Just a quick reply to say Thanks for *both* your responses Marshall.

 

I'll break them down when I've gone through them and may get back to you at a 
later date.

 

Cheers

 

N.
 
> Date: Tue, 13 Apr 2010 15:26:10 -0400
> From: mdud...@king-cart.com
> To: silver-list@eskimo.com
> Subject: Re: CS>where is everyone?/..."TAITP~WBSF"?
> 
> The strength of the Tyndall "I", that is the intensity of the scattered 
> light to the light beam is given by the following equation:
> 
> I = kNV^2/w^4
> 
> where N is the number of particles, V is the volume of each particle, 
> and w is the wavelength of the light. From this we can see the following:
> 
> If a particle doubles in diameter, its volume will go up by a factor of 
> 8, and the intensity of the Tyndall from that particle will go up by 8^2 
> = 64, so the Tyndall goes up by the 6th power of the diameter. However, 
> if you are comparing the same ppm solutions with different particle 
> sizes, the number of particles will go down by a factor of 8, if you 
> double the size. Thus the intensity of the Tyndall from two colloids 
> with the same ppm, but a 2:1 difference in particle size will be 8:1, 
> that is it will vary to the 3rd power. That is why a bright Tyndall is 
> usually more indicative of particle size than concentration.
> 
> Now for a typical colloid the wavelength, is more dramatic. The 
> intensity will vary inversely by the 4th power of the light's 
> wavelength. For example, if you take blue laser of 330 nm and a red one 
> of 660 nm, that ratio will be 2:1, and the intensity of the Tyndall from 
> them would be that the blue one would be 2^4 or 16 times brighter.
> 
> Now from this is appears that the ratio of light scattered from small 
> and large particles will have the same ratio independent of the 
> wavelength of the light. This is true for the general case of most sols 
> which are of non-conductive particles. However silver and gold are 
> different, being very good conductors, they have resonances, somewhat 
> like an antenna. As it turns out silver particles of the following 
> sizes will have the following maximums on the Tyndall wavelengths:
> 
> 38 nm - 470 nm
> 47 nm - 490 nm
> 90 nm - 560 nm
> 118 nm - 600 nm
> 
> The fwhm of these runs approximately 1/2 of their peak wavelength.
> 
> If you look at 
> http://products.mercola.com/Images/home-tanning-beds/wavelength-chart.jpg 
> to see what colors the wavelengths are we find that red and amber sill 
> scatter much more by the 118 nm particles than the blue, and that for 38 
> nm particles, they will scatter blue better. From the chart I have the 
> ratio is rather large, 5:1 for the 38 nm between blue and amber and 
> almost 5:1 for the 118 between amber and blue. Thus there is a 25:1 
> difference between these two wavelengths and particle sizes. So it does 
> appear by using different colored light, and Tyndall intensity, to get a 
> crude handle on particle size and concentration over and above the 
> "color" of the sol. Only problem is that when the particle sizes get 
> below 30 or so nm, they both absorb and scatter UV light which cannot be 
> seen at all.
> 
> Marshall
> 
> 
> 
> Neville Munn wrote:
> > Now you're touching on a subject that I've been pondering for a while 
> > but can't seem to find anything of value to read in the public domain.
> > 
> > You mentioned red laser becoming less apparant, but 405nm blue DOES 
> > show up. I'm still curious to know if there are any methods of home 
> > determination of particle size approximation using laser lights, red 
> > or green or blue or whatever other colour which *could* indicate a 
> > particular nm range in the colour spectrum. If light can be used to 
> > determine approximate particle size is it possible one can make use of 
> > differing laser colours to approximate particle size in solution?
> > 
> > Praps you could help me out with this:
> > 
> > I got three red lasers, 
> > (1) 650nm+/-10 maximum output 1mW.......{bright beam passing thru liquid}
> > (2) 650nm+/-10 maximum output 5mW.......{beam of lesser brightness}
> > (3) 630-650nm maximum output 1mW........{no beam at all}
> > 
> > Is there anything you can tell me regarding the differences in beam 
> > strength between these lasers, all shone thru the same solution? 
> > Particularly the last one with no beam at all.
> > 
> > N.
> > 
> > ------------------------------------------------------------------------
> > Date: Tue, 13 Apr 2010 00:44:19 -0700
> > From: dokdal...@yahoo.com
> > Subject: Re: CS>where is everyone?/..."TAITP~WBSF"?
> > To: silver-list@eskimo.com
> >
> > 
> > FYI: Using a Blue 405-nm Laser, or even Green 
> > LD...can-detect smaller...Size!
> > Have gone down to 385-nm (non-laser) light source, using special TRIX 
> > & PMT.
> > (Not sure Particle(s) Size PEAKING at 405 nm, but-maybe...Marshall knows?)
> > 
> >
> > Tyndall will become LESS apparent (using RED), but 405~Blue 
> > still Detecting!
> > 
> > As long as it's only-slightly Yellow (and don't Smell/Taste 
> > like P*ss), it's GQQD
> > to use for ANY application you wanted, but for INTERNAL 
> > use...It's UP-to user?
> > 
> > 
> >
> >
> >
> > ------------------------------------------------------------------------
> > Looking for a hot date? View photos of singles in your area! 
> > <http://clk.atdmt.com/NMN/go/150855801/direct/01/>
> 
> 
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