You could use a Carbon dioxide scrubber to remove the CO2 and then still
be able to use a vacuum for distillation.

The House of Jade wrote:

>  Well, you are now talking about vacuum fermentation for which there
> is a
> patented process. Stripping off ethanol as it is produced solves one
> problem
> but the problem is that the vacuum system must deal with the massive
> amounts
> of carbon dioxide being generated by the fermentation process; so
> vacuum
> fermentation of ethanol never got off the ground.
>
> Yes, it is possible to use a rather high vacuum to break the azeotrope
> and
> obtain 200 proof (absolute, anhydrous) ethanol. However, high vacuum
> distillation is best carried out in borosilicate glass, as metal
> stills are
> subject to crushing. A lot of ethanol will be wasted out the pump
> unless you
> have efficient cold trapping (usually acetone/dry ice slurry) with its
> own
> dangers. So, molecular sieves are easier and safer to render 96%
> ethanol
> anhydrous.
>
> Also bear in mind that anhydrous ethanol will very efficiently soak up
>
> moisture from the air and return to the azeotropic state, so to keep
> it dry,
> you must handle it using special atmosphere-excluding techniques.
>
> Hope this helps...
>
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