There are other ion paths from impurities in the electrodes and electrolyte 
that allow charge to flow in the other direction thus closing the circuit.

John Lindsay
johnslind...@mac.com
+61403577711

> On 24 Jun 2015, at 6:24 am, paul dove via EV <ev@lists.evdl.org> wrote:
> 
> Just so you know you are getting over my head but this is the way I 
> understand it.
> Inside a battery plain electrons can't travel around because it takes too 
> much energy to put a plain electron in solution. Electrons can only travel 
> inside the battery via charged chemicals, ions, which can dissolve off the 
> electrodes. The chemical reaction is what pushes the electrons inside toward 
> the negative end, because the electrodes at the two ends are made of 
> different materials, which have different chemical stability. 
> 
> 
>      From: Peri Hartman <pe...@kotatko.com>
> To: paul dove <dov...@bellsouth.net>; Electric Vehicle Discussion List 
> <ev@lists.evdl.org> 
> Sent: Tuesday, June 23, 2015 3:34 PM
> Subject: Re[2]: [EVDL] "Zero self-discharge"
> 
> So, let me try to paraphrase this.  Are you saying that
> - the electrolyte can only conduct ions,
> - with an open circuit (nothing connected to the terminals), no 
> electrons can move from one side to the other,
> - therefore, with an open circuit, there can be no loss of charge over 
> time?
> 
> In theory, that sounds solid.  However, what if there is some internal 
> leakage of electrons?  What if the electrolyte is not a perfect 
> insulator?  Is it possible for some electrons to travel (and ions in the 
> opposite direction) and some discharge to happen?
> 
> Peri
> 
> 
> 
> ------ Original Message ------
> From: "paul dove via EV" <ev@lists.evdl.org>
> To: "Electric Vehicle Discussion List" <ev@lists.evdl.org>
> Sent: 23-Jun-15 1:21:20 PM
> Subject: Re: [EVDL] "Zero self-discharge"
> 
>> 
>> 
>> Oh, yea, sorry I don't know why I was thinking magneticfield.
>> At any rate the rest of what I said is accurate I believe.There is no 
>> electric field in a battery. A battery is a chemical reactor. The 
>> reaction is called red-ox reactions. In the battery is electrolyte 
>> which can conduct ions but not electrons. Electrons must move external 
>> to the battery.
>> 
>> The potential in the battery is a chemical potential or the chemical 
>> energy.
>> 
>> 
>> 
>> 
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