning to Mike Monett...
> From: Marshall Dudley
> Date: Mon, 23 Jun 2003 09:41:21
>
>   > This guy is claiming to be a Ray-O-Vac engineer? I have my doubts.
>
>   Boy, posting in html sure garbles things.
>
>   Yes, he  is a reliability engineer for batteries, and he  knows what
>   he is talking about.
>
>   > Putting a  partially discharged battery in series  with  good ones
>   > will not  cause a reverse current, but can cause a  current  to be
>   > forced through  it when it becomes totally dead which  might  be a
>   > problem.
>
>   This is exactly the problem. Current flows in the  reverse direction
>   as he described. This causes gas to build up. Batteries that are not
>   designed for recharging have no way to vent this gas. Eventually the
>   battery explodes.

How could the current flow backwards when you have cells in series and none are 
backwards. If it
reveresed in one of the cells it would have to reverse in all the cells, and 
energy would be
going into all the cells, which would require an external power source. It is 
physically
impossible.  If you find a way, let me know, I could use a free energy machine.

>
>
>   > To get  a  reverse current requires the  battery  to  be installed
>   > backwards, or in parallel with one or more batteries that  are not
>   > discharged. Out  of  3 possibilities, he chose  the  one  that was
>   > wrong.
>
>   No. When  the batteries are in series, the  strong  batteries charge
>   the weak one in the reverse direction. This is called cell reversal.
>
>   If the  battery is not designed for recharging,  gas  buildup causes
>   the battery to explode.
>
>   > Regular batteries are in a steel can also for most types,  such as
>   > a C or D cell. He should know that if he is a battery engineer.
>
>   > Marshall
>
>   As he described, carbon-zinc batteries have a zinc outer shell. Here
>   is a picture from the Energizer site:
>
>   http://data.energizer.com/batteryinfo/cross_sections_for_manuals/cs1215.pdf

Carbon-zinc cells have always had a zinc outer shell which is part of the 
battery itself and
disappears as the cell is used. Cells use to have this as the outer shell until 
the mid 50's and
would always leak after discharge. In the 50's  when leakproof batteries were 
introduced they
started putting the entire thing inside a steel shell. If you were alive then, 
they even
advertised "encased in steel" for a while.

I have some old leakproof carbon zinc batteries around, and they definitely 
have a steel case on
them.  Looking at the pdf file, it seems that they have replaced the steel case 
with a plastic
case.  If so, we are both wrong now, it is neither zinc nor steel but plastic. 
Having not bought
carbon zinc batteries for many years I was unaware that some manufacturers have 
replaced the
steel outer case with plastic.  I believe the lantern batteries are still using 
steel though.

Marshall


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