[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-02 Thread Keith Addison

womplex_oo1 wrote:

Ok fine. You win.  They don't teach this stuff in Canadian schools,
and I'm trying to find my way around using 50% intuition.  The
Journey to Forever website is really poorly organized - there is no
top-down comprehensive table of contents, and I can't download the
documents, say in pdf format, so that i can read them offline or
print them out so that I can read them while suffering less computer
screen walleye-vision-induced eye strain (the primary cause of
goldfish attention spans).

One thing I've learned from business: the more components of a
machine that you can make yourself, the lower your business costs.
What small start-up entrepreneurs need is comprehensive how-to
information,

- growing fungi  bacteria,
- extracting enzymes,
- appropriate containers for liquid processing,
- modular scalable steam explosion pre-processing equipment you can
build yourself,
- growing yeast,
- fermentation,
- making your own polyvinyl alcohol membranes,

and so on...

I repeat, the more components you have to buy from somewhere else,
the more expensive the end product.  To get the cost down, we
literally have to be able to do *everything* ourselves in one fully
integrated  optimized operation.

Repeat away, but hasn't it dawned on you by now that that's what 
we're discussing here all the time? If you can't see that that's 
exactly what Journey to Forever is on about, then you really are 
blind, or worse. And it's not just me who'd say that, we get loads of 
email from people all the time saying just the opposite of what you 
say, and also, very often, the opposite of your opinion that it's 
really poorly organized. That opinion I'd not be taking seriously 
from somebody who feels that PDF files are the route to proper 
organization. LOL! You can't grep dead trees. PDFs are a major reason 
the paperless office has failed to materialize - so you print it out, 
stuff it in a filing cabinet or something, or what, keep it on your 
hard disk? Have you got a full-text search program that will search 
it? (Whatever might be the advantage of that, eh?) Open it up, if you 
can ever find the thing, and no url, no way of knowing where it came 
from. It's as clunky as hell, and the type's all blurred - unlike 
html. That's probably where your goldfish vision comes from. Quite 
the most awkward, unwilling, otherwise piece of garbage to be found 
on the Web. That would really be the end of the Web, if websites were 
organized the way you want them to be. Why not learn something of the 
basics of downloading information from websites, and then handling it 
properly? Seriously, you're only getting a keyhole view of what's 
there, no use complaining about the keyhole - open the damn' door, 
it's not locked!

there is no
top-down comprehensive table of contents, and I can't download the

At the top-left on every page: Sitemap (text only)
http://journeytoforever.org/sitemap.html

We're not about to disorganize our website for the sake of the 
incompetent. Blind people can use it (they're among the most able 
users of the Internet, and I think PDFs are particularly unkind to 
them), people with really old gear can use it, kids can use it, 
everybody likes it, but you can't use it, and complain. You're the 
one out of step.

Keith


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Re: [biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-02 Thread Greg and April


- Original Message -
From: womplex_oo1 [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Sunday, September 01, 2002 22:53
Subject: [biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate
water-alcohol mixtures


 and I can't download the
 documents, say in pdf format, so that i can read them offline

There are many ways to read web documents off line. The one that I use the
most is to send my self an e-mail of the page, (and save it on computer as a
HTML) one reasion I like this one the best is because I can change the size
of the font with out much hasle (this can help with the eye strain).  I have
found that a few times, I may have to goto RTF (Rich Text Format) for the
e-mail then cut or copy-then paste.  If for some reasion that does not work,
I put it in My Favorites and mark it for off line viewing and down load
the web page.



 One thing I've learned from business: the more components of a
 machine that you can make yourself, the lower your business costs.
 What small start-up entrepreneurs need is comprehensive how-to
 information,

 - growing fungi  bacteria,
 - extracting enzymes,
 - appropriate containers for liquid processing,
 - modular scalable steam explosion pre-processing equipment you can
 build yourself,
 - growing yeast,
 - fermentation,
 - making your own polyvinyl alcohol membranes,


I have found that all I need to do is ask on this list, and more often than
not someone might have the answer, your question might be missed, and you
might have to ask again, but, hey we are all here for learning and shareing
info.


Greg H.



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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread womplex_oo1

I just found out that dessicants like silica gel only work in humid 
air (because of their high surface area, low vapor pressure pores).  

Osmosis would work to selectively separate water from ethanol.  The 
process uses a polyvinyl alcohol (PVA) membrane developed in Japan.  
The process consumes very little energy, requiring only a certain 
amount of pressure.

i've also found a gov't website on the conversion of whole plants 
(leaves, stem, roots) into fermentable sugars for ethanol 
production.  Here it is...

http://www.ott.doe.gov/biofuels/understanding_biomass.html

It's an interesting read. Particularly important because starchy 
granules comprise a very small percentage of plant material, and so 
by throwing away plant fiber, we're wasting 99 percent of the 
potential chemical energy available in plants, and hence also 99 
percent of the solar energy that went into growing the plants in the 
first place:

Component   Percent Dry Weight
--- 
Cellulose  40-60% 
Hemicellulose  20-40% 
Lignin 10-25% 


Apparently Lignin is the hardest component to hydrolize into 
fermentable sugars, and the ability to do this is critical to making 
biomass ethanol a consumer product.  Something like a 10-fold 
reduction in the cost of lignin-to-sugar enzymes is required, and 
intense research is ongoing to try to achieve this.




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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread Keith Addison

womplex_oo1 wrote:

I just found out that dessicants like silica gel only work in humid
air (because of their high surface area, low vapor pressure pores).

This is all in the archives, several times perhaps. You have several 
steps to go still before you find a good way of removing the 5% of 
the water content from 95% ethanol. For 15% ethanol, well. Keep 
trying I guess.

Osmosis would work to selectively separate water from ethanol.  The
process uses a polyvinyl alcohol (PVA) membrane developed in Japan.
The process consumes very little energy, requiring only a certain
amount of pressure.

i've also found a gov't website on the conversion of whole plants
(leaves, stem, roots) into fermentable sugars for ethanol
production.  Here it is...

http://www.ott.doe.gov/biofuels/understanding_biomass.html

Not much there. I think I've given you this before:
http://journeytoforever.org/ethanol_link.html#cellulose
Ethanol from cellulose

See especially Wood-Ethanol Report: Technology Review, Environment 
Canada 1999 -- good overview of the problem and the current solutions 
on offer.
http://www.pyr.ec.gc.ca/ep/wet/section16.html

It's an interesting read. Particularly important because starchy
granules comprise a very small percentage of plant material, and so
by throwing away plant fiber, we're wasting 99 percent of the
potential chemical energy available in plants, and hence also 99
percent of the solar energy that went into growing the plants in the
first place:

Your idea of waste and nature's idea of waste are two different 
things. What you call waste is returned to the soil to maintain the 
organic matter content, essential for everything - soil fertility, 
crop production, and the viability of the soilfoodweb, the tons of 
micro-organisms in an acre of soil that make plant growth possible.

So if you're going to take that away too and burn it in your car, 
what will you substitute for it? Chemical fertilizers?

Maybe you'll deign to answer this time. You seldom respond to 
questions people ask you here. It's a discussion group, you know.

Keith


Component   Percent Dry Weight
---
Cellulose  40-60%
Hemicellulose  20-40%
Lignin 10-25%


Apparently Lignin is the hardest component to hydrolize into
fermentable sugars, and the ability to do this is critical to making
biomass ethanol a consumer product.  Something like a 10-fold
reduction in the cost of lignin-to-sugar enzymes is required, and
intense research is ongoing to try to achieve this.


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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread womplex_oo1

What questions?  Perhaps I was away from my computer.  Anyways there 
is alot of information on that website about using cellulose as a 
feedstock, but the webpage has failed to justify it -- they 
completely failed to answer the question WHY???

Here is why:  Most plants are composed of less than 10% starch, the 
traditional component that is fermented into ethanol.  The remaining 
90% or more of the plant, by weight is composed of the following:

 
 Component   Percent Dry Weight
 ---
 Cellulose  40-60%
 Hemicellulose  20-40%
 Lignin 10-25%
 
 

These materials can be burned to generate heat, so to ignore them as 
a potential source of automotive fuel is a HUGE WASTE.  The Journey 
to Forever website doesn't pay enough attention to putting this 
capability into the hands of the general public.  Their webpages 
concentrate on using only the starch.  No wonder ethanol as an 
alternative fuel is not convincing enough people -- Not even the guys 
who build their own stills are going as far as they could.



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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread womplex_oo1

To add to that, we have guys from the University of Pennsylvania 
publishing scientific articles telling the public that using corn to 
make ethanol is a ZERO net producer of energy.  Most people just give 
up when they hear that.  But if you armed the public with the 
knowledge that they are throwing away 90 percent of the potential 
fuel, those researchers would get a professional slap upside the 
head, and probably issue a formal retraction of their paper.

You gotta tell people man.  More than that, you gotta make the 
technology available so that entrepreneurs can use it.






--- In [EMAIL PROTECTED], womplex_oo1 [EMAIL PROTECTED] wrote:
 What questions?  Perhaps I was away from my computer.  Anyways 
there 
 is alot of information on that website about using cellulose as a 
 feedstock, but the webpage has failed to justify it -- they 
 completely failed to answer the question WHY???
 
 Here is why:  Most plants are composed of less than 10% starch, the 
 traditional component that is fermented into ethanol.  The 
remaining 
 90% or more of the plant, by weight is composed of the following:
 
  
  Component   Percent Dry Weight
  ---
  Cellulose  40-60%
  Hemicellulose  20-40%
  Lignin 10-25%
  
  
 
 These materials can be burned to generate heat, so to ignore them 
as 
 a potential source of automotive fuel is a HUGE WASTE.  The Journey 
 to Forever website doesn't pay enough attention to putting this 
 capability into the hands of the general public.  Their webpages 
 concentrate on using only the starch.  No wonder ethanol as an 
 alternative fuel is not convincing enough people -- Not even the 
guys 
 who build their own stills are going as far as they could.


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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread womplex_oo1

Here is something else that really ticks me off:  coal liquefaction, 
making gasoline out of coal using the most environmentally 
destructive means, is getting far more attention than this.





--- In [EMAIL PROTECTED], womplex_oo1 [EMAIL PROTECTED] wrote:
 To add to that, we have guys from the University of Pennsylvania 
 publishing scientific articles telling the public that using corn 
to 
 make ethanol is a ZERO net producer of energy.  Most people just 
give 
 up when they hear that.  But if you armed the public with the 
 knowledge that they are throwing away 90 percent of the potential 
 fuel, those researchers would get a professional slap upside the 
 head, and probably issue a formal retraction of their paper.
 
 You gotta tell people man.  More than that, you gotta make the 
 technology available so that entrepreneurs can use it.
 
 
 
 
 
 
 --- In [EMAIL PROTECTED], womplex_oo1 [EMAIL PROTECTED] wrote:
  What questions?  Perhaps I was away from my computer.  Anyways 
 there 
  is alot of information on that website about using cellulose as a 
  feedstock, but the webpage has failed to justify it -- they 
  completely failed to answer the question WHY???
  
  Here is why:  Most plants are composed of less than 10% starch, 
the 
  traditional component that is fermented into ethanol.  The 
 remaining 
  90% or more of the plant, by weight is composed of the following:
  
   
   Component   Percent Dry Weight
   ---
   Cellulose  40-60%
   Hemicellulose  20-40%
   Lignin 10-25%
   
   
  
  These materials can be burned to generate heat, so to ignore them 
 as 
  a potential source of automotive fuel is a HUGE WASTE.  The 
Journey 
  to Forever website doesn't pay enough attention to putting this 
  capability into the hands of the general public.  Their webpages 
  concentrate on using only the starch.  No wonder ethanol as an 
  alternative fuel is not convincing enough people -- Not even the 
 guys 
  who build their own stills are going as far as they could.


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[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread Keith Addison

womplex_oo1 wrote:

What questions?

This one, for a start:

You:

 It's an interesting read. Particularly important because starchy
 granules comprise a very small percentage of plant material, and so
 by throwing away plant fiber, we're wasting 99 percent of the
 potential chemical energy available in plants, and hence also 99
 percent of the solar energy that went into growing the plants in the
 first place:

Me:

Your idea of waste and nature's idea of waste are two different
things. What you call waste is returned to the soil to maintain the
organic matter content, essential for everything - soil fertility,
crop production, and the viability of the soilfoodweb, the tons of
micro-organisms in an acre of soil that make plant growth possible.

So if you're going to take that away too and burn it in your car,
what will you substitute for it? Chemical fertilizers?

And now we have it again from you that it's a HUGE WASTE.

Perhaps I was away from my computer.  Anyways there
is alot of information on that website about using cellulose as a
feedstock, but the webpage has failed to justify it -- they
completely failed to answer the question WHY???

Huh? Journey to Forever doesn't tell you why, doesn't pay enough 
attention. Um, how many seconds did you spend there? It's said many 
web-surfers have the same attention span as a goldfish, 9 seconds. 
You spent more than 9 seconds at our ethanol pages and come away 
saying we don't justify it, don't say why, focus only on starch 
conversion? Then you talk about energy balances of ethanol, and you 
didn't see that there either? It's in the archives too, and in a few 
recent messages. But okay, if you insist, you pay lots of attention, 
we don't, LOL!

Here is why:  Most plants are composed of less than 10% starch, the
traditional component that is fermented into ethanol.  The remaining
90% or more of the plant, by weight is composed of the following:

 
  Component   Percent Dry Weight
  ---
  Cellulose  40-60%
  Hemicellulose  20-40%
  Lignin 10-25%
  
  

These materials can be burned to generate heat, so to ignore them as
a potential source of automotive fuel is a HUGE WASTE.

Before you start destroying even more topsoil than has already been 
destroyed by this type of thinking (?), try answering the question, 
eh? The obvious question. Curtis also commented on it, don't ignore 
him please.

The Journey
to Forever website doesn't pay enough attention to putting this
capability into the hands of the general public.  Their webpages
concentrate on using only the starch.  No wonder ethanol as an
alternative fuel is not convincing enough people -- Not even the guys
who build their own stills are going as far as they could.

You're being a bit ridiculous. AFAIK there is only one way available 
for anything less than an industry to make ethanol from cellulose, 
which is by acid hydrolysis, instructions for which are to be found 
at... ah, go have another look, it was right under your nose and you 
didn't see it.

The entire scientific establishment has so far failed to put that 
capability into anybody's hands effectively, it's not there yet, it's 
in the future. If you'd actually read the references you were sent 
you might have seen that. Arkenol, for instance, has been in the 
final development stages for more than three years, nothing happens. 
Lots of talk from Iogen, but not a lot of production yet, if any. And 
so on. Every year they get millions and millions in grants, and it 
still doesn't happen. I'm not knocking it, it'll happen - but YOU 
want US to make it happen yesterday? Sheesh!

It also seems to have escaped you that once the enzymes or whatever 
have converted the cellulose to sugars, it then follows the usual 
route - fermentation and distillation. They don't attempt to mop up 
all that water with bits of various kinds of blotting paper instead.

To add to that, we have guys from the University of Pennsylvania
publishing scientific articles telling the public that using corn to
make ethanol is a ZERO net producer of energy.  Most people just give
up when they hear that.

Cornell University, not Pennsylvania, his name is David Pimentel. 
Scientific articles is stretching it more than somewhat. There's a 
lot of info at Journey to Forever about it, including several 
complete debunkings, there's been LOTS of discussion about it here 
(the last four days ago - see Re: [biofuel] Re: ethanol economics), 
and these resources have been used to counter Pimentel's BS in quite 
a few instances. And you?

But if you armed the public with the
knowledge that they are throwing away 90 percent of the potential
fuel, those researchers would get a professional slap upside the
head, and probably issue a formal retraction of their paper.

Yes, no doubt, if it worked, which it doesn't, yet - but if you went 
about it your way you'd simply be handing Pimentel et al. a gun to 
shoot you with. 

[biofuel] Re: Polyvinyl Alcohol (PVA) Membranes to dehydrate water-alcohol mixtures

2002-09-01 Thread womplex_oo1

Ok fine. You win.  They don't teach this stuff in Canadian schools, 
and I'm trying to find my way around using 50% intuition.  The 
Journey to Forever website is really poorly organized - there is no 
top-down comprehensive table of contents, and I can't download the 
documents, say in pdf format, so that i can read them offline or 
print them out so that I can read them while suffering less computer 
screen walleye-vision-induced eye strain (the primary cause of 
goldfish attention spans).

One thing I've learned from business: the more components of a 
machine that you can make yourself, the lower your business costs.  
What small start-up entrepreneurs need is comprehensive how-to 
information,

- growing fungi  bacteria,
- extracting enzymes,
- appropriate containers for liquid processing,
- modular scalable steam explosion pre-processing equipment you can 
build yourself,
- growing yeast,
- fermentation,
- making your own polyvinyl alcohol membranes,

and so on...

I repeat, the more components you have to buy from somewhere else, 
the more expensive the end product.  To get the cost down, we 
literally have to be able to do *everything* ourselves in one fully 
integrated  optimized operation.



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