Well, you are now talking about vacuum fermentation for which there is a 
patented process. Stripping off ethanol as it is produced solves one problem 
but the problem is that the vacuum system must deal with the massive amounts 
of carbon dioxide being generated by the fermentation process; so vacuum 
fermentation of ethanol never got off the ground.

Yes, it is possible to use a rather high vacuum to break the azeotrope and 
obtain 200 proof (absolute, anhydrous) ethanol. However, high vacuum 
distillation is best carried out in borosilicate glass, as metal stills are 
subject to crushing. A lot of ethanol will be wasted out the pump unless you 
have efficient cold trapping (usually acetone/dry ice slurry) with its own 
dangers. So, molecular sieves are easier and safer to render 96% ethanol 
anhydrous.

Also bear in mind that anhydrous ethanol will very efficiently soak up 
moisture from the air and return to the azeotropic state, so to keep it dry, 
you must handle it using special atmosphere-excluding techniques.

Hope this helps...

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