>> Distilleries that make grain alcohol for consumption usually don't make
>> anything that is 100%/200 proof.

There's a physical limit on distillation of ethanol from water---you
can only get 95.6% (191 proof). If you want better than that you have
to add benzene and distill that, but then the product contains trace
amounts of benzene and is not food-grade so it's much harder to
obtain. OK, so there's spectroscopically pure ethanol, involving
special processes and absurd price is.

http://en.wikipedia.org/wiki/Alcoholic_beverage

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