List,

I performed the following experiment:

Case 1 was to make one quart of CS using a constant 1 ma DC current for 4
hours with electrodes spaced about 2 inches and with constant stirring.
Starting V= 173.7 volts, I=0.86 ma, so R = 202K.  Ending V = 13.8, I=1.18
ma, so R= 11.7K.  Using Ivan's formala, the PPM was 1.3*(202/11.7) = 22.4
PPM.   uS measured 14.5 with Hanna PWT.  At the end there was some gunk
which sluffed off the wires and sunk to the bottom.

Case 2 is exactly the same as Case 1, except the polarity was reversed about
every 45 seconds.  Start V=168, I=0.96 so R=175K.  End V=30, I=1.16 so
R=25.9K.  PPM calculates to 8.8 and measured 6.7 uS.  Both wires were black,
but no gunk was produced.

Both batches have very faint Tyndall effect, visiable only in a dark room.
Case 1 was slightly more visible.  Both were made with Wallmart DW which
measures around 1 uS with the PWT.

So it is obvious to me that polarity reversing definitely produces a weaker
batch.  Case 1 is (14.5-1)/(6.7-1) = about 2.4 times stronger, comparing uS
measurements.  Or, case 1 is 22.4/8.8= about 2.5 times higher PPM using
Ivan's formula.

Granted this was not a highly controlled experiment.  One quart jar may have
had a bit more residual silver which had "plated out" on the glass than
another.  I may not have filled the jars to exactly the same level, the 120
volt line voltage may have been a bit different, etc.  But the difference
(more than a factor of 2) between polarity reversal and not is much too
large to be explained away be sloppy experiment procedures.

So it appears that one must run their constant current generator a bit more
than twice as long if polarity reversal is used to end up with the same PPM
for no reversal.  What is interesting is that at polarity reversal time, the
voltage rises up and settles back to the pre-switch voltage in just a few
seconds.  Thus one would think the production strength would not be affected
more than 10% or so instead of over 50%.

So, fellow scientists, why the big drop in uS or PPM when polarity switching
is used?  How about if some of you repeat the experiment to ensure my
findings are valid?  I suspect similar results will occur even if your
generator is not constant current (e.g. 3 9 volt batteries).

--Steve







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