Exactly.

This is why every lithium manufacturer recommends and uses a bms.



On Fri, Feb 15, 2013 at 10:20 AM, Lee Hart <[email protected]> wrote:

> On 2/15/2013 12:12 AM, Bruce EVangel Parmenter wrote:
>
>> -What voltage would be a good disconnect voltage set point for that 12V
>> Li-ion drop in battery? What voltage would prevent draining the Li-ion
>> battery too low causing damage?
>>
>
> With a 12v lead-acid, the traditional cutoff voltage under load is 10.5v.
> I suspect that the commercial cutoff devices aren't that precise, and
> probably cut off at anything from 9v to 11v.
>
> However, lead-acids have a useful feature. Their internal resistance goes
> up as their state of charge goes down. Before the cells go dead, their
> resistance gets high enough to cause an excessive voltage drop under load.
> This rather sudden voltage drop it what triggers the cutoff device to
> disconnect the load.
>
> Suppose all the cells are matched (same amphour capacity, same initial
> state of charge). Then when you hit 10.5v, the 6 cells in a 12v battery are
> each 1.75v under load. They aren't actually dead at this point. If you
> remove the load, the resistive voltage drop goes away, and they immediately
> bounce up to 1.95-2.0v. You haven't actually hurt the battery. Charge it
> back up, and it will be fine (subject to whatever wear and tear a deep
> cycle takes).
>
> Now, suppose the lead-acid cells are *not* all matched and balanced. When
> it reaches 10.5v, you may have 5 cells at 2.1v, and one cell at 0v. The one
> at 0v has just been *murdered*. This battery is not going to come back.
> Even if it seems to recharge, it will have lost most of its amphour
> capacity.
>
> Now let's try this same cutoff device with lithium. If you have a BMS, at
> 10.5v each of the 4 lithium cells has 2.625v. That will be fine. They're
> not dead yet, and they can be safely recharged and will survive.
>
> But suppose there is no BMS. Lithiums do not have the large resistance
> increase as they approach dead. The weakest cell keeps right on trying,
> right up to a few moments before it drops dead. At the 10.5v cutoff, you
> may have 3 cells at 3.1v, and one at 1.2v. The 1.2v cell's voltage won't
> bounce up to a "safe" voltage range. It has been seriously damaged, and
> won't recover. And without a BMS, you won't *know* you've damaged it, and
> may blithely keep using it, potentially leading to a fire!
>
> So that's the situation as I see it. When everything is fine, it works.
> When something goes wrong (like the cells wandering out of balance, or
> leaving the lights on, etc.), there is a risk of failure. If things go very
> wrong, the failure can be dramatic!
>
> --
> For every complex problem, there is a solution that is simple, obvious,
> and wrong. -- H.L. Mencken
> --
> Lee A. Hart, 
> http://www.sunrise-ev.com/**LeesEVs.htm<http://www.sunrise-ev.com/LeesEVs.htm>
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-- 
Marcus Reddish

*North Valley Systems LLC*
Stevensville, Montana
406-360-8628
northvalleyev.com
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