Hi David,

I have anticipated your answer and I think this is what you asked for. I
have used TPP to generate the DECOY database using these settings:

[image: image.png]

I have searched PEAKS again and uploaded the new file ‘
PEAKS_target_decoy.pep.xml’ and the decoy database to the shared folder.

Link: PEAKS Dataset
<https://drive.google.com/drive/folders/1Q3LF1wRTM62KfS20dfXmToQMY9ji9Dug>

See what you think of the output.

Best,
Sergio

--------------------------
Sergio Ciordia Higuera
Proteomics Facility
National Center for Biotechnology
C\Darwin, 3
Universidad Autónoma de Madrid
Cantoblanco
28049 Madrid (Spain)
Phone: +34 91 585 4540 / 4695
Fax: +34 91 585 4506


El jue, 10 oct 2024 a las 22:47, Sergio Ciordia (<[email protected]>)
escribió:

> OK, I think I understand you now. I think what you are asking me to do is
> to create a database containing the target and decoy entries and repeat the
> search. Then in the output that PEAKS gives us, we could locate the
> ‘unknown’ decoy. Is this what you need?.
>
> Sergio
>
> --------------------------
> Sergio Ciordia Higuera
> Proteomics Facility
> National Center for Biotechnology
> C\Darwin, 3
> Universidad Autónoma de Madrid
> Cantoblanco
> 28049 Madrid (Spain)
> Phone: +34 91 585 4540 / 4695
> Fax: +34 91 585 4506
>
>
> El jue, 10 oct 2024 a las 22:33, 'David Shteynberg' via spctools-discuss (<
> [email protected]>) escribió:
>
>> I think we have a bit of misunderstanding here.  I am not looking for
>> decoys that are "known" to PEAKS,  I want to include entrapment decoys that
>> are "unknown" to PEAKS and known to us as true negatives.  Then we can
>> utilized the true negatives to estimate error rates.  The true negative
>> entrapment decoys should not be revealed to the search algorithm, just like
>> the false positives among the target sequences are not known to the
>> algorithm, but represent the error we are trying to control.
>>
>> I hope this makes sense.
>>
>> -David
>>
>> On Thu, Oct 10, 2024 at 10:48 AM Sergio Ciordia <[email protected]>
>> wrote:
>>
>>> Hi David,
>>>
>>> There are several commercial softwares such as PEAKS or Proteome
>>> Discoverer that you upload the target database directly and they internally
>>> generate the Target-Decoy database. The problem is that when you launch the
>>> search and get the output, the software usually removes the decoy entries
>>> from the final results and that's why they don't appear in the list.
>>>
>>> I understand then that we would need the same ‘pep.xml’ file but
>>> containing all the target and decoy entries. Is that what you need?.
>>>
>>> Best,
>>> Sergio
>>>
>>> --------------------------
>>> Sergio Ciordia Higuera
>>> Proteomics Facility
>>> National Center for Biotechnology
>>> C\Darwin, 3
>>> Universidad Autónoma de Madrid
>>> Cantoblanco
>>> 28049 Madrid (Spain)
>>> Phone: +34 91 585 4540 / 4695
>>> Fax: +34 91 585 4506
>>>
>>>
>>> El jue, 10 oct 2024 a las 19:40, 'David Shteynberg' via spctools-discuss
>>> (<[email protected]>) escribió:
>>>
>>>> Hello Sergio,
>>>>
>>>> Thanks for sending this. After taking a look I have another request.
>>>> The database you searched against seems to not contain any entrapment
>>>> DECOYS to help independently validate any computed scores or
>>>> probabilities.  Are you able to search this data against a database
>>>> containing some decoys?  You can use the TPP decoy generator to create
>>>> decoys (we have been using deBruijn randomized sequences), or should I
>>>> create it and give you the database to search?
>>>>
>>>> Best,
>>>> -David
>>>>
>>>> On Thu, Oct 10, 2024 at 3:52 AM Sergio Ciordia <[email protected]>
>>>> wrote:
>>>>
>>>>> Thank you David. You are right, I attach in this new link the 3 files
>>>>> you need: mzML, fasta and pep.xml.
>>>>>
>>>>> Link: PEAKS Dataset
>>>>> <https://drive.google.com/drive/folders/1Q3LF1wRTM62KfS20dfXmToQMY9ji9Dug>
>>>>>
>>>>> I hope you can do something. Thanks anyway for your concern.
>>>>>
>>>>> Best regards,
>>>>> Sergio
>>>>>
>>>>> --------------------------
>>>>> Sergio Ciordia Higuera
>>>>> Proteomics Facility
>>>>> National Center for Biotechnology
>>>>> C\Darwin, 3
>>>>> Universidad Autónoma de Madrid
>>>>> Cantoblanco
>>>>> 28049 Madrid (Spain)
>>>>> Phone: +34 91 585 4540 / 4695
>>>>> Fax: +34 91 585 4506
>>>>>
>>>>>
>>>>> El jue, 10 oct 2024 a las 1:34, David Shteynberg (<
>>>>> [email protected]>) escribió:
>>>>>
>>>>>> Thank you Sergio!  Would you mind also sending the mzML data and the
>>>>>> sequence database that goes along with these search results from PEAKS?
>>>>>>
>>>>>> Best,
>>>>>> -David
>>>>>>
>>>>>> On Oct 9, 2024, at 3:58 PM, Sergio Ciordia <[email protected]>
>>>>>> wrote:
>>>>>>
>>>>>> Hi David,
>>>>>>
>>>>>> Thank you for your quick and honest response. I am sorry to hear that
>>>>>> you have no funds to continue TPP implementation. I hope this problem 
>>>>>> will
>>>>>> be solved.
>>>>>> Nevertheless, I appreciate your consideration of evaluating a sample
>>>>>> file. This file contains what the PEAKS team calls ‘Peptide output in
>>>>>> pepxml’. I hope it is adequate but in any case I don't think there will 
>>>>>> be
>>>>>> a problem in getting a suitable data output for TPP if necessary. The 
>>>>>> other
>>>>>> format that can be obtained is mzidentML in case it is of interest.
>>>>>>
>>>>>> LINK: pepXML PEAKS sample
>>>>>> <https://drive.google.com/file/d/185t5m7vJPLQAj8vVpcviX_p58DHZfyAB/view?usp=sharing>
>>>>>>
>>>>>> Thanks again for your reply.
>>>>>>
>>>>>> Best regards,
>>>>>> Sergio
>>>>>>
>>>>>> --------------------------
>>>>>> Sergio Ciordia Higuera
>>>>>> Proteomics Facility
>>>>>> National Center for Biotechnology
>>>>>> C\Darwin, 3
>>>>>> Universidad Autónoma de Madrid
>>>>>> Cantoblanco
>>>>>> 28049 Madrid (Spain)
>>>>>> Phone: +34 91 585 4540 / 4695
>>>>>> Fax: +34 91 585 4506
>>>>>>
>>>>>>
>>>>>> El jue, 10 oct 2024 a las 0:46, David Shteynberg (<
>>>>>> [email protected]>) escribió:
>>>>>>
>>>>>>> Hello Sergio,
>>>>>>>
>>>>>>> Thank you for your email.  As you know PEAKS is not a search engine
>>>>>>> that we have integrated in the TPP, mainly because we have not had any
>>>>>>> requests for this feature before your email.  It is something that can 
>>>>>>> be
>>>>>>> done with a bit of work and testing, but unfortunately there is 
>>>>>>> currently
>>>>>>> no funding for us to continue this work.  I wish I had a more satisfying
>>>>>>> answer to give you, but perhaps, if you can forward your sample pep.xml
>>>>>>> file, we can do this if more funding becomes available.
>>>>>>>
>>>>>>> Best,
>>>>>>> -David
>>>>>>>
>>>>>>> On Oct 9, 2024, at 3:35 PM, Sergio Ciordia <[email protected]>
>>>>>>> wrote:
>>>>>>>
>>>>>>> Hi,
>>>>>>>
>>>>>>> I have been using TPP for some time now mainly to validate with
>>>>>>> PeptideProphet the results I get with various search engines and to
>>>>>>> generate a spectral library that I use in various programs. The thing is
>>>>>>> that in my lab we are now using PEAKS (v12) and the output is really 
>>>>>>> good.
>>>>>>> I was wondering if it would be possible to include in TPP an analysis
>>>>>>> pipeline of the PEAKS data from the pep.xml file generated by the 
>>>>>>> program.
>>>>>>> I know it is a commercial software but the output is very good and I
>>>>>>> would be very grateful if you could consider including it like Sequest 
>>>>>>> or
>>>>>>> Mascot. I think it would not be complicated since they already have the
>>>>>>> pep.xml output, it would only have to be compatible with XInteract to be
>>>>>>> able to validate peptide-spectrum matches.
>>>>>>>
>>>>>>> If necessary I can provide a sample pep.xml file.
>>>>>>>
>>>>>>> Thank you very much.
>>>>>>>
>>>>>>> Best regards,
>>>>>>> Sergio
>>>>>>>
>>>>>>> --
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>>>>>>>
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