Re: [Biofuel] FFA's as Weed Killer

2006-05-04 Thread Thomas Kelly
Fox Mulder wrote:
hi, pouring glycerine on the leaves kills.
glycerine is alkaline; so, alkalinity kills leaves.
Further, methyl ester kills leaves.
 The best weed killer;
 Follow the ingredients;
glycerine left over from your biodiesel 2parts
sodium ethanoate  1part

We are talking about the FFAs separated out of the glycerine cocktail; 
the coproduct of biodiesel production.
The value of FFAs as a weed killer comes from the fact that it is readily 
broken down and there is minimum, if any contamination of the soil. The pH 
of the FFAs, as best I can determine, is very similar to the pH of my soil 
~ 6.5.
 It has been pointed out that the use of the glycerine left over from 
your biodiesel  kills weeds, but the concern is that it also kills 
earthworms  one of the hardest-working employees I have in my garden. 
My use of compost and a thick layer of mulch is as much an attempt to build 
an environment attractive to earthworms, saprophytic fungi and bacteria as 
it is to support plant growth directly. If fact, w/o these organisms, much 
of the nutrients tied up in the compost and mulch would not be available to 
my plants.
 Once separated (see JTF) the crude glycerine (methanol recovered) is 
slightly acidic, not alkaline. It can be neutralized it w.  baking soda or 
ammonia and can be used to produce biogas (methane), or added to the 
ferment  ethanol. At the moment, I neutralize it w. ammonia and add it 
to my compost (1 part glycerine: 2 parts water). The glycerine is rapidly 
metabolized for energy and the ammonia contributes nitrogen. It seems to 
work well.
 The minerals that precipitate out upon separation of the cocktail (in 
my case a mix of sodium and potassium phosphate) are fertilizers. My compost 
piles are essentially layers of grass clippings, then leaves, then manure 
..  repeat. I dissolve about 1 tablespoon of the mineral precip. in the 
water that I mix with the glycerine and pour it on the leaf layer using a 
watering can. I have several pounds of mineral precip and many gallons of 
glycerine, so I may have to find other ways to use it, but am more than 
hesitant to spray either directly on my garden or flower beds.
That leaves the FFAs from separation. I've noodled around with adding 
them to my heating fuel (BD100). I suspect that there was some glycerine 
contamination because after a bout a week to 10 days the electrodes in my 
burner were coated w.  a thick, crusty goo. I'll let it settle for a month 
at warmer temp  get back to that , but for now, FFAs as weed killers has 
caught my interest.
 Sorry to get so wordy. I'm not adding anything new. It has all been 
discussed at JTF and by list members. The discussion, so far, has put an 
emphasis on the minimal environmental impact of FFAs as weed killers, not 
that they are the best, as in most effective. After all there's always 
Roundup or 2,4-D if one simply wants to kill plants w/o worrying about 
consequences.
Tom 



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Re: [Biofuel] FFA's as Weed Killer

2006-05-03 Thread fox mulder

--- Ryan Pope [EMAIL PROTECTED] wrote:

From what I remember from my botany courses,
 plant leaves are also very 
 tightly regulated to reduce water loss.  A leaf is
 basically a large, flat 
 surface coursing with fluid; exactly what you would
 do to promote 
 evaporation.  To slow evap., most leaves have
 passive pores that close in 
 dry conditions as well as a secreted waxy surface. 
 If the FFA were 
 disrupting the waxy surface or causing the pores to
 open or both, you would 
 get rapid fluid loss, browning, wilting, etc., but
 the plant would repair 
 and recover in a short time.
 
Gooeyness...hmmm...surface gooeyness?  Or the
 whole leaf is a spongey 
 mess?  Maybe the waxy seal balling up like oil drops
 in water?
 
Ryan
 
 
 From: Thomas Kelly [EMAIL PROTECTED]
 Reply-To: biofuel@sustainablelists.org
 To: biofuel@sustainablelists.org
 Subject: Re: [Biofuel] FFA's as Weed Killer
 Date: Tue, 2 May 2006 14:25:47 -0400
 
 Bob,
   In response to my note: One day later
 ~24hrs, the leaves were 
 browning
 and wilted.
   You wrote:
  I sure would like to see some references on the
 mechanism of this 
 effect.
 
   I wonder if the FFAs are disrupting the
 structure of cell membranes.
 All cell membranes are phospholipid bilayers with
 hydrophobic fatty acids
 pointing inward towards each other and away from
 water. The hydrophilic
 phosphates are on the inner and outer surfaces
 interacting w. water. 
 Replace
 water w.FFAs and this structure could be
 compromised.
  After 24 hrs the leaves are more than wilted,
 they are gooey (for lack
 of a better word).
  I'd be interested in knowing the mechanism as
 well. I dug up a few
 treated dandelions 3 - 4 days after treatment. The
 roots seemed fine. This
 morning, a week after treatment, some of the
 sprayed plants are sprouting
 new leaves and the sickly-looking dandelions have
 sent up new flowers. The
 effect does not seem to be systemic.
 I like that. It seems very effective against a
 variety of weeds that lack
 tap roots or runners.
   
 Tom
 
 
 - Original Message -
 From: bob allen [EMAIL PROTECTED]
 To: biofuel@sustainablelists.org
 Sent: Tuesday, May 02, 2006 11:49 AM
 Subject: Re: [Biofuel] FFA's as Weed Killer
 
 
 
 Howdy
 
 Thomas Kelly wrote:
   Hi Bob,
   What do you mean  a dilute solution?   I
 sprayed the FFAs, full
   strength, on the leaves of some weeds.
 
 I guess my assumption was wrong- when I recover
 ffa's I get a very
 viscous liquid which would be hard to spray. but
 then my wvo is about
 half saturated fat.
 
 
   One day later ~24hrs, the leaves were browning
 and wilted.
 
 I think todd also mentioned such an effect.  I sure
 would like to see
 some references on the mechanism of this effect.
 
How would I test the pH of FFAs? I use wide
 range pH paper to test 
 my
   wash water. I don't think they'll work on FFAs.
 
 try taking a gram or so of your ffa's and add it to
 about 100ml water.
 Free fatty acids will not dissolve well and should
 not change the pH
 paper reading.  I just tried it with a sample of
 oleic acid. pH of the
 solution/emulsion was unchanged after adding the
 oleic acid.
 
 
It appears as though some of the weeds I
 sprayed last week are
   sending
   up new shoots.
 
 I'll try spraying some oleic acid on a plant or two
 (as soon as it quits
 raining) and see what happens.
 
 
   
Tom
   - Original Message -
   From: bob allen [EMAIL PROTECTED]
   To: biofuel@sustainablelists.org
   Sent: Monday, May 01, 2006 11:34 AM
   Subject: Re: [Biofuel] FFA's as Weed Killer
  
  
 howdy Thomas
  
   I am a little surprised that a dilute solution
 of ffa's would have any
   impact on plant life over a 24 hour period. My
 guess is that your
   solution contains more than ffa's.  What is the
 pH ? how about total
   dissolved solids, ie salts ?  Do you have any
 idea of the concentration
   of the ffa (in water I assume)?
  
   Thomas Kelly wrote:
  I've been gardening for over 30 years by
 essentially building dirt
   and caring for my plants from the ground up.
   I've been know to chop off a weed's head now
 and again or yank them 
 from
   the ground. I've squished bugs by the
 thousands and lured others to
   deadly traps. I've never used a spray that has
 any real obvious results
   (dead insects or weeds).
  I've been splitting my glycerine co-product
 into FFA's, potassium
   (and some sodium) phosphate, and crude
 glycerine.
  Yesterday I sprayed FFA's on some weeds in
 an area of the garden 
 that
   hasn't been turned yet. Today they appear to be
 dying. It didn't seem 
 to
   discriminate ... dandelions, wild mustard,
 plantain, grass  all
   withering.
  I'm a bit taken back. The sprays I concoct
 from chives, peppers,
   mulberry leaves etc. are intended to
 repel/discourage pests. I don't 
 see
   any corpses

Re: [Biofuel] FFA's as Weed Killer

2006-05-02 Thread Thomas Kelly
Hi Bob,
What do you mean  a dilute solution?   I sprayed the FFAs, full 
strength, on the leaves of some weeds.
One day later ~24hrs, the leaves were browning and wilted.
 How would I test the pH of FFAs? I use wide range pH paper to test my 
wash water. I don't think they'll work on FFAs.
 It appears as though some of the weeds I sprayed last week are sending 
up new shoots.
Tom
- Original Message - 
From: bob allen [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Monday, May 01, 2006 11:34 AM
Subject: Re: [Biofuel] FFA's as Weed Killer


  howdy Thomas

I am a little surprised that a dilute solution of ffa's would have any
impact on plant life over a 24 hour period. My guess is that your
solution contains more than ffa's.  What is the pH ? how about total
dissolved solids, ie salts ?  Do you have any idea of the concentration
of the ffa (in water I assume)?

Thomas Kelly wrote:
I've been gardening for over 30 years by essentially building dirt
 and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them from
 the ground. I've squished bugs by the thousands and lured others to
 deadly traps. I've never used a spray that has any real obvious results
 (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden that
 hasn't been turned yet. Today they appear to be dying. It didn't seem to
 discriminate ... dandelions, wild mustard, plantain, grass  all
 withering.
I'm a bit taken back. The sprays I concoct from chives, peppers,
 mulberry leaves etc. are intended to repel/discourage pests. I don't see
 any corpses. It's more a matter of faith or delusion that they are
 working ... I don't care which. Weeds involve physical removal and
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only
 24 hrs after spraying. What is the mechanism of FFA action on plants?
 Does it act on the lipid component of the cell membranes? Is it systemic
 or just act on the point of contact - the leaves. If it only acts on the
 leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed killers,
 it would be very good news to an aging gardener who turns each section
 of the garden by hand, meticulously picking out the weeds. I don't mind
 the turning, countless tons of compost over the years has turned shallow
 hard-pan clay into beautiful rich soil that takes little effort to turn.
 It's the bending to pick the weeds that gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both mentioned
 FFA's as weed killer.
  My back thanks you,
 Tom


 

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Re: [Biofuel] FFA's as Weed Killer

2006-05-02 Thread bob allen

Howdy

Thomas Kelly wrote:
 Hi Bob,
 What do you mean  a dilute solution?   I sprayed the FFAs, full 
 strength, on the leaves of some weeds.

I guess my assumption was wrong- when I recover ffa's I get a very 
viscous liquid which would be hard to spray. but then my wvo is about 
half saturated fat.


 One day later ~24hrs, the leaves were browning and wilted.

I think todd also mentioned such an effect.  I sure would like to see 
some references on the mechanism of this effect.

  How would I test the pH of FFAs? I use wide range pH paper to test my 
 wash water. I don't think they'll work on FFAs.

try taking a gram or so of your ffa's and add it to about 100ml water. 
Free fatty acids will not dissolve well and should not change the pH 
paper reading.  I just tried it with a sample of oleic acid. pH of the 
solution/emulsion was unchanged after adding the oleic acid.


  It appears as though some of the weeds I sprayed last week are sending 
 up new shoots.

I'll try spraying some oleic acid on a plant or two (as soon as it quits 
raining) and see what happens.


 Tom
 - Original Message - 
 From: bob allen [EMAIL PROTECTED]
 To: biofuel@sustainablelists.org
 Sent: Monday, May 01, 2006 11:34 AM
 Subject: Re: [Biofuel] FFA's as Weed Killer
 
 
   howdy Thomas
 
 I am a little surprised that a dilute solution of ffa's would have any
 impact on plant life over a 24 hour period. My guess is that your
 solution contains more than ffa's.  What is the pH ? how about total
 dissolved solids, ie salts ?  Do you have any idea of the concentration
 of the ffa (in water I assume)?
 
 Thomas Kelly wrote:
I've been gardening for over 30 years by essentially building dirt
 and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them from
 the ground. I've squished bugs by the thousands and lured others to
 deadly traps. I've never used a spray that has any real obvious results
 (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden that
 hasn't been turned yet. Today they appear to be dying. It didn't seem to
 discriminate ... dandelions, wild mustard, plantain, grass  all
 withering.
I'm a bit taken back. The sprays I concoct from chives, peppers,
 mulberry leaves etc. are intended to repel/discourage pests. I don't see
 any corpses. It's more a matter of faith or delusion that they are
 working ... I don't care which. Weeds involve physical removal and
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only
 24 hrs after spraying. What is the mechanism of FFA action on plants?
 Does it act on the lipid component of the cell membranes? Is it systemic
 or just act on the point of contact - the leaves. If it only acts on the
 leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed killers,
 it would be very good news to an aging gardener who turns each section
 of the garden by hand, meticulously picking out the weeds. I don't mind
 the turning, countless tons of compost over the years has turned shallow
 hard-pan clay into beautiful rich soil that takes little effort to turn.
 It's the bending to pick the weeds that gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both mentioned
 FFA's as weed killer.
  My back thanks you,
 Tom


 

 ___
 Biofuel mailing list
 Biofuel@sustainablelists.org
 http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org

 Biofuel at Journey to Forever:
 http://journeytoforever.org/biofuel.html

 Search the combined Biofuel and Biofuels-biz list archives (50,000 
 messages):
 http://www.mail-archive.com/biofuel@sustainablelists.org/

 
 


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http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves — Richard Feynman

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Re: [Biofuel] FFA's as Weed Killer

2006-05-02 Thread Keith Addison
Hi Tom

Hi Keith,

  Good for you! Thirty years in the same place?

This is the 28th year for this garden.

I don't even want to think about how many places I've lived in in the 
last 28 years. I'm trying to do the same thing here in 18 months! 
Well, I've done it before. I'd just love to go on building it up for 
another 25 years, but I won't have that chance. Actually only part of 
me would like that, the rest wouldn't, I'd soon rebel. We'll be off 
when we're finished, even if we keep the place on.

I have an area about 5M  X  7M that hasn't been turned yet. Weeds have
stuck their heads up and I did spray some of them with the FFA's two days
ago. I used a hand sprayer and aimed directly at the leaves to minimize soil
contamination. I don't doubt that FFA's break down rapidly in the soil,
but I was a little startled at how effective they are at damaging the leaves
of plants.
If they only kill the leaf, and are not systemic poisons, then shouldn't the
plant just send up new shoots?

If it's strong enough to survive the loss. I guess weeds and rough 
grasses should usually be strong enough.

 Enough of this writing. Time to go to work. I'll spray the weeds living
in 1/2 of the section and turn them under. I'll pull the weeds from the
other 1/2 as I turn the soil.
Maybe I'll even pot a few weeds and spray them to see if they regenerate.

I shall watch with interest from afar.

Best

Keith


Tom
   - Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Friday, April 28, 2006 1:51 PM
Subject: Re: [Biofuel] FFA's as Weed Killer


  Hello Tom
 
I've been gardening for over 30 years by essentially building
 dirt and caring for my plants from the ground up.
 
  Good for you! Thirty years in the same place?
 
 I've been know to chop off a weed's head now and again or yank them
 from the ground. I've squished bugs by the thousands and lured
 others to deadly traps. I've never used a spray that has any real
 obvious results (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden
 that hasn't been turned yet. Today they appear to be dying. It
 didn't seem to discriminate ... dandelions, wild mustard, plantain,
 grass  all withering.
I'm a bit taken back. The sprays I concoct from chives, peppers,
 mulberry leaves etc. are intended to repel/discourage pests. I don't
 see any corpses. It's more a matter of faith or delusion that they
 are working ... I don't care which.
 
  I think they discourage rather than kill, either directly or by
  strengthening the plant's resistance.
 
 Weeds involve physical removal and discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble
 only 24 hrs after spraying. What is the mechanism of FFA action on
 plants? Does it act on the lipid component of the cell membranes? Is
 it systemic or just act on the point of contact - the leaves. If it
 only acts on the leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed
 killers, it would be very good news to an aging gardener who turns
 each section of the garden by hand, meticulously picking out the
 weeds. I don't mind the turning, countless tons of compost over the
 years has turned shallow hard-pan clay into beautiful rich soil that
 takes little effort to turn. It's the bending to pick the weeds
 that gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both
 mentioned FFA's as weed killer.
 
  Also Ken Provost.
 
  You ask the same questions I do. I've been wanting to run some
  side-by-side trials of FFA, raw by-product and vinegar, especially of
  FFA, but I'm put off by not knowing the mechanism, especially whether
  it's systemic or point-of-contact, and its residual effect on the
  soil life before it breaks down. What will FFA do to something like
  mycorrhizal fungi? I know that raw by-product kills worms,
  unsurprisingly, I expect FFA will too. So I'm reluctant to use it.
 
  Best
 
  Keith
 
 
  My back thanks you,
 Tom


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Re: [Biofuel] FFA's as Weed Killer

2006-05-02 Thread Thomas Kelly
Bob,
 In response to my note: One day later ~24hrs, the leaves were browning 
and wilted.
 You wrote:
 I sure would like to see some references on the mechanism of this effect.

 I wonder if the FFAs are disrupting the structure of cell membranes. 
All cell membranes are phospholipid bilayers with hydrophobic fatty acids 
pointing inward towards each other and away from water. The hydrophilic 
phosphates are on the inner and outer surfaces interacting w. water. Replace 
water w.FFAs and this structure could be compromised.
After 24 hrs the leaves are more than wilted, they are gooey (for lack 
of a better word).
I'd be interested in knowing the mechanism as well. I dug up a few 
treated dandelions 3 - 4 days after treatment. The roots seemed fine. This 
morning, a week after treatment, some of the sprayed plants are sprouting 
new leaves and the sickly-looking dandelions have sent up new flowers. The 
effect does not seem to be systemic.
I like that. It seems very effective against a variety of weeds that lack 
tap roots or runners.
  Tom


- Original Message - 
From: bob allen [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Tuesday, May 02, 2006 11:49 AM
Subject: Re: [Biofuel] FFA's as Weed Killer



Howdy

Thomas Kelly wrote:
 Hi Bob,
 What do you mean  a dilute solution?   I sprayed the FFAs, full
 strength, on the leaves of some weeds.

I guess my assumption was wrong- when I recover ffa's I get a very
viscous liquid which would be hard to spray. but then my wvo is about
half saturated fat.


 One day later ~24hrs, the leaves were browning and wilted.

I think todd also mentioned such an effect.  I sure would like to see
some references on the mechanism of this effect.

  How would I test the pH of FFAs? I use wide range pH paper to test my
 wash water. I don't think they'll work on FFAs.

try taking a gram or so of your ffa's and add it to about 100ml water.
Free fatty acids will not dissolve well and should not change the pH
paper reading.  I just tried it with a sample of oleic acid. pH of the
solution/emulsion was unchanged after adding the oleic acid.


  It appears as though some of the weeds I sprayed last week are 
 sending
 up new shoots.

I'll try spraying some oleic acid on a plant or two (as soon as it quits
raining) and see what happens.


 Tom
 - Original Message - 
 From: bob allen [EMAIL PROTECTED]
 To: biofuel@sustainablelists.org
 Sent: Monday, May 01, 2006 11:34 AM
 Subject: Re: [Biofuel] FFA's as Weed Killer


   howdy Thomas

 I am a little surprised that a dilute solution of ffa's would have any
 impact on plant life over a 24 hour period. My guess is that your
 solution contains more than ffa's.  What is the pH ? how about total
 dissolved solids, ie salts ?  Do you have any idea of the concentration
 of the ffa (in water I assume)?

 Thomas Kelly wrote:
I've been gardening for over 30 years by essentially building dirt
 and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them from
 the ground. I've squished bugs by the thousands and lured others to
 deadly traps. I've never used a spray that has any real obvious results
 (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden that
 hasn't been turned yet. Today they appear to be dying. It didn't seem to
 discriminate ... dandelions, wild mustard, plantain, grass  all
 withering.
I'm a bit taken back. The sprays I concoct from chives, peppers,
 mulberry leaves etc. are intended to repel/discourage pests. I don't see
 any corpses. It's more a matter of faith or delusion that they are
 working ... I don't care which. Weeds involve physical removal and
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only
 24 hrs after spraying. What is the mechanism of FFA action on plants?
 Does it act on the lipid component of the cell membranes? Is it systemic
 or just act on the point of contact - the leaves. If it only acts on the
 leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed killers,
 it would be very good news to an aging gardener who turns each section
 of the garden by hand, meticulously picking out the weeds. I don't mind
 the turning, countless tons of compost over the years has turned shallow
 hard-pan clay into beautiful rich soil that takes little effort to turn.
 It's the bending to pick the weeds that gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both mentioned
 FFA's as weed killer.
  My back thanks you,
 Tom

Re: [Biofuel] FFA's as Weed Killer

2006-05-02 Thread Ryan Pope
  From what I remember from my botany courses, plant leaves are also very 
tightly regulated to reduce water loss.  A leaf is basically a large, flat 
surface coursing with fluid; exactly what you would do to promote 
evaporation.  To slow evap., most leaves have passive pores that close in 
dry conditions as well as a secreted waxy surface.  If the FFA were 
disrupting the waxy surface or causing the pores to open or both, you would 
get rapid fluid loss, browning, wilting, etc., but the plant would repair 
and recover in a short time.


  Gooeyness...hmmm...surface gooeyness?  Or the whole leaf is a spongey 
mess?  Maybe the waxy seal balling up like oil drops in water?


  Ryan



From: Thomas Kelly [EMAIL PROTECTED]
Reply-To: biofuel@sustainablelists.org
To: biofuel@sustainablelists.org
Subject: Re: [Biofuel] FFA's as Weed Killer
Date: Tue, 2 May 2006 14:25:47 -0400

Bob,
 In response to my note: One day later ~24hrs, the leaves were 
browning

and wilted.
 You wrote:
 I sure would like to see some references on the mechanism of this 
effect.


 I wonder if the FFAs are disrupting the structure of cell membranes.
All cell membranes are phospholipid bilayers with hydrophobic fatty acids
pointing inward towards each other and away from water. The hydrophilic
phosphates are on the inner and outer surfaces interacting w. water. 
Replace

water w.FFAs and this structure could be compromised.
After 24 hrs the leaves are more than wilted, they are gooey (for lack
of a better word).
I'd be interested in knowing the mechanism as well. I dug up a few
treated dandelions 3 - 4 days after treatment. The roots seemed fine. This
morning, a week after treatment, some of the sprayed plants are sprouting
new leaves and the sickly-looking dandelions have sent up new flowers. The
effect does not seem to be systemic.
I like that. It seems very effective against a variety of weeds that lack
tap roots or runners.
  Tom


- Original Message -
From: bob allen [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Tuesday, May 02, 2006 11:49 AM
Subject: Re: [Biofuel] FFA's as Weed Killer



Howdy

Thomas Kelly wrote:
 Hi Bob,
 What do you mean  a dilute solution?   I sprayed the FFAs, full
 strength, on the leaves of some weeds.

I guess my assumption was wrong- when I recover ffa's I get a very
viscous liquid which would be hard to spray. but then my wvo is about
half saturated fat.


 One day later ~24hrs, the leaves were browning and wilted.

I think todd also mentioned such an effect.  I sure would like to see
some references on the mechanism of this effect.

  How would I test the pH of FFAs? I use wide range pH paper to test 
my

 wash water. I don't think they'll work on FFAs.

try taking a gram or so of your ffa's and add it to about 100ml water.
Free fatty acids will not dissolve well and should not change the pH
paper reading.  I just tried it with a sample of oleic acid. pH of the
solution/emulsion was unchanged after adding the oleic acid.


  It appears as though some of the weeds I sprayed last week are
 sending
 up new shoots.

I'll try spraying some oleic acid on a plant or two (as soon as it quits
raining) and see what happens.


 Tom
 - Original Message -
 From: bob allen [EMAIL PROTECTED]
 To: biofuel@sustainablelists.org
 Sent: Monday, May 01, 2006 11:34 AM
 Subject: Re: [Biofuel] FFA's as Weed Killer


   howdy Thomas

 I am a little surprised that a dilute solution of ffa's would have any
 impact on plant life over a 24 hour period. My guess is that your
 solution contains more than ffa's.  What is the pH ? how about total
 dissolved solids, ie salts ?  Do you have any idea of the concentration
 of the ffa (in water I assume)?

 Thomas Kelly wrote:
I've been gardening for over 30 years by essentially building dirt
 and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them 
from

 the ground. I've squished bugs by the thousands and lured others to
 deadly traps. I've never used a spray that has any real obvious results
 (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden 
that
 hasn't been turned yet. Today they appear to be dying. It didn't seem 
to

 discriminate ... dandelions, wild mustard, plantain, grass  all
 withering.
I'm a bit taken back. The sprays I concoct from chives, peppers,
 mulberry leaves etc. are intended to repel/discourage pests. I don't 
see

 any corpses. It's more a matter of faith or delusion that they are
 working ... I don't care which. Weeds involve physical removal and
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only
 24 hrs after spraying. What

Re: [Biofuel] FFA's as Weed Killer

2006-05-01 Thread bob allen
  howdy Thomas

I am a little surprised that a dilute solution of ffa's would have any 
impact on plant life over a 24 hour period. My guess is that your 
solution contains more than ffa's.  What is the pH ? how about total 
dissolved solids, ie salts ?  Do you have any idea of the concentration 
of the ffa (in water I assume)?

Thomas Kelly wrote:
I've been gardening for over 30 years by essentially building dirt 
 and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them from 
 the ground. I've squished bugs by the thousands and lured others to 
 deadly traps. I've never used a spray that has any real obvious results 
 (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium 
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden that 
 hasn't been turned yet. Today they appear to be dying. It didn't seem to 
 discriminate ... dandelions, wild mustard, plantain, grass  all 
 withering.
I'm a bit taken back. The sprays I concoct from chives, peppers, 
 mulberry leaves etc. are intended to repel/discourage pests. I don't see 
 any corpses. It's more a matter of faith or delusion that they are 
 working ... I don't care which. Weeds involve physical removal and 
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only 
 24 hrs after spraying. What is the mechanism of FFA action on plants? 
 Does it act on the lipid component of the cell membranes? Is it systemic 
 or just act on the point of contact - the leaves. If it only acts on the 
 leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed killers, 
 it would be very good news to an aging gardener who turns each section 
 of the garden by hand, meticulously picking out the weeds. I don't mind 
 the turning, countless tons of compost over the years has turned shallow 
 hard-pan clay into beautiful rich soil that takes little effort to turn. 
 It's the bending to pick the weeds that gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both mentioned 
 FFA's as weed killer.
  My back thanks you,
 Tom
 
 
 
 
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from fooling ourselves — Richard Feynman

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Re: [Biofuel] FFA's as Weed Killer

2006-05-01 Thread Mike Weaver
How do you separate out the FFA's?

bob allen wrote:

  howdy Thomas

I am a little surprised that a dilute solution of ffa's would have any 
impact on plant life over a 24 hour period. My guess is that your 
solution contains more than ffa's.  What is the pH ? how about total 
dissolved solids, ie salts ?  Do you have any idea of the concentration 
of the ffa (in water I assume)?

Thomas Kelly wrote:
  

   I've been gardening for over 30 years by essentially building dirt 
and caring for my plants from the ground up.
I've been know to chop off a weed's head now and again or yank them from 
the ground. I've squished bugs by the thousands and lured others to 
deadly traps. I've never used a spray that has any real obvious results 
(dead insects or weeds).
   I've been splitting my glycerine co-product into FFA's, potassium 
(and some sodium) phosphate, and crude glycerine.
   Yesterday I sprayed FFA's on some weeds in an area of the garden that 
hasn't been turned yet. Today they appear to be dying. It didn't seem to 
discriminate ... dandelions, wild mustard, plantain, grass  all 
withering.
   I'm a bit taken back. The sprays I concoct from chives, peppers, 
mulberry leaves etc. are intended to repel/discourage pests. I don't see 
any corpses. It's more a matter of faith or delusion that they are 
working ... I don't care which. Weeds involve physical removal and 
discouragement with thick mulch.
 The weeds sprayed w. FFA's appear to be in serious trouble only 
24 hrs after spraying. What is the mechanism of FFA action on plants? 
Does it act on the lipid component of the cell membranes? Is it systemic 
or just act on the point of contact - the leaves. If it only acts on the 
leaves, will new shoots be sent up?
 If FFA's are non-toxic, biodegradable, and effective weed killers, 
it would be very good news to an aging gardener who turns each section 
of the garden by hand, meticulously picking out the weeds. I don't mind 
the turning, countless tons of compost over the years has turned shallow 
hard-pan clay into beautiful rich soil that takes little effort to turn. 
It's the bending to pick the weeds that gets to my back.
 I believe Todd Swearingen and Prof. Bob Allen have both mentioned 
FFA's as weed killer.
 My back thanks you,
Tom




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Re: [Biofuel] FFA's as Weed Killer

2006-05-01 Thread Appal Energy
See the glycerol separation section at JTF.

FFAs (100% pure) rise to the surface.

They're not soluble in water.

In their pure state they would be be applied in a similar manner as used 
by county and state road crews to curb weeds along asphalt roadways.

Todd Swearingen

.

Mike Weaver wrote:

How do you separate out the FFA's?

bob allen wrote:

  

 howdy Thomas

I am a little surprised that a dilute solution of ffa's would have any 
impact on plant life over a 24 hour period. My guess is that your 
solution contains more than ffa's.  What is the pH ? how about total 
dissolved solids, ie salts ?  Do you have any idea of the concentration 
of the ffa (in water I assume)?

Thomas Kelly wrote:
 



  I've been gardening for over 30 years by essentially building dirt 
and caring for my plants from the ground up.
I've been know to chop off a weed's head now and again or yank them from 
the ground. I've squished bugs by the thousands and lured others to 
deadly traps. I've never used a spray that has any real obvious results 
(dead insects or weeds).
  I've been splitting my glycerine co-product into FFA's, potassium 
(and some sodium) phosphate, and crude glycerine.
  Yesterday I sprayed FFA's on some weeds in an area of the garden that 
hasn't been turned yet. Today they appear to be dying. It didn't seem to 
discriminate ... dandelions, wild mustard, plantain, grass  all 
withering.
  I'm a bit taken back. The sprays I concoct from chives, peppers, 
mulberry leaves etc. are intended to repel/discourage pests. I don't see 
any corpses. It's more a matter of faith or delusion that they are 
working ... I don't care which. Weeds involve physical removal and 
discouragement with thick mulch.
The weeds sprayed w. FFA's appear to be in serious trouble only 
24 hrs after spraying. What is the mechanism of FFA action on plants? 
Does it act on the lipid component of the cell membranes? Is it systemic 
or just act on the point of contact - the leaves. If it only acts on the 
leaves, will new shoots be sent up?
If FFA's are non-toxic, biodegradable, and effective weed killers, 
it would be very good news to an aging gardener who turns each section 
of the garden by hand, meticulously picking out the weeds. I don't mind 
the turning, countless tons of compost over the years has turned shallow 
hard-pan clay into beautiful rich soil that takes little effort to turn. 
It's the bending to pick the weeds that gets to my back.
I believe Todd Swearingen and Prof. Bob Allen have both mentioned 
FFA's as weed killer.
My back thanks you,
   Tom




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Re: [Biofuel] FFA's as Weed Killer

2006-04-29 Thread Thomas Kelly
Hi Keith,

 Good for you! Thirty years in the same place?

This is the 28th year for this garden.

I have an area about 5M  X  7M that hasn't been turned yet. Weeds have 
stuck their heads up and I did spray some of them with the FFA's two days 
ago. I used a hand sprayer and aimed directly at the leaves to minimize soil 
contamination. I don't doubt that FFA's break down rapidly in the soil, 
but I was a little startled at how effective they are at damaging the leaves 
of plants.
If they only kill the leaf, and are not systemic poisons, then shouldn't the 
plant just send up new shoots?
 Enough of this writing. Time to go to work. I'll spray the weeds living 
in 1/2 of the section and turn them under. I'll pull the weeds from the 
other 1/2 as I turn the soil.
Maybe I'll even pot a few weeds and spray them to see if they regenerate.
Tom
   - Original Message - 
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Friday, April 28, 2006 1:51 PM
Subject: Re: [Biofuel] FFA's as Weed Killer


 Hello Tom

   I've been gardening for over 30 years by essentially building
dirt and caring for my plants from the ground up.

 Good for you! Thirty years in the same place?

I've been know to chop off a weed's head now and again or yank them
from the ground. I've squished bugs by the thousands and lured
others to deadly traps. I've never used a spray that has any real
obvious results (dead insects or weeds).
   I've been splitting my glycerine co-product into FFA's, potassium
(and some sodium) phosphate, and crude glycerine.
   Yesterday I sprayed FFA's on some weeds in an area of the garden
that hasn't been turned yet. Today they appear to be dying. It
didn't seem to discriminate ... dandelions, wild mustard, plantain,
grass  all withering.
   I'm a bit taken back. The sprays I concoct from chives, peppers,
mulberry leaves etc. are intended to repel/discourage pests. I don't
see any corpses. It's more a matter of faith or delusion that they
are working ... I don't care which.

 I think they discourage rather than kill, either directly or by
 strengthening the plant's resistance.

Weeds involve physical removal and discouragement with thick mulch.
 The weeds sprayed w. FFA's appear to be in serious trouble
only 24 hrs after spraying. What is the mechanism of FFA action on
plants? Does it act on the lipid component of the cell membranes? Is
it systemic or just act on the point of contact - the leaves. If it
only acts on the leaves, will new shoots be sent up?
 If FFA's are non-toxic, biodegradable, and effective weed
killers, it would be very good news to an aging gardener who turns
each section of the garden by hand, meticulously picking out the
weeds. I don't mind the turning, countless tons of compost over the
years has turned shallow hard-pan clay into beautiful rich soil that
takes little effort to turn. It's the bending to pick the weeds
that gets to my back.
 I believe Todd Swearingen and Prof. Bob Allen have both
mentioned FFA's as weed killer.

 Also Ken Provost.

 You ask the same questions I do. I've been wanting to run some
 side-by-side trials of FFA, raw by-product and vinegar, especially of
 FFA, but I'm put off by not knowing the mechanism, especially whether
 it's systemic or point-of-contact, and its residual effect on the
 soil life before it breaks down. What will FFA do to something like
 mycorrhizal fungi? I know that raw by-product kills worms,
 unsurprisingly, I expect FFA will too. So I'm reluctant to use it.

 Best

 Keith


 My back thanks you,
Tom


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 messages):
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[Biofuel] FFA's as Weed Killer

2006-04-28 Thread Thomas Kelly



 I've been gardening for over 30 years 
by essentially "building dirt" and caring for my plants from the ground up. 

I've been know to chop off a weed's head now and 
again or yank them from the ground. I've squished "bugs" by the 
thousandsand lured others to deadly traps. I've never used a spray that 
has any real obvious results (dead insects or "weeds"). 
 I've been splitting my glycerine 
co-product into FFA's, potassium (and some sodium) phosphate, and crude 
glycerine.
Yesterday I sprayed FFA's on some 
weeds in an area of the garden that hasn't been turned yet. Today they appear to 
be dying. It didn't seem to discriminate ... dandelions, wild mustard, plantain, 
grass  all withering. 
 I'm a bit taken back. The sprays I 
concoct from chives, peppers, mulberry leaves etc. are intended to 
repel/discourage pests. I don't see any corpses.It's more a matter of 
faith or delusion that they are working ...I don't care which. Weeds 
involve physical removal and discouragement with thick mulch.
 The "weeds" sprayed w. 
FFA's appear to be in serious trouble only 24 hrs after spraying. What is the 
mechanism of FFA action on plants? Does it act on the lipid component of the 
cell membranes? Is it systemic or just act on the point of contact - the leaves. 
If it only acts on the leaves, will new shoots be sent up?
 If FFA's are non-toxic, 
biodegradable, and effective weed killers, it would be very good news to an 
aging gardener who turns each section of the garden by hand, meticulously 
picking outthe weeds. I don't mind the turning, countless tons of compost 
over the years has turned shallow hard-pan clay into beautiful rich soil that 
takes little effort to turn. It's the bending to pick the "weeds" that gets to 
my back.
 I believe Todd Swearingen 
and Prof. Bob Allen have both mentioned FFA's as weed killer. 
My back thanks 
you,
 
Tom
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Re: [Biofuel] FFA's as Weed Killer

2006-04-28 Thread Appal Energy
  What is the mechanism of FFA action on plants?

Suffocation and some burning if in direct sunlight.

The consolation about veg oils or FFAs when land applied is that the 
microbes needed to degrade them are readily present and in high 
populations, opposed to fossil oils, where the type needed are very 
small in number in comparison.

Todd Swearingen


Thomas Kelly wrote:

I've been gardening for over 30 years by essentially building 
 dirt and caring for my plants from the ground up.
 I've been know to chop off a weed's head now and again or yank them 
 from the ground. I've squished bugs by the thousands and lured 
 others to deadly traps. I've never used a spray that has any real 
 obvious results (dead insects or weeds).
I've been splitting my glycerine co-product into FFA's, potassium 
 (and some sodium) phosphate, and crude glycerine.
Yesterday I sprayed FFA's on some weeds in an area of the garden 
 that hasn't been turned yet. Today they appear to be dying. It didn't 
 seem to discriminate ... dandelions, wild mustard, plantain, grass 
  all withering.
I'm a bit taken back. The sprays I concoct from chives, peppers, 
 mulberry leaves etc. are intended to repel/discourage pests. I don't 
 see any corpses. It's more a matter of faith or delusion that they are 
 working ... I don't care which. Weeds involve physical removal and 
 discouragement with thick mulch.
  The weeds sprayed w. FFA's appear to be in serious trouble only 
 24 hrs after spraying. What is the mechanism of FFA action on plants? 
 Does it act on the lipid component of the cell membranes? Is it 
 systemic or just act on the point of contact - the leaves. If it only 
 acts on the leaves, will new shoots be sent up?
  If FFA's are non-toxic, biodegradable, and effective weed 
 killers, it would be very good news to an aging gardener who turns 
 each section of the garden by hand, meticulously picking out the 
 weeds. I don't mind the turning, countless tons of compost over the 
 years has turned shallow hard-pan clay into beautiful rich soil that 
 takes little effort to turn. It's the bending to pick the weeds that 
 gets to my back.
  I believe Todd Swearingen and Prof. Bob Allen have both mentioned 
 FFA's as weed killer.
  My back thanks you,
 Tom



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Re: [Biofuel] FFA's as Weed Killer

2006-04-28 Thread Keith Addison
Hello Tom

   I've been gardening for over 30 years by essentially building 
dirt and caring for my plants from the ground up.

Good for you! Thirty years in the same place?

I've been know to chop off a weed's head now and again or yank them 
from the ground. I've squished bugs by the thousands and lured 
others to deadly traps. I've never used a spray that has any real 
obvious results (dead insects or weeds).
   I've been splitting my glycerine co-product into FFA's, potassium 
(and some sodium) phosphate, and crude glycerine.
   Yesterday I sprayed FFA's on some weeds in an area of the garden 
that hasn't been turned yet. Today they appear to be dying. It 
didn't seem to discriminate ... dandelions, wild mustard, plantain, 
grass  all withering.
   I'm a bit taken back. The sprays I concoct from chives, peppers, 
mulberry leaves etc. are intended to repel/discourage pests. I don't 
see any corpses. It's more a matter of faith or delusion that they 
are working ... I don't care which.

I think they discourage rather than kill, either directly or by 
strengthening the plant's resistance.

Weeds involve physical removal and discouragement with thick mulch.
 The weeds sprayed w. FFA's appear to be in serious trouble 
only 24 hrs after spraying. What is the mechanism of FFA action on 
plants? Does it act on the lipid component of the cell membranes? Is 
it systemic or just act on the point of contact - the leaves. If it 
only acts on the leaves, will new shoots be sent up?
 If FFA's are non-toxic, biodegradable, and effective weed 
killers, it would be very good news to an aging gardener who turns 
each section of the garden by hand, meticulously picking out the 
weeds. I don't mind the turning, countless tons of compost over the 
years has turned shallow hard-pan clay into beautiful rich soil that 
takes little effort to turn. It's the bending to pick the weeds 
that gets to my back.
 I believe Todd Swearingen and Prof. Bob Allen have both 
mentioned FFA's as weed killer.

Also Ken Provost.

You ask the same questions I do. I've been wanting to run some 
side-by-side trials of FFA, raw by-product and vinegar, especially of 
FFA, but I'm put off by not knowing the mechanism, especially whether 
it's systemic or point-of-contact, and its residual effect on the 
soil life before it breaks down. What will FFA do to something like 
mycorrhizal fungi? I know that raw by-product kills worms, 
unsurprisingly, I expect FFA will too. So I'm reluctant to use it.

Best

Keith


 My back thanks you,
Tom


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