On 18 Nov 2015, at 10:34, Matt Bayliss wrote:

[4] TCP stream decoded acket capture of above session
http://pastebin.centos.org/36261/

The first line there which should be a SMTP greeting banner is instead:

220 ********************************************

That matches what I see when telnetting to port 25 on the host implied by the 'mydomain' parameter in your postconf output and since that's not what your smtpd_banner setting should yield, this must be external to your mail server. That is a strong indication that you have something very similar to a Cisco PIX or ASA firewall with its dysfunctional "fixup smtp" misfeature enabled, "protecting" that mail server from any risk of working properly.

Turn that off if you want to run a real mail server.

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