Got it.
I have made a small perl script as a service that would only return reject as a policy (that sould have rendered most of the mailing impossibble), and postfix was still mailing happily. Since I have recompiled Postfix from the source, it was out of the question the the process was faulty, so the only option is that Postfix couldn't connect to a local service.

It was the firewall. The FORWARD chain was set to drop all, and the rest is history......

Thanks everyone for the extraordinary efforts.

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