If you put citric acid in your distilled water when doing the
electrolysis, it will produce silver citrate. It appears that chlorine
compounds do not combine with the citrate form. Apparently the citrate
has Ag3+, a complex, but silver chloride had Ag+, so once it is formed,
they do not interact even though both can disassociate in water to some
extent. Excess citric acid increases the solubility of silver citrate
significantly, otherwise you limit of solubility is around 250 ppm.
Marshall
On 1/16/2012 7:49 PM, mgperrault wrote:
If anyone would like to summarize about making silver citrate, I would
appreciate it. ratios? Silver must be oxide first? This is possible
with hydrogen peroxide? what about the 80% ions, what happens? Can
be made simply be adding citrate to water when making a batch with
typical low voltage method? chloride in lemon juice defeats the
purpose of the citrate?
Thank you
mg
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